Phenylacetic acid derivatives and fungicides containing them

ABSTRACT

Unsaturated phenylacetic acid derivatives of the general formula ##STR1## where U is ═O, ═CH--OCH 3 , ═N--OCH 3 , ═N--NH--CH 3 , ═CH 2 , ═CH--CH 3 , ═CH--CH 2  --CH 3  or ═CH--S--CH 3  and 
     Z 1  and Z 2  are hydrogen, halogen, trifluoromethyl, cyanide, NO 2  or unsubstituted or substituted alkyl, alkenyl, aryl, alkynyl, alkoxy, aryloxy, arylalkoxy, acyloxy, hetaryl, --CO 2  R 1 , --CONR 2  R 3 , COR 4  or NR 5  R 6 , and Z 1  and Z 2  may also form a ring, 
     A is meta or para and is (CH 2 ) n , CH═CH, O--(CH 2 ) n , O--(CH 2 ) n  --CO, CH 2  --O--CO--(CH 2 ) n , CO--O--(CH 2 ) n , O--CO--(CH 2 ) n , O--(CH 2 ) n  --CO--O, O--(CH 2 ) n+2  --O, CH 2  O--(CH 2 ) n , CH 2  --S--(CH 2 ) n  CH 2  --NR 7  --(CH 2 ) n , CH(CN)--O--CO--(CH 2 ) n , CH═N--(CH 2 ) n  or CH═N--O--(CH 2 ) n . 
     n is from 0 to 20, 
     B is substituted or unsubstituted and is hydrogen, alkyl, cycloalkyl, aryl or hetaryl, 
     R 1  to R 7  are hydrogen or unsubstituted or substituted alkyl, cycloalkyl, alkenyl, alkynyl, aryl, hetaryl, aralkyl or cycloalkylalkyl, their acid addition products and base addition products, and fungicides and insecticides containing these compounds.

This application is continuation of application Ser. No. 07/595,413, filed on Oct. 11, 1990, now abandoned.

The present invention relates to phenylacetic acid derivatives having a fungicidal and insecticidal action, fungicides containing these compounds and methods for controlling fungi.

It is known that methyl acrylate derivatives or glyoxylic ester O-methyl oxime derivatives, for example methyl 2-(2-benzoyloxyphenyl)-3-methoxyacrylate (EP-178 826), 2-benzyloxyphenylglyoxylic acid methyl ester O-methyl oxime (DE-36 23 921) or 2-phenyloxymethylenephenylglyoxylic acid methyl ester O-methyl oxime (DE-36 23 921), can be used as fungicides. However, the fungicidal action of these compounds is unsatisfactory.

We have found that novel unsaturated phenylacetic acid derivatives of the formula I ##STR2## where U is ═O, ═CH--OCH₃, ═N--OCH₃, ═N--NH--CH₃, ═CH₂, ═CH--CH₃, ═CH--CH₂ --CH₃, ═CH--S--CH₃,

Z¹ and Z² are identical or different and are each hydrogen, halogen, trifluoromethyl, cyanide, NO₂ or the unsubstituted or substituted radicals alkyl, alkenyl, aryl, alkynyl, alkoxy, aryloxy, arylalkoxy, acyloxy, hetaryl, --CO₂ R¹, --CONR² R³, --COR⁴ or --NR⁵ R⁶ or Z¹ and Z² together form a ring which is fused with the phenyl radical of which they are substituents,

A is meta or para to the substituted methyl acetate radical and is (CH₂)_(n), O--(CH₂)_(n), O--(CH₂)_(n) --CO, CH═CH--(CH₂)_(n), CH₂ O--CO--(CH₂)_(n), CO--O--(CH₂)_(n), O--CO--(CH₂)_(n), O--(CH₂)_(n) --CO--O, O--(CH₂)_(n+2) --O, CH₂ --O--(CH₂)_(n), CH₂ --S--(CH₂)_(n), CH₂ --NR⁷ --(CH₂)_(n), CH(CN)--O--CO--(CH₂)_(n), CH═N--(CH₂)_(n) or CH═N--O--(CH₂)_(n), n is from 0 to 20,

B is hydrogen or the unsubstituted or substituted radicals alkyl, cycloalkyl, aryl or hetaryl, where the radial --A--B must not be hydrogen, and

R¹ to R⁷ are identical or different and are each hydrogen or the unsubstituted or substituted radials alkyl, cycloalkyl, alkenyl, alkynyl, aryl, hetaryl, aralkyl or cycloalkylalkyl,

and their plant-tolerated acid addition products or base addition products, except for the compounds of the formulae ##STR3## have high fungitoxic and insecticidal activity and are also very well tolerated by plants.

Acids for acid addition products are, for example, mineral acids, such as hydrochloric acid, hydrobromic acid, phosphoric acid, sulfuric acid or nitric acid, or carboxylic acids, such as formic acid, acetic acid, oxalic acid, malonic acid, lactic acid, malic acid, succinic acid, tartaric acid, citric acid, salicylic acid, p-toluenesulfonic acid or dodecylbenzenesulfonic acid, or proton-acidic compounds generally, for example saccharin.

Bases for base addition products are, for example, potassium hydroxide, sodium hydroxide, potassium carbonate, sodium carbonate and ammonium hydroxide.

In the preparation, the novel compounds of the formula I may be obtained as mixtures of stereoisomers (E/Z isomers, diastereomers, enantismers), which can be separated into the individual components in a conventional manner, for example by crystallization or chromatography. Both the individual isomers and mixtures thereof can be used as fungicides and form subjects of the invention.

Z¹ and Z² are each, for example, hydrogen, fluorine, chlorine, bromine, a straight-chain, cyclic or branched, saturated or unsaturated hydrocarbon radical of 1 to 6, in particular 1 to 4, carbon atoms, C₁ -C₄ -alkoxy, C₂ -C₆ -alkylcarbonyloxy, phenyl, phenoxy, benzyl, benzyloxy, thienyl, furyl, pyrryl, pyrazolyl, imidazolyl, oxazolyl, isoxazolyl, thiazolyl, pyridyl, pyridazinyl, pyrimidyl, pyrazinyl, quinolyl, isoquinolyl, indolyl, benzimidazolyl, quinazolyl, quinoxalyl, COOR¹, CONR² R³, COR⁴ or NR⁵ R⁶, or the stated hydrocarbon, aryl or hetaryl radicals may have from 1 to 3 identical or different substituents from the group consisting of fluorine, chlorine, bromine, iodine, C₁ -C₈ -alkyl, C₁ -C₈ -alkylthio, C₁ -C₈ -alkylsulfinyl, cyano, hydroxyl and nitro.

Z¹ and Z² are each, in particular, hydrogen, fluorine, chlorine, bromine, a straight-chain, cyclic or branched, saturated or unsaturated hydrocarbon radical of 1 to 6, in particular 1 to 4, carbon atoms, C₁ -C₄ -alkoxy, C₂ -C₆ -alkylcarbonyl, phenyl, phenoxy, benzyl or benzyloxy.

Z¹ and Z² are each preferably hydrogen.

A is meta or para to the substituted methyl acetate radical and is (CH₂)_(n), CH═CH--(CH₂)_(n), O--(CH₂)_(n), O--(CH₂)_(n--CO), CH₂ --O--CO--(CH₂)_(n), CO--O--(CH₂)_(n), O--CO--(CH₂)_(n), O--(CH₂) n--CO--O, O--(CH₂)_(n+2) --O, CH₂ --O--(CH₂)_(n), CH₂ --S--(CH₂)_(n), CH₂ --NR⁷ --(CH₂)_(n), CH(CN)--O--CO--(CH₂)═_(n), CH═N--(CH₂)_(n) or CH═N--O--(CH₂)_(n).

A is, in particular, (CH₂)_(n), CH═CH--(CH₂)_(n), O--(CH₂)_(n), CH₂ --O--CO--(CH₂)═_(n), CH₂ --O--(CH₂)_(n) or CH₂ --S--(CH₂)_(n).

n is, for example, from 0 to 20, in particular from 0 to 10, preferably 0, 1, 2, 3 or 4.

B is, for example, an unsaturated or saturated straight-chain or branched hydrocarbon radical of 1 to 6, in particular 1 to 4, carbon atoms, C₃ -C₆ -cycloalkyl, phenyl, phenoxy, thienyl, furyl, pyrryl, pyrazolyl, imidazolyl, oxazolyl, isoxazolyl, thiazolyl, pyridyl, pyridazinyl, pyrimidyl, pyrazinyl, quinolyl, isoquinolyl, indolyl, benzimidazolyl, quinazolyl or quinoxazolyl, where the stated cycloalkyl, alkyl, aryl or heteraryl radicals may have from 1 to 3 identical or different substituents from the group consisting of fluorine, chlorine, bromine, iodine, C₁ -C₈ -alkyl, C₁ -C₈ -alkylthio, C₁ -C₈ -alkylsulfinyl, cyano, hydroxyl and nitro.

B is preferably an unsaturated or saturated straight-chain or branched hydrocarbon radical of 1 to 6, in particular 1 to 4, carbon atoms, C₃ -C₆ -cycloalkyl, phenyl, phenoxy, pyridyl or benzoimidazolyl.

Preferred compounds are those in which the group AB is meta to the group ##STR4##

U is ═O, ═CH--OCH₃, ═N--OCH₃, ═N--NHCH₃, ═CH₂, ═CH--CH₃, ═CH--CH₃ --CH₃ or --CH--SCH₃, preferably ═O, ═CH--OCH₃, ═N--OCH₃, ═CH--CH₃ or ═CH--S--CH₃, particularly preferably ═O, ═CH--OCH₃, ═N--OCH₃ or ═CH--CH₃.

If U gives rise to syn/anti isomers, the invention relates to all isomers, in particular the anti isomers.

R¹ to R⁷ are each, for example, identical or different straight-chain or branched hydrocarbon radicals of 1 to 6, in particular 1 to 4, carbon atoms, cyclic hydrocarbon radicals of 3 to 6 carbon atoms, phenyl, benzyl, cyclohexylmethyl, thienyl, furyl, pyrryl, pyrazolyl, imidazolyl, oxazolyl, isoxazolyl, thiazolyl, pyridyl, pyridazinyl, pyrimidyl, pyrazinyl, quinolyl, isoquinolyl, indolyl, benzoimidazolyl, quinazolyl or quinoxalyl, where the stated alkyl, cycloalkyl, aryl or hetaryl radicals may have from 1 to 3 identical or different substituents from the group consisting of fluorine, chlorine, bromine, iodine, C₁ -C₈ -alkyl, C₁ -C₈ -alkylthio, C₁ -C₈ -alkylsulfinyl, cyano, hydroxyl and nitro.

The novel compounds can be prepared, for example, by the following processes:

The benzyl bromides 2 are obtained by known processes (EP 251 082) from the corresponding phenylacetic esters 1 (Scheme 1). ##STR5##

The ketoesters 5 are key intermediates and can be prepared by reacting the corresponding haloaromatics 3 with magnesium and then reacting the resulting Grignard compounds 4 with dimethyl oxalate (M. Rambaud et al., Synthesis 1988, 564), oxalic acid imidazolide methyl ester (EP 253 213) or oxalyl chloride methyl ester. The derivatives 6 can be synthesized (Scheme 2) from the ketoesters 5 by reaction with CH₃ ON⁺ H₃ Cl⁻ or by a Wittig reaction with (C₆ H₅)₃ P⁺ --CH₂ --O--CH₃ X⁻ or (C₆ H₅)₃ P⁺ --CH₂ --CH₃ X⁻, where X is halogen. ##STR6##

X: Halogen

U: ═CH--OCH₃, ═N--OCH₃ or ═CH--OCH₃

Alternatively, the ketoesters 5 are obtainable from the corresponding aldehydes 7 (Scheme 3).

The aldehydes 7 are converted into the corresponding cyanohydrins 8 by reaction with HCN. The cyanohydrins 8 are converted by reaction with HCl and methanol into the imidoester hydrochlorides 9, which are then hydrolyzed to the mandelic esters 10. These mandelic esters 10 can then be oxidized with NaOCl/tetramethylpiperidin-N-oxyl (Tempo; P. Anelli et al., JOC 52 (1987), 2559) to the ketoesters 5 (Scheme 3). ##STR7##

Either the ketoesters 5 can be brominated with NBS (N-bromosuccinimide) to give the ketoester bromides 11 (Scheme 4) or their keto functions can be reacted with P⁺ (C₆ H₅)₃ --CH₂ --O--CH₃ ⁻ Cl (EP 178 826), CH₃ --O--NH₃ ⁻ Cl (EP 253 213) or H₂ N--NHCH₃ (OZ 39 772). The subsequent NBS bromination of these derivatives 12 then gives the benzyl bromides 13 (Scheme 4). ##STR8##

U: ═CH--OCH₃, ═N--OCH₃ or ═N--NH--CH₃

Z¹ and Z² : as defined above

NBS: N-bromosuccinimide

The benzyl bromides 14 can be reacted with nucleophiles, eg. carboxylates (OZ 39 491), phenolates, alcoholates (EP 251 082), mercaptans (EP 226 917), amines, etc. by standard processes to give the novel compounds 15 (Scheme 5). ##STR9##

U: ═O, ═CH--OCH ═N--OCH₃, ═N--NH--CH₃

A: CH₂ --O--(CH₂ O)_(n), CH₂ --S--(CH₂)_(n), CH₂ --O--CO(CH₂)_(n) or CH₂ --NR⁷ --(CH₂)_(n)

n, B, Z¹, Z² or R⁷ : as defined above

Furthermore, the benzyl bromides 14 can be reacted with phosphites or phosphines to give phosphonates 16 or phosphonium salts 17, which then react with aldehydes to give the styrene derivatives 18. Hydrogenation of these styrene derivatives 18 with a diimine or with H₂ in the presence of a suitable hydrogenation catalyst, eg. Pd or Pt, in a suitable organic solvent, such as tetrahydrofuran, methanol or acetic acid, gives the alkylated aromatics 19 (cf. EP 229 974; Scheme 6). ##STR10##

U: ═O, ═CH--OCH₃, ═N--OCH₃ or ═N--NH--CH₃

B, R⁸, R⁹ and n: as defined above

The benzyl bromides 14 can also be oxidized with oxidizing agents, such as N-methylmorpholine N-oxide (OZ 50/40842, DE 2948058) or dimethyl sulfoxide (Nace et al., J. Org. Chem. 24 (1959), 1782) to give the aldehydes 20. ##STR11##

U: ═O, ═CH--OCH₃, ═N--OCH₃ or ═N--NH--CH₃

Z¹ and Z² : as defined above

These aldehydes 20 react, for example in Wittig reactions similar to Scheme 6, with phosphonates or phosphonium salts to give the styrene derivatives 18.

The aldehydes 20 can also be reacted with, for example, amines or hydroxyamines or HCN to give Schiff's bases or oxime ethers 21 (Scheme 8) or cyanohydrins 22 (Scheme 9). ##STR12##

U: ═O, ═CH--OCH₃, ═N--OCH₃ or ═N--NH--CH₃

A: CH═N--O--(CH₂)_(n) or CH═N--(CH₂)_(n),

B, Z¹, Z² or n: as defined above

The hydroxyl function of the cyanohydrins 22 can be further reacted. Thus, acylated cyanohydrins 23 are obtained, for example, by reacting the compounds 22 with acyl chlorides (Scheme 9). ##STR13##

U: ═O, ═CH--OCH₃, ═N--OCH₃ or ═N--NH--CH₃

B, n, Z¹ or Z² : as defined above

The benzyl bromides 11 can likewise (cf. Scheme 5) be reacted with nucleophiles, such as carboxylates, alcoholates, mercaptans, etc., the derivatives 24 being obtained. The compounds 24 can be converted into the active ingredients 25 by means of a Wittig reaction with (C₆ H₅)₃ P⁺ --CH₂ --O--CH₃ Cl⁻ (EP 178 826), C₆ H₅ P⁺ --CH₃ X⁻ (X=halogen), (C₆ H₅)₃ P⁺ --CH₂ --CH₃ X⁻ (X=halogen; DE 3705389) or (C₃ H₅)₃ P⁺ --CH₂ --CH₂ --CH₃ X⁻ (X=halogen) or by reaction with CH₃ --O--N⁺ H₃ Cl⁻ (EP 253 213) or H₂ N--NHCH₃ (Scheme 10) . ##STR14##

A: CH₂ --O--CO, CH₂ --O--(CH₂)_(n), CH₂ --S--(CH₂)_(n) or CH₂ --NR⁷ (CH₂)_(n)

U: ═CH--OCH₃, ═N--OCH₃, ═N--NH--CH₃, ═CH₂, ═CH--CH₃ or ═CH--CH₂ --CH₃

B, n, Z¹, Z² or R as defined above.

Active ingredients of the structure 28 are obtained from the corresponding hydroxyphenylacetic esters 26, for example by alkylation of the compounds 26 to give the phenyl ethers 27 and subsequent formulation/methylation of 27 (EP 251 082) to give the active ingredients 28 (Scheme 11). ##STR15##

A: O--(CH₂)_(n), O--(CH₂)_(n+1) --CO or O--(CH₂)_(n+2) --O

B, n, Z¹ or Z² : as defined above

Alternatively, the hydroxyl function of the compounds 26 can be protected by a suitable protective group, eg. tetrahydropyranyl or benzyl.

Formylation/methylation (EP 251 082) of these protected phenols 29 then gives the methyl α-phenyl-β-methoxyacrylates 30, from which the phenols 31 can be liberated by treatment with hydrochloric acid in methanol or by catalytic hydrogenation (Scheme 12). ##STR16##

SG: Protective group, eg. benzyl or tetrahydropyranyl

The phenols 31 can then be reacted with electrophiles under standard conditions, the active ingredients 32 being obtained (Scheme 13). ##STR17##

A: O--(CH₂)_(n), O--(CH₂)_(n) --CO, O--CO--(CH₂)_(n), O--(CH₂)_(n) --CO--O or O--(CH₂)_(n+2) --O

B, n, Z¹ or Z² : as defined above

Other useful starting materials for the preparation of the novel compounds 41 are the hydroxybenzaldehydes 33.

The hydroxybenzaldehydes 33 can be reacted with benzyl bromide under base catalysis. The benzylated derivatives 34 thus obtained are converted into the corresponding cyanohydrins 35 by reaction with HCN.

These can be reacted with methanol and hydrochloric acid to give the imidoester hydrochlorides 36, which can be hydrolyzed to the mandelic esters 37.

The compounds 37 are oxidized with tetramethylpiperidine-N-oxyl (Tempo: P. Anelli et al., JOC 52 (1987), 2559)/NaOCl to give the ketoesters 38. These can be subjected to hydrogenolysis to give the phenols 39, which in turn react with methoxyamine hydrochloride or H₂ N--NHCH₃ to give the phenolic building blocks 40. These can be etherified or esterified, the novel active ingredients 41 being obtained (Scheme 14). Alternatively, the ketoesters 39 are etherified or esterified to the compounds 42. The derivatives 42 are then converted into the active ingredients 41 by reaction with CH₃ --O--NH₃ Cl or H₂ N--NHCH₃ (Scheme 14). ##STR18##

A: O--(CH₂)_(n), O--(CH₂)_(n) --CO, O--CO--(CH₂)_(n), O--(CH₂)_(n) --CO--O or O--(CH₂)_(n+2) --O

U: ═N--OCH₃ or ═N--NH--CH₃

B, n, Z¹ or Z² : as defined above

The ketoesters 38 can on the other hand also be subjected to Wittig reactions under base catalysis with (C₆ H₅)₃ P⁺ --CH₂ --O--CH₃ X⁻, (C₆ H₅)₃ P⁺ --CH₃ X⁻, (C₆ H₅)₃ P⁺ --CH₂ --CH₃ X⁻ or (C₆ H₅)₃ P⁺ --CH₂ --CH₂ --CH₃ X⁻ to give the benzyl ethers 43 (X=halogen).

The benzyl group can then be eliminated from these by hydrogenolysis or a free radical reaction, the phenols 44 being obtained. These can be etherified or esterified to the active ingredients 45 in reactions similar to Schemes 13 and 14 (Scheme 15). ##STR19##

U: ═CH--OCH₃, ═CH₂, ═CH--CH₃ or ═CH--CH₂ --CH₃

A: O--(CH₂)_(n), O--(CH₂)_(n) --CO, O--CO--(CH₂)_(n), O--(CH₂)_(n) --CO--O or O--(CH₂)_(n+2) --O

B, n, Z¹ and Z² : as defined above

Alternatively, the active ingredients 48 can be prepared by a method similar to Schemes 14 and 15 by introducing the side chain into the hydroxybenzaldehydes 33 themselves.

The benzaldehydes 46 thus obtained are then converted by the method described in Scheme 14 into the phenylketoacetates 47, which give the active ingredients 48 by a Wittig reaction with (C₆ H₅)₃ P⁺ --CH₂ --O--CH₃ X⁻, (C₆ H₅)₃ P⁺ --CH₃ X⁻, (C₆ H₅)₃ P⁺ --CH₂ --CH₃ X⁻ or (C₆ H₅)₃ P⁺ --CH₂ --CH₂ --CH₃ X⁺ (X=halogen) or by reaction with CH₃ --O--N⁺ H₃ Cl⁻ or H₂ N--NHCH₃ (Scheme 16). ##STR20##

U: ═CH--OCH₃, ═N--OCH₃, ═N--NH--CH₃, ═CH₂, ═CH--CH₃ or ═CH--CH₂ --CH₃

A: O--(CH₂)_(n), O--(CH₂)_(n) --CO, O--CO--(CH₂)_(n), O--(CH₂)_(n) --CO--O or O--(CH₂)_(n+2) --O

B, n, Z¹ and Z² : as defined above

The benzyl bromides 11 described in Scheme 4 can also be used for the synthesis of further key intermediates (Scheme 17). For example, the benzyl bromides 11 can be reacted with Na acetate or K acetate in highly solvating solvents, such as dimethylformamide or N-methylpyrrolidone, to give the acetates 49. The latter react under base catalysis with (C₆ H₅)₃ P⁺ --CH₂ --O--CH₃ X⁻, (C₆ H₅)₃ P⁺ --CH₃ X⁻, (C₆ H₅)₃ P⁺ --CH₂ --CH₃ X⁻ or (C₆ H₅)₃ P⁺ --CH₂ --CH₂ --CH₃ X⁻ (X=halogen) in Wittig reactions or with CH₃ ON⁺ H₃ Cl⁻ or H₂ N--NHCH₃, the derivatives 50 being formed.

The benzyl alcohols 51 and 52 are obtainable from the derivatives 49 and 50 by alkaline ester hydrolyis with aqueous alkali in the presence of a solubilizer, such as acetonitrile, dioxane or tetrahydrofuran. ##STR21##

U: ═CH--OCH₃, ═N--OCH₃, ═N--NH--CH₃, ═CH₂, ═CH--CH₃ or ═CH--CH₂ --CH₃

Z¹ and Z² : as defined above

The benzyl bromides 13, likewise obtained according to Scheme 4, can be converted into the acetates 53 (Scheme 18) similarly to Scheme 17. ##STR22##

U: ═CH--OCH₃, ═N--OCH₃ or ═N--NH--CH₃

Z¹ and Z² : as defined above

The benzyl alcohols 54 can be converted into the benzaldehydes 55 by oxidation with suitable oxidation agents, such as dimethyl sulfoxide or pyridinium chlorochromate, into the benzoic acid 56 by oxidation with, for example, chromium(VI) oxide in acetone/sulfuric acid and into the bromides 57 or chlorides 58 by reaction with suitable hydrogenating agents, eg. PBr₃ or HBr or PCl₅, SOCl₂ or PCl₃ (Scheme 19). ##STR23##

U: ═O, ═CH--OCH₃, ═N--OCH₃, ═N--NH--CH₃, ═CH₂, ═CH--CH₃ or ═CH--CH₂ --CH₃

Z¹ and Z² : as defined above

The active ingredients 59 are obtainable (Scheme 19) from the benzaldehydes 55 similarly to the reactions described in Schemes 6, 8 and 9. ##STR24##

A: HC═CH, CH₂ --CH₂, CH(CN)--OH, CH(CN)--O--CO--(CH₂)_(n), CH═N--(CH₂)_(n) or CH═N--O--(CH₂)_(n)

U: ═CH--OCH₃, ═N--OCH₃, ═N--NH--CH₃, ═CH₂, ═CH--CH₃ or ═CH--CH₂ --CH₃

B, Z¹ and Z² : as defined above

The benzoic acids 56 can be esterified under standard conditions, the benzoic esters 60 being obtained (Scheme 21). ##STR25##

U: ═O, ═CH--OCH₃, ═N--OCH₃, ═N--NH--CH₃, ═CH₂, ═CH--CH₃ or ═CH--CH₂ --CH₃

Z¹ and Z² : as defined above

The benzyl bromides 57 or chlorides 58 can be converted into stilbene or dihydrostilbenes 61 in reactions similar to Scheme 6, via their phosphonium salts or phosphonates (Scheme 22). ##STR26##

U: ═CH--OCH₃, ═N--OCH₃, ═N--NH--CH₃, ═CH₂, --CH--CH₃ or --CH--CH₂ --CH₃

A: HC═CH, H₂ C--CH₂

B, Z¹ and Z² : as defined above

The thioenolethers 63 can be prepared from the corresponding oxo analogs 64 by methods known from the literature (EP 178 826) (Scheme 23). ##STR27##

A, B, Z¹ and Z² : as defined above

The Examples which follow illustrate the preparation of the novel compounds.

EXAMPLE 1

a) Methyl m-methylmandelate

A mixture of 65 g (1 mol) of KCN and 53.5 g (1 mol) of NH₄ Cl in 300 ml of water and 60 g (0.5 mol) of m-tolylaldehyde in 500 Ml Of ether is stirred overnight at room temperature (20° C.). Thereafter, the organic phase is separated off, extracted twice with water, dried and evaporated down.

67.6 g of the cyanohydrin are obtained as a reddish brown oil.

67.6 g (about 0.5 mol) of the crude cyanohydrin product are dissolved in 600 ml of ether and the solution is cooled to 0° C.

32 g (1 mol) of methanol and 136 ml (0.6 mol) of a 4.4 M solution of hydrochloric acid in ether are added in succession and the mixture is stirred overnight at 10°-15° C. and for a further two days at room temperature. The imidoester hydrochloride which is crystallized out is filtered off under suction, washed with ether, transferred to a flask and hydrolyzed by boiling for 30 minutes with water.

The aqueous phase is cooled to room temperature and extracted twice with ether. The ether phase is filtered over a short silica gel column, dried over MgSO₄ and evaporated down. 40 g (0.22 mol; 44% based on m-tolylaldehyde) of methyl m-methylmandelate are obtained as the residue in the form of a yellow oil.

¹ H-NMR (CDCl₃): δ: 2.3 (s, 3H); 3.7 (s, 3H); 4.1 (s, broad, 1H); 5.1 (s, 1H); 7.1 (m, 4H).

b) Methyl m-methylphenylglyoxylate (Table 1, Number 1, abbreviation: 1/1)

170 ml of 12.5% strength NaOCl solution are added dropwise at 20° C. to a stirred mixture of 40 g (0.22 mol) of methyl m-methylmandelate and 1.5 g (9.6 mmol) of tetramethylpiperidine-N-oxyl in 200 ml of CH₂ Cl₂ and 1.4 g (13 mmol) KBr, 3.5 g (25 mmol) of NaH₂ PO₄.H₂ O and 4.3 g (25 mmol) of Na₂ HPO₄.2 H₂ O in 200 ml of water.

Stirring is carried out for 3 hours at room temperature, after which the organic phase is separated off, washed with NAHCO₃ solution and water and evaporated down.

The residue obtained comprises 37.5 g (0.21 mol, 96%) of methyl m-methylphenylglyoxylate as a yellow oil.

¹ H-NMR (CDCl₃): δ: 2.4 (s, 3H); 4.0 (s, 3H); 7.4 (m, 2H); 7.8 (m, 2H).

EXAMPLE 2

a) Methyl m-bromomethylenephenylglyoxylate (Table 1, Number 2, abbreviation 1/2)

18 g (0.1 mol) of methyl m-methylphenylglyoxylate, 20 g (0.11 mol) of N-bromosuccinimide and 0.1 g (0.6 mmol) of azoisobutyronitrile in 200 ml of CCl₄ are exposed for 4 hours to a 300 watt UV lamp, the solution heating up to the reflux temperature.

The precipitated succinimide is then filtered off under suction. The organic phase is washed with water, dried with MgSO₄ and filtered under suction over a little silica gel, and the filtrate is evaporated down. 28.6 g of a reddish brown oil are obtained, which is shown by NMR analysis to contain 65% of the desired compound methyl m-bromomethylenephenylglyoxylate (70%, based on methyl m-methylphenylglyoxylate), about 20% of the corresponding dibromide and about 15% of starting material.

¹ H-NMR (CDCl₃): δ: 4.0 (s, 3H); 4.55 (s, 2H); 7.3-8.2 (m, 4H).

b) Methyl m- (o-methylphenoxymethylene) -phenylglyoxylate (Table 2, Number 490, abbreviation 2/490)

0.6 g (24 mmol) of NaH is added a little at a time to a solution of 2.2 g (20.4 mmol) of o-cresol in 50 ml of dimethylformamide at room temperature, vigorous evolution of gas occurring. 5.1 g of the crude methyl m-bromomethylenephenylglyoxylate (Example 1c; contains 13 mmol of the benzyl bromide) are then added. The reaction mixture warms up to about 40° C.

Stirring is carried out for 4 hours at room temperature, the reaction mixture is diluted with water and the aqueous phase is extracted several times with ether. The combined ether phases are washed several times with Na₂ CO₃ solution and water, dried over MgSO₄ and evaporated down.

The residue is purified by column chromatography, after which 3.8 g of the desired product, contaminated with o-cresol, are obtained.

Bulb tube distillation (0. 1 mbar; 175°-225° C.) gives 2.4 g (65%) of methyl m-(o-methylphenoxymethylene)phenylglyoxylate as a yellow oil.

¹ H-NMR (CDCl₃): δ: 4.0 (s, 3H); 5.1 (s, 2H); 6.7-7.2 (m, 4H); 7.5 (t, J=9Hz, 1H); 7.7 (d, J=9Hz, 1H); 8.0 (d, J=9Hz, 1H); 8.1 (d, J=9Hz, 1H).

EXAMPLE 3

Methyl 2-[m-(o-methylphenoxymethylene)-phenyl]-crotonate (Table 6, Number 65, abbreviation 6/65)

5.8 ml of a 15% strength solution of butyllithium in hexane are added to 4.2 g (10 mmol) of ethyltriphenylphosphonium iodide in 20 ml of tetrahydrofuran at 0° C. while stirring.

After 30 minutes at room temperature, the mixture is cooled to -780° C., a pale yellow solid being precipitated, and a solution of 2.4 g (8 mmol) of methyl m-(o-methylphenoxymethylene)-phenylglyoxylate in tetrahydrofuran is added. The color of the reaction mixture changes from orange to yellow.

The reaction mixture is stirred for 2 hours at room temperature, after which it is poured onto water, the phases are separated and the aqueous phase is extracted several times with ether.

The ether phase is dried over MgSO₄ and filtered under suction over a short silica gel column, and the filtrate is evaporated down.

The remaining oil is chromatographed once with 5:1 cyclohexane/ethyl acetate and once with 4:1 cyclohexane/methylene chloride. 0.8 g (34%) of methyl 2-[m-(o-methylphenoxymethylene)-phenyl]-crotonate is obtained as a yellow oil.

¹ H-NMR (CDCl₃): δ: 1.7 (d, 8Hz, 3H); 2.3 (s, 3H); 3.7 (s, 3H); 5.1 (s, 2H); 6.8-7.5 (m, 9H).

EXAMPLE 4

m-Methylphenylglyoxylic acid methyl ester O-methyl oxime (Table 1, Number 37, abbreviation 1/37)

15 g (84 mmol) of methyl m-methylphenylglyoxylate and 8.3 g (100 mmol) of O-methylhydroxylamine hydrochloride in 150 ml of methanol are refluxed for 5 hours. Thereafter, the solvent is evaporated off and the residue is filtered with ether over silica gel.

Evaporating off the ether gives 16.2 g (93%) of m-methylphenylglyoxylic acid methyl ester O-methyl oxime as an oily cis/trans mixture (nonpolar isomer:polar isomer=25:1).

¹ H-NMR (CDCl₃): δ (nonpolar isomer): 2.35 (s, 3H); 3.93 (s, 3H); 4.0 (s, 3H); 7.1-7.5 (m, 4H); δ (polar isomer) 2.38 (s, 3H) ; 3.87 (s, 3H) ; 4.05 (s, 3H); 7.1-7.5 (m, 4H).

EXAMPLE 5

m-Bromomethylenephenylglyoxylic acid methyl ester O-methyl oxime (Table 1, Number 38, abbreviation 1/38)

15 g (72.4 mmol) of m-methylphenylglyoxylic acid methyl ester O-methyl oxime, 13.5 g (75.8 mmol) of N-bromosuccinimide and 0.1 g (0.6 mmol) of azobisisobutyrodinitrile in 150 ml of CH₂ Cl₂ are exposed for 4 hours to a 300 watt UV lamp, the reaction mixture being refluxed. Thereafter, the organic phase is extracted with water, dried over MgSO₄ and evaporated down.

Purification by column chromatography gives 10.7 g of the nonpolar isomer and 6.1 g of the polar isomer, each of which contains about 5% of the corresponding dibromide and about 10% of the starting material.

¹ H-NMR (CDCl₃): δ (nonpolar isomer): 3.95 (s, 3H); 4.05 (s, 3H); 4.5 (s, 2H); 7.2-7.5 (m, 3H); 7.6 (s, 1H); δ (polar isomer): 3.90 (s, 3H); 4.10 (s, 3H); 4.5 (s, 2H); 7.2-7.5 (m, 4H).

EXAMPLE 6

m-(6-methyl-2-oxymethylenepyridyl)-phenylglyoxylic acid methyl ester O-methyl oxime (Table 20, Number 2, abbreviation 20/2)

0.18 g (6.3 mmol) of NaH is added to 0.76 g (7 mmol) of 2-hydroxy-6-methylpyridine in 20 ml of dimethylformamide. Stirring is carried out for 30 minutes at room temperature, after which evolution of gas has ceased.

2 g of m-bromomethylenephenylglyoxylic acid methyl ester O-methyl oxime (nonpolar isomer, containing 1.7 g (6 mmol) of the substituted benzyl bromide) are then added and the mixture is stirred overnight at room temperature. Thereafter, the reaction mixture is diluted with water and the aqueous phase is extracted three times with ether. The combined ether phases are extracted with water, dried over MgSO₄ and evaporated down.

The oily residue is chromatographed with 1:1 cyclohexane/methylene chloride.

0.5 g (27%) of m-(6-methyl-2-oxymethylenepyridyl)-phenylglyoxylic acid methyl ester O-methyl oxime is obtained as a yellow oil.

¹ H-NMR (CDCl₃): δ: 2.45 (s, 3H); 3.95 (s, 3H); 4.05 (s, 3H); 5.4 (s, 2H); 6.6 (d, J=8Hz, 1H); 6.75 (d, J=8Hz, 1H); 7.3-7.6 (m, 4H); 7.7 (s, 1H).

EXAMPLE 7

2-(N-methyl-N-phenyl-m-aminomethylphenyl)-3-methoxyacrylate (Table 2, Number 88)

2.9 g (10 mmol) of methyl 2-(m-bromomethylphenyl)-3-methoxyacrylate (prepared similarly to EP 226 917) and 1.1 g (10 mmol) of N-methylaniline in 30 ml of CH₂ Cl₂ are stirred for 1 hour at room temperature and for 5 hours while refluxing. Thereafter, the organic phase is extracted with NaHCO₃ solution and water, dried over MgSO₄ and evaporated down.

Chromatography with 10:1 cyclohexane/ethyl acetate gives 2.5 g (80%) of the title compound as a pale yellow oil.

¹ H-NMR (CDCl₃): δ: 3.0 (s, 3H); 3.65 (s, 3H); 3.75 (s, 3H); 4.5 (s, 3H); 6.6-6.8 (m, 3H); 7.0-7.4 (m, 6H); 7.5 (s, 1H).

EXAMPLE 8

a) Methyl 2-(m-formylphenyl)-3-methoxyacrylate (Table 1, Number 22)

5.7 g (20 mmol) of methyl 2-(m-bromomethylphenyl)-3-methoxyacrylate and 6.7 g (50 mmol) of N-methylmorpholine N-oxide monohydrate in 100 ml of CCl₄ are refluxed for 7 hours. The reaction mixture is cooled and is extracted once with water, once with 2 N HCl and again with water. The organic phase is dried over MgSO₄ and evaporated down.

The oily residue is chromatographed with 4:1 cyclohexane/ethyl acetate, after which 3.0 g (13.6 mmol, 68%) of methyl 2-(m-formylphenyl)-3-methoxyacrylate are obtained as a colorless oil.

¹ H-NMR (CDCl₃): δ: 3.75 (s, 3H); 3.85 (s, 3H); 7.5 (t, J=8Hz, 1H); 7.65 (m, 2H); 7.8 (d, broad, J=8Hz, 1H); 7.9 (s, broad, 1H); 10 (s, 1H).

b) Methyl 2-[m-(α-phenylcarboxy)-cyanomethylphenyl]-3-methoxyacrylate ((Table 2, Number 95)

A mixture of 2.9 g (13 mmol) of methyl 2-(m-formylphenyl)-3-methoxyacrylate in 20 ml of ether and 1.7 g (26 mmol) of KCN and 1.5 g (26 mmol) of NH₄ Cl in 7.5 ml of water is stirred at room temperature overnight, after which only a small amount of starting material is detectable by thin layer chromatography.

Thereafter, the reaction mixture is diluted with a little water, and the aqueous phase is separated off and is extracted twice with ether. The combined organic phases are dried over MgSO₄ and evaporated down.

The remaining oil is subjected to coarse chromatographic purification to give 2.4 g of a colorless oil, which is directly reacted further.

1.4 g (10 mmol) of benzoyl chloride are added dropwise to 2.4 g (about 10 mmol) of the crude cyanohydrin product, 1.1 g (11 mmol) of triethylamine and 0.1 g of p-N-dimethylaminopyridine in 20 ml of CH₂ Cl₂ while cooling slightly, a white solid being precipitated.

After 1 hour at room temperature, the reaction mixture is washed once with water, twice with Na bisulfite solution and again with water, dried over MgSO₄ and evaporated down. The remaining oil is chromatographed once with 8:1 cyclohexane/ethyl acetate and once with 0.1% methanol in methylene chloride, after which 2.1 g (6 mmol), 46% based on methyl 2-(m-formylphenyl)-3-methoxyacrylate) of the title compound are obtained as a colorless oil.

¹ H-NMR (CDCl₂): δ: 3.75 (s, 3H); 3.85 (s, 3H); 6.7 (s, 1H), 7.4-7.7 (m, 9H); 8.1 (d, J=8Hz, 1H).

EXAMPLE 9

2-(p-Benzyloxyphenyl)-3-methoxyacrylate (Table 1, Number 33)

90 g (0.54 mol) of methyl 4-hydroxyphenylacetate, 60 g (0.71 mol) of dihydropyran and 0.1 g of p-toluenesulfonic acid are combined. The temperature of the mixture initially decreases to 5°-10° C. but increases again in the course of the reaction and is kept at 30°-35° C. by cooling in a water bath. After 1 hour, the excess dihydropyran is stripped off under reduced pressure from a water pump.

The crude tetrahydropyranyl ether product is dissolved in 220 ml of methyl formate, and 44 g (0.78 mol) of NaOCH₃ are added while cooling to about 10° C.

After 2 hours at room temperature, the reaction mixture is diluted with CH₂ Cl₂ and water and the aqueous phase is acidified to pH 4.5 with dilute hydrochloric acid and is extracted several times with CH₂ Cl₂. The combined organic phases are dried over MgSO₄ and evaporated down.

The oily crude product obtained as the residue is dissolved in 700 ml of . . . , 90 g (0.65 mol) of K₂ CO₃ and 74 g (0.59 mol) of dimethyl sulfate are added and the mixture is stirred overnight at room temperature.

The reaction mixture is then evaporated down in a rotary evaporator and the residue is diluted with water. The aqueous phase is extracted several times with ether. The combined ether phases are dried over MgSO₄ and evaporated down.

The crude methyl 2-(p-tetrahydropyranyloxyphenyl)-3-methoxyacrylate thus obtained is dissolved in 700 ml of methanol, and 0.5 ml of concentrated hydrochloric acid and 5 ml of water are added. After 2 hours at room temperature, 2 g of NaHCO₃ are added and the reaction mixture is evaporated down in a rotary evaporator.

The oily residue is taken up in CH₂ Cl₂, and the solution is dried over MgSO₄ and evaporated down. The residue is partially crystalline and is stirred with methyl tert-butyl ether. The solid is filtered off under suction, the mother liquor is evaporated down and the residue is chromatographed.

The title compound is obtained as a white solid (mp.=107°-109° C.) in a total yield of 66 g (0.32 mol; 59%, based on methyl p-hydroxyphenyl acetate).

¹ H-NMR (CDCl₃): δ: 3.75 (s, 3H); 3.8 (s, 3H); 6.75 (d, J=8Hz, 2H); 7.15 (d, J=8Hz, 2H); 7.5 (s, 1H).

EXAMPLE 10 2-(p-Benzyloxyphenyl)-3-methoxyacrylate (Table 3, Number 14)

1. 8 g (10. 5 mmol) of benzyl bromide are added, at -20° C., to 2.1 g (10 mmol) of methyl 2-(p-hydroxyphenyl)-3-methoxyacrylate and 0.56 g (10 mmol) of KOH powder in 20 ml of dimethylformamide. Stirring is then carried out for 3 hours at room temperature. Thereafter, the reaction mixture is diluted with water and the aqueous phase is extracted three times with ether.

The combined ether phases are extracted with water, dried over MgSO₄ and evaporated down. Chromatographic purification of the oily residue gives 2.4 g (8.1 mmol, 80%) of the title compound as a colorless solid (mp.=77°-79° C.).

¹ H-NMR (CDCl₃) : δ: 3.75 (s, 3H); 3.85 (s, 3H); 5.1 (s, 2H); 6.95 (d, J=11Hz, 2H); 7.2-7.5 (m, 7H); 7.55 (s, 1H).

EXAMPLE 11

Methyl 2-m-(phenylcarbonylmethyleneoxyphenyl)-3-methoxyacrylate (Table 2, Number 19)

0.3 g (12 mmol) of sodium hydride is added a little at a time to 2.1 g (10 mmol) of methyl 2-m-hydroxyphenyl-3-methoxyacrylate (Table 1, Number 24; prepared similarly to Example 5a) in 20 ml of dimethylformamide.

After the end of the addition, the reaction mixture is stirred for 30 minutes at room temperature, after which 3.3 g (1.6 mmol) of a-bromoacetophenone are added.

Stirring is continued overnight at room temperature, after which the reaction mixture is diluted with water and the aqueous phase is extracted three times with ether. The ether phase is extracted with water, dried over magnesium sulfate and evaporated down.

The remaining oil is chromatographed, 1.1 g (3.4 mmol, 34%) of the title compound being obtained as a white solid (mp. 103°-105° C.).

¹ H-NMR (CDCl₃): δ: 3.35 (s, 2H); 3.65 (s, 3H); 3.8 (s, 3H); 5.55 (s, 2H); 6.8 (m, 3H); 7.2 (t, J=8Hz, 1H); 7.5-7.8 (m, 4H); 8.05 (d, J=8Hz, 2H).

EXAMPLE 12

a) Methyl m-benzyloxymandelate

61 g (0.5 mol) of m-hydroxybenzaldehyde, 86 g (0.5 mol) of benzyl bromide and 70 g (0.5 mol) of K₂ CO₃ in 500 ml of ethanol are refluxed for 3 hours.

The solid is then filtered off and the ethanol is evaporated off in a rotary evaporator. Thereafter, the residue is taken up in CH₂ Cl₂ and the organic phase is extracted with 1 NAOH and twice with water. The solution is dried over MgSO₄ and the solvent is evaporated under reduced pressure.

The residue obtained comprises 102.5 g of m-benzyloxybenzaldehyde as a reddish brown oil.

A mixture of 102.5 g of the above crude benzyl ether in 400 ml of ether and 65 g (1 mol) of KCN and 53.5 g (1 mol) of NH₄ Cl in 300 ml of water is stirred overnight at room temperature. Thereafter, the organic phase is separated off, extracted twice with NaCl solution, dried over MgSO₄ and evaporated down. The residue obtained comprises 113 g of m-benzyloxymandelonitrile as a brown oil which is directly reacted further.

140 ml of 4.4 molar hydrochloric acid solution (0.62 mol) in ether are added, at 0°-50° C., to 113 g of the crude mandelonitrile product and 32 g (1 mol) of methanol in 500 ml of ether. Stirring is carried out overnight at 5°-15° C.; the corresponding imidoester hydrochloride is precipitated and is filtered off under suction and washed with ether (yield: 107 g). The solid is transferred to a round-bottomed flask and boiled for 30 minutes with 500 ml of water. Thereafter, the reaction mixture is cooled to room temperature and the aqueous phase is extracted with ether.

The combined ether phases are filtered with suction through silica gel, dried over MgSO₄ and evaporated down.

86 g (0.32 mol; 63%, based on m-hydroxybenzaldehyde) of methyl m-benzyloxymandelate are obtained as a residue.

¹ H-NMR (CDCl₃): δ: 3.5 (s, broad, 1H); 3.7 (s, 3H); 5.05 (s, 2H); 5.15 (s, 1H); 6.8-7.1 (m, 3H); 7.2-7.5 (m, 6H).

b) Methyl m-benzyloxyphenylglyoxylate

245 ml of 12.5% strength NaOCl solution are added dropwise to a stirred mixture of 86 g (0.32 mol) of methyl m-benzyloxymandelate and 2 g (13 mmol) of tetramethylpiperidine-1-oxyl in 250 ml of CH₂ Cl₂ and 1.95 g (16 mmol) of KBr, 4.9 g (28 mmol) of Na₂ HPO₄.2H₂ O and 6.1 g (44 mmol) of NaH₂ PO₄.H₂ O in 250 ml of water, while cooling with a water bath.

Stirring is carried out for 3 hours at room temperature, the aqueous phase is separated off and the organic phase is extracted with NaHCO₃ solution and with water. The organic phase is dried over MgSO₄ and evaporated down. 78 g (0.29 mol, 90%) of methyl m-benzyloxyphenylglyoxylate are obtained as a residue.

¹ H-NMR (CDCl₃): δ: 3.95 (s, 3H); 5.1 (s, 2H); 7.1-7.7 (m, 9H).

EXAMPLE 13

m-Benzyloxyphenylglyoxylic acid methyl ester O-methyl oxime (Table 2, Number 119)

4 g (15 mmol) of methyl m-benzyloxyphenylglyoxylate and 1.4 g (17 mmol) of O-methylhydroxylamine hydrochloride in 25 ml of ethanol are refluxed for 3 hours. The reaction mixture is then evaporated down. The residue is taken up in ether and the insoluble constituents are filtered off.

The solvent is evaporated off and the remaining residue is purified by column chromatography.

3.1 g (10.4 mmol, 69%) of the nonpolar isomer (colorless crystals, mp.=62°-63° C.) and 0.9 g (3 mmol, 20%) of the polar isomers (colorless crystals, mp.=63°-64° C.) of the title compound are obtained.

¹ H-NMR (CDCl₃) of the nonpolar isomer: δ: 3.9 (s, 3H); 4.0 (s, 3H); 5.05 (s, 2H); 6.95-7.5 (m, 9H).

¹ H-NMR (CDCl₃) of the polar isomer: δ: 3.85 (s, 3H); 4.05 (s, 3H); 5.05 (s, 2H); 7.0 (m, 3H); 7.2-7.5 (m, 6H).

EXAMPLE 14

a) m-Hydroxyphenylglyoxylic acid methyl ester O-methyl oxime (Table 1, Number 42)

65 g (0.24 mol) of methyl m-benzyloxyglyoxylate and 6 g of 10% strength Pd/C in 500 ml of methanol are stirred at 60° C. under hydrogen (1 bar).

After a reaction time of 8 hours in each case, the hydrogenation catalyst is filtered off and the same amount of fresh catalyst is added.

After a total reaction time of 32 hours, the reaction is complete. The catalyst is filtered off and the reaction mixture is evaporated down. The residue obtained comprises 42 g of methyl m-hydroxyphenylglyoxylate as an oily crude product.

21 g of the above crude product and 10 g (0.12 mol) of O-methylhydroxylamine hydrochloride in 200 ml of methanol are refluxed for 2 hours.

Thereafter, the solvent is distilled off, the residue is taken up in ether and the undissolved constituents are filtered off. The ether is evaporated off and the residue thus obtained is purified by column chromatography. 8.7 g (42 mmol; 35%, based on methyl mbenzyloxyphenylglyoxylate) of the nonpolar isomer (pale yellow oil) and 4.2 g (20 mmol; 17%, based on methyl mbenzyloxyphenylglyoxylate) of the polar isomer of the title compound are obtained.

¹ H-NMR (CDCl₃) of the nonpolar isomer: δ: 3.9 (s, 3H); 4.0 (s, 3H); 5.7 (s, broad, 1H); 6.9 (d, J=8Hz, 1H); 7.1 (m, 2H); 7.2 (t, J=8Hz, 1H).

¹ H-NMR (CDCl₃) of the polar isomer: δ: 3.85 (s, 3H); 4.05 (s, 3H); 6.2 (s, broad, 1H); 6.8-7.0 (m, 3H); 7.2 (t, J=8Hz, 1H).

EXAMPLE 15

m-(o-Fluorobenzyloxy)-phenylglyoxylic acid methyl ester O-methyl oxime (Table 5, Number 1)

0.3 g (12.5 mmol) of sodium hydride is added a little at a time to 2.1 g (10 mmol) of m-hydroxyphenylglyoxylic acid methyl ester O-methyl oxime (nonpolar isomer:polar isomer=2:1) in 20 ml of dimethylformamide. Stirring is carried out for 30 minutes at room temperature, 1.9 g (10 mmol) of 2-fluorobenzyl bromide are added and stirring is continued overnight at room temperature.

The reaction mixture is then diluted with water and extracted with ether. The combined ether phases are extracted with water, dried over MgSO₄ and evaporated down. Purification of the residue by column chromatography gives 1.7 g (5.4 mmol, 54%) of the nonpolar isomer (pale yellow oil) and 0.5 g (1.6 mmol, 16%) of the polar isomer (colorless solid, mp.=77°-79° C.) of the title compound.

¹ H-NMR (CDCl₃) of the nonpolar isomer: δ: 3.9 (s, 3H); 5.1 (s, 2H); 6.9-7.6 (m, 8H).

¹ H-NMR (CDCl₃) of the polar isomer: δ: 3.85 (s, 3H), 4.05 (s, 3H); 5.1 (s, 2H); 6.9-7.6 (m, 8H).

EXAMPLE 16

Methyl 2-(p-acetoxyphenyl)-3-methoxyacrylate (Table 3, Number 22)

3 g (10.5 mmol) of methyl 2-(p-bromomethylphenyl)-3-methoxyacrylate (prepared similarly to EP 226 917), 1.1 g (11.2 mmol) of potassium acetate and 50 mg of potassium iodide in 70 ml of N-methylpyrrolidone are stirred for 3 hours at 70°-80° C. The reaction mixture is diluted with water and extracted three times with ether. The combined ether phases are washed with water, dried over MgSO₄ and evaporated down. Purification of the residue by column chromatography gives 2.3 g (8.7 mmol, 83%) of the title compound as colorless crystals (mp.= 69°-70° C.).

¹ H-NMR (CDCl₃): δ: 2.1 (s, 3H); 3.75 (s, 3H); 3.85 (s, 3H); 5.1 (s, 2H); 7.35 (s, 4H); 7.6 (s, 1H).

EXAMPLE 17

Methyl 2- (p-hydroxymethylphenyl) -3-methoxyacrylate (Table 1, Number 36)

12 g (45 mmol) of methyl 2-(p-acetoxyphenyl)-3-methoxyacrylate in 200 ml of dioxane and 1.9 g (47 mmol) of NAOH in 100 ml of water are stirred for 24 hours at room temperature. A further 1.8 g of NAOH are added, stirring is carried out for 30 minutes and the reaction mixture is evaporated down under reduced pressure.

The residue is taken up with dilute hydrochloric acid and the aqueous phase is extracted three times with ether. The ether phase is filtered under suction over Al₂ O₃ and the solvent is evaporated off. The residue obtained comprises 4.2 g (19 mmol, 40%) of the title compound as a colorless oil.

¹ H-NMR (CDCl₃ ): δ: 2.4 (s, broad, 1H); 3.75 (s, 3H); 3.85 (s, 3H); 4.65 (s, 2H); 7.3 (s,-4H); 7.55 (s, 1H)

EXAMPLE 18

Methyl 2-(p-carboxyphenyl)-3-methoxyacrylate (Table 1, Number 32)

5 ml of Jones reagent (L. Chinn, Selection of Oxidants in Synthesis, Marcel Dekker, New York 1971, page 42) are added dropwise, at from -10° to -20° C., to 2.2 g (10 mmol) of methyl 2-(p-hydroxymethylphenyl)-3-methoxyacrylate in 20 ml of acetone. The mixture is allowed to reach room temperature and a further 3 ml of Jones reagent are added to the greenish solution, after which a permanent orange color is obtained.

The excess oxidizing agent is decomposed by adding a little methanol, the precipitated greenish solid is filtered off under suction and the solvent is evaporated under reduced pressure. The residue is taken up in CH₂ Cl₂ and the organic phase is extracted twice with water, dried over MgSO₄ and evaporated down.

The residue is purified by column chromatography, after which 0.8 g (3.4 mmol, 34%) of the title compound is obtained.

¹ H-NMR (CDCl₃): δ: 3.75 (s, 3H) ; 3. 9 (s, 3H) ; 7.45 (d, J=8Hz, 2H) ; 7.6 (s, 1H); 8.1 (d, J=8Hz, 2H); 11.4 (s, broad, 1H).

EXAMPLE 19

Methyl 2-(p-carboxymethylphenyl)-3-methoxyacrylate (Table 3, Number 26)

0.3 g (12.5 mmol) of sodium hydride is added a little at a time to 1 g (4 mmol) of methyl 2-(p-carboxyphenyl)-3-methoxyacrylate in 10 ml of dimethylformamide. Stirring is carried out for 30 minutes at room temperature, after which 1.3 g (10 mmol) of dimethyl sulfate are added. Stirring is continued for a further 30 minutes, the mixture is diluted with 100 ml of 1% strength NH₄ OH solution and the aqueous phase is extracted with methylene chloride. The solvent is evaporated off, the residue is taken up in ether and the ether-insoluble residue is filtered off under suction and discarded.

The organic phase is washed with water, dried over MgSO₄ and evaporated down.

Purification of the residue by column chromatography gives 0.5 g (2 mmol, 50%) of the title compound as colorless crystals (mp.=81°-84° C.).

¹ H-NMR (CDCl₃): δ=3.75 (s, 3H); 3.9 (s, 3H); 3.95 (s, 3H); 7.45 (d, J=8Hz, 2H); 7.6 (s, 1H); 8.05 (d, J=8Hz, 2H).

                                      TABLE 1                                      __________________________________________________________________________      ##STR28##                                                                     No.      U     Y        mp   NMR: δ (ppm)                                __________________________________________________________________________      1       O     3-CH.sub.3                                                                              oil  2.4(S, 3H,); 4.0(S, 3H)                            2       O     3-CH.sub.2 Br                                                                           oil  4.0(S, 3H); 4.5(S, 2H)                             3       O     3-CH.sub.2 Cl                                                    4       O     3-CHO                                                            5       O     3-COOH                                                           6       O     3-PO(OCH.sub.3).sub.2                                            7       O     3-P.sup.+ (C.sub.6 H.sub.5).sub.3 Cl.sup.-                       8       O     3-CH.sub.2 OH                                                    9       O     4-CH.sub.2 Br                                                   10       O     4-CH.sub.2 Cl                                                   11       O     4-CHO                                                           12       O     4-COOH                                                          13       O     4-PO(OCH.sub.3).sub.2                                           14       O     4-P.sup.+ (C.sub.6 H.sub.5).sub.3 Cl.sup.-                      15       O     4-CH.sub.2 OH                                                   16       HCOCH.sub.3                                                                          3-CH.sub.3                                                                              58-61                                                  17       HCOCH.sub.3                                                                          3-CH.sub.2 Br                                                                           90-91                                                  18       HCOCH.sub.3                                                                          3-CH.sub.2 Cl                                                   19       HCOCH.sub.3                                                                          3-CHO    oil  7.6(S, 1H); 10.0(S, 1H)                           20       HCOCH.sub.3                                                                          3-COOH   158-162                                                21       HCOCH.sub.3                                                                          3-OH     94-96                                                  22       HCOCH.sub.3                                                                          3-PO(OCH.sub.3).sub.2                                                                   93- 94                                                 23       HCOCH.sub.3                                                                          3-P.sup.+ (C.sub.6 H.sub.5).sub.3 Cl.sup.-                      24       HCOCH.sub.3                                                                          3-CH.sub.2 OH                                                                           oil  4.6(S, 1H); 7.55(S, 1H)                           25       HCOCH.sub.3                                                                          4-CH.sub.3                                                                              62-63                                                  26       HCOCH.sub.3                                                                          4-CH.sub.2 Br                                                                           76-81                                                  27       HCOCH.sub.3                                                                          4-CH.sub.2 Cl                                                   28       HCOCH.sub.3                                                                          4-CHO                                                           29       HCOCH.sub.3                                                                          4-COOH   158-162                                                30       HCOCH.sub.3                                                                          4-OH     107-109                                                31       HCOCH.sub.3                                                                          4-PO(OCH.sub.3).sub.2                                           32       HCOCH.sub.3                                                                          4-P.sup.+ (C.sub.6 H.sub.5).sub.3 Cl.sup.-                      33       HCOCH.sub.3                                                                          4-CH.sub.2 OH                                                                           62-63                                                   34a)    NOCH.sub.3                                                                           3-CH.sub.3                                                                              oil  2.35(S, 3H); 3.9(S, 3H);                          non-polar isomer             4.0(S, 3H)                                         34b)    NOCH.sub.3                                                                           3-CH.sub.3                                                                              66-67                                                  polar isomer                                                                    35a)    NOCH.sub.3                                                                           3-CH.sub.2 Br                                                                           74-75                                                  non-polar isomer                                                                35b)    NOCH.sub.3                                                                           3-CH.sub.2 Br                                                                           68-69                                                  36       NOCH.sub.3                                                                           3-CH.sub.2 Cl                                                   37       NOCH.sub.3                                                                           3-CHO                                                           38       NOCH.sub.3                                                                           3-COOH                                                          39       NOCH.sub.3                                                                           3-PO(OCH.sub.3).sub.2                                           40       NOCH.sub.3                                                                           3-P.sup.+ (C.sub.6 H.sub.5).sub.3 Cl.sup.-                      41       NOCH.sub.3                                                                           3-CH.sub.2 .sup.- OH                                            42       NOCH.sub.3                                                                           4-CH.sub.3                                                      43       NOCH.sub.3                                                                           4-CH.sub.2 Br                                                   44       NOCH.sub.3                                                                           4-CH.sub.2 Cl                                                   45       NOCH.sub.3                                                                           4-CHO                                                           46       NOCH.sub.3                                                                           4-COOH                                                          47       NOCH.sub.3                                                                           4-PO(OCH.sub.3).sub.2                                           48       NOCH.sub.3                                                                           4-P.sup.+ (C.sub.6 H.sub.5).sub.3 Cl.sup.-                      49       NOCH.sub.3                                                                           4-CH.sub.2 OH                                                   50       CHCH.sub.3                                                                           3-CH.sub.3                                                      51       CHCH.sub.3                                                                           3-CH.sub.2 Br                                                   52       CHCH.sub.3                                                                           3-CH.sub.2 Cl                                                   53       CHCH.sub.3                                                                           3-CHO                                                           54       CHCH.sub.3                                                                           3-COOH                                                          55       CHCH.sub.3                                                                           3-OH                                                            56       CHCH.sub.3                                                                           3-PO(OCH.sub.3).sub.2                                           57       CHCH.sub.3                                                                           3-P.sup.+ (C.sub.6 H.sub.5).sub.3 .sup.- Cl                     58       CHCH.sub.3                                                                           3-CH.sub.2 OH                                                   59       CHCH.sub.3                                                                           4-CH.sub.3                                                      60       CHCH.sub.3                                                                           4-CH.sub.2 Br                                                   61       CHCH.sub.3                                                                           4-CH.sub.2 Cl                                                   62       CHCH.sub.3                                                                           4-CHO                                                           63       CHCH.sub.3                                                                           4-COOH                                                          64       CHCH.sub.3                                                                           4-OH                                                            65       CHCH.sub.3                                                                           4-PO(OCH.sub.3).sub.2                                           66       CHCH.sub.3                                                                           4-P.sup.+ (C.sub.6 H.sub.5).sub.3 .sup.- Cl                     67       CHCH.sub.3                                                                           4-CH.sub.2 OH                                                   __________________________________________________________________________

    TABLE 2       ##STR29##        No. U A B mp NMR: δ       (ppm)                                           1 HCOCH.sub.3 CH.sub.2      CH.sub.2 H    2 HCOCH.sub.3 CH.sub.2 CH.sub.2 CH.sub.3  3 HCOCH.sub.3      CH.sub.2 CH.sub.2 cyclohexyl  4 HCOCH.sub.3 CH.sub.2 CH.sub.2 phenyl oil      2.95(S, 4H); 7.55(S, 1H)  5 HCOCH.sub.3 CH.sub.2 CH.sub.2 2-pyridyl  6      HCOCH.sub.3 CHCH H  7 HCOCH.sub.3 CHCH CH.sub.3  8 HCOCH.sub.3 CHCH      cyclohexyl  9 HCOCH.sub.3 CHCH 2-naphthyl  10 HCOCH.sub.3 CHCH 2-pyridyl       11 HCOCH.sub.3 OCH.sub.2 H oil 3.7; 3, 78; 3.82(3S, 9H);      7.55(S,      1H)  12 HCOCH.sub.3 OCH.sub.2 CH.sub.3 43-45  13 HCOCH.sub.3 OCH.sub.2      cyclohexyl  14 HCOCH.sub.3 OCH.sub.2 phenyl oil 5.05(S, 2H); 7.55(S, 1H)       15 HCOCH.sub.3 O CH.sub.2 2-pyridyl  16 HCOCH.sub.3 OCH.sub.2 CO H  17      HCOCH.sub.3 OCH.sub.2 CO CH.sub.3  18 HCOCH.sub.3 OCH.sub.2       CO cyclohexyl  19 HCOCH.sub.3 OCH.sub.2 CO phenyl 103-105       20 HCOCH.sub.3 OCH.sub.2 CO 2-pyridyl  21 HCOCH.sub.3 CH.sub.2 OCO H      oil 5.2(S, 2H); 7.55(S, 1H)  22 HCOCH.sub.3 CH.sub.2 OCO CH.sub.3 34-35      23 HCOCH.sub.3 CH.sub.2 OCO cyclohexyl  24 HCOCH.sub.3 CH.sub.2 OCO      phenyl oil 5.4(S, 2H); 7.6(S, 1H)  25 HCOCH.sub.3 CH.sub.2 OCO 2-pyridyl       26 HCOCH.sub.3 COOCH.sub.2 H  27 HCOCH.sub.3 COOCH.sub.2 CH.sub.3  28      HCOCH.sub.3 COOCH.sub.2 cyclohexyl  29 HCOCH.sub.3 COOCH.sub.2 phenyl      30 HCOCH.sub.3 COOCH.sub.2 2-pyridyl  31 HCOCH.sub.3 OCOCH.sub.2 H  32      HCOCH.sub.3 OCOCH.sub.2 CH.sub.3  33 HCOCH.sub.3 OCOCH.sub.2 cyclohexyl      34 HCOCH.sub.3 OCOCH.sub. 2 phenyl 65-66  35 HCOCH.sub.3 OCOCH.sub.2      2-pyridyl  36 HCOCH.sub.3 OCO phenyl 98-99  37 HCOCH.sub.3 OCH.sub.2 COO      CH.sub.3 51-53  38 HCOCH.sub.3 O(CH.sub.2).sub.3 COO CH.sub.3 oil 4.0(t,      J=7Hz, 3H); 7.55(S, 1H)  39 HCOCH.sub.3 O(CH.sub.2).sub.7 COO CH.sub.3      oil 3.95(t, J=7Hz, 2H); 7.55(S, 1H)  40 HCOCH.sub.3 O(CH.sub.2).sub.2 O      H oil 4.1(t, J=5Hz, 2H), 7.55(S, 1H)  41 HCOCH.sub.3 O(CH.sub.2).sub.2 O      CH.sub.3  42 HCOCH.sub.3 O(CH.sub.2).sub.2 O cyclohexyl  43 HCOCH.sub.3  (      OCH.sub.2).sub.2 O phenyl oil 4.3(S, 4H); 7.55(S, 1H)  44 HCOCH.sub.3      O(CH.sub.2).sub.2 O 2-pyridyl  45 HCOCH.sub.3 O(CH.sub.2).sub.3 O H oil      4.1(t, J=6Hz, 2H), 7.55(S, 1H)  46 HCOCH.sub.3 O(CH.sub.2).sub.3 O      CH.sub.3  47 HCOCH.sub.3 O(CH.sub.2).sub.3 O cyclohexyl  47 HCOCH.sub.3  (      OCH.sub.2 ).sub.3 O cyclohexyl  48 HCOCH.sub.3 O(CH.sub.2).sub.3 O      phenyl 68-69  49 HCOCH.sub.3 O(CH.sub.2).sub.3 O 2-pyridyl       50 HCOCH.sub.3 O(CH.sub.2).sub.4 O H oil 4.0(t, J=6Hz, 2H); 7.55(S, 1H)       51 HCOCH.sub.3 O(CH.sub.2).sub.4 O CH.sub.3       52 HCOCH.sub.3 O(CH.sub.2).sub.4 O cyclohexyl       53 HCOCH.sub.3 O(CH.sub.2).sub.4 O phenyl 92-93  54 HCOCH.sub.3      O(CH.sub.2).sub.4 O 2-pyridyl  55 HCOCH.sub.3 O(CH.sub.2).sub.5 O H  56      HCOCH.sub.3 O(CH.sub.2).sub.5 O CH.sub.3       57 HCOCH.sub.3 O(CH.sub.2).sub.5 O cyclohexyl       58 HCOCH.sub.3 O(CH.sub.2).sub.5 O phenyl oil 4.0(t, J=6Hz, 4H);      7.55(S, 1H)  59 HCOCH.sub.3 O(CH.sub.2).sub.5 O 2-pyridyl       60 HCOCH.sub.3 O(CH.sub.2).sub.6 O H  61 HCOCH.sub.3 O(CH.sub.2).sub.6      O CH.sub.3  62 HCOCH.sub.3 O(CH.sub. 2).sub.6 O cyclohexyl       63 HCOCH.sub.3 O(CH.sub.2).sub.6 O phenyl 78-80  64 HCOCH.sub.3      O(CH.sub.2).sub.6 O 2-pyridyl  65 HCOCH.sub.3 O(CH.sub.2).sub.8 O H oil      3.95(t, J=6Hz, 2H); 7.55(S, 1H)  66 HCOCH.sub.3 O(CH.sub.2).sub.8 O      CH.sub.3  67 HCOCH.sub.3 O(CH.sub.2).sub.8 O cyclohexyl  68 HCOCH.sub.3  (      OCH.sub.2).sub.8 O phenyl 69-74  69 HCOCH.sub.3 O(CH.sub.2).sub.8 O      2-pyridyl  70 HCOCH.sub.3 O(CH.sub.2).sub.10 O H  71 HCOCH.sub.3      O(CH.sub.2).sub.10 O CH.sub.3  72 HCOCH.sub.3 O(CH.sub.2).sub.10 O      cyclohexyl  73 HCOCH.sub.3 O(CH.sub.2).sub.10 O phenyl 49-52  74      HCOCH.sub.3 O(CH.sub.2).sub.10 O 2-pyridyl  75 HCOCH.sub.3 CH.sub.2 O      CH.sub.3  76 HCOCH.sub.3 CH.sub.2 O cyclohexyl  77 HCOCH.sub.3 CH.sub.2      O phenyl 72-74  78 HCOCH.sub.3 CH.sub. 2 O pyridyl  79 HCOCH.sub.3      CH.sub.2 SCH.sub.2 phenyl oil 3.55(S, 4H); 7.55(S, 1H)  80 HCOCH.sub.3      CH.sub.2 S H  81 HCOCH.sub.3 CH.sub.2 S CH.sub.3  82 HCOCH.sub.3      CH.sub.2 S cyclohexyl  83 HCOCH.sub.3 CH.sub.2 S phenyl 69-70  84      HCOCH.sub.3 CH.sub.2 S 2-pyridyl oil 4.45(S, 2H); 7.55(S, 1H)  85      HCOCH.sub.3 CH.sub.2 N(CH.sub.3) H  86 HCOCH.sub.3 CH.sub.2 N(CH.sub.3)      CH.sub.3  87 HCOCH.sub.3 CH.sub.2 N(CH.sub.3) cyclohexyl  88 HCOCH.sub.3      CH.sub.2 N(CH.sub.3) phenyl oil 3.65(S, 3H); 3.75(S, 3H);      4.55(S,      2H)  89 HCOCH.sub.3 CH.sub.2 N(CH.sub.3) 2-pyridyl  90 HCOCH.sub.3       O      CH(CN)COCH.sub.2 H  91 HCOCH.sub.3 CH(CN)OCOCH.sub.2 CH.sub.3  92      HCOCH.sub.3 CH(CN)OCOCH.sub.2 cyclohexyl       93 HCOCH.sub.3 CH(CN)OCOCH.sub.2 phenyl       94 HCOCH.sub.3 CH(CN)OCOCH.sub.2 pyridyl  95 HCOCH.sub.3 CH(CN)OCO      phenyl oil 6.7(S, 1H); 7.6(S, 1H)  96 HCOCH.sub.3 CHN H  97 HCOCH.sub.3      CHN CH.sub.3  98 HCOCH.sub.3 CHN cyclohexyl  99 HCOCH.sub.3 CHN phenyl      100 HCOCH.sub.3 CHN 2-pyridyl 101 HCOCH.sub.3 CHNOCH.sub.2 H 102      HCOCH.sub.3 CHNOCH.sub.2 CH.sub.3 103 HCOCH.sub.3 CHNOCH.sub.2 cyclohexyl       104 HCOCH.sub.3 CHNOCH.sub.2 phenyl 105 HCOCH.sub.3 CHNOCH.sub.2      2-pyridyl 106 NOCH.sub.3 CH.sub.2 CH.sub.2 H 107 NOCH.sub.3 CH.sub.2      CH.sub.2 CH.sub.3 108 NOCH.sub.3 CH.sub.2 CH.sub.2 cyclohexyl 109      NOCH.sub.3 CH.sub.2 CH.sub.2 phenyl 110 NOCH.sub.3 CH.sub.2 CH.sub.2      2-pyridyl 111 NOCH.sub.3 CHCH H 112 NOCH.sub.3 CHCH CH.sub.3 113      NOCH.sub.3 CHCH cyclohexyl 114 NOCH.sub.3 CHCH phenyl 115 NOCH.sub.3      CHCH 2-pyridyl 116 NOCH.sub.3 OCH.sub.2 H 117 NOCH.sub.3 OCH.sub.2      CH.sub.3 118 NOCH.sub.3 OCH.sub.2 cyclohexyl  119a) NOCH.sub.3 OCH.sub.2      phenyl 62-63 non-polar isomer      3.9(S, 3H); 4.0(S, 3H); 5.05(S, 2H)      119b) NOCH.sub.3 OCH.sub.2 phenyl 63-64 polar isomer      3.85(S, 3H),      4.05(S, 3H);      5.05(S, 2H) 120 NOCH.sub.3 OCH.sub.2 2-pyridyl 121      NOCH.sub.3 OCH.sub.2 CO H 122 NOCH.sub.3 OCH.sub.2 CO CH.sub.3 123      NOCH.sub.3 OCH.sub.2 CO cyclohexyl 124 NOCH.sub.3 OCH.sub.2 CO phenyl      125 NOCH.sub.3 OCH.sub.2 CO 2-pyridyl 126 NOCH.sub.3 CH.sub.2 OCO H 127      NOCH.sub.3 CH.sub.2 OCO CH.sub.3 128 NOCH.sub.3 CH.sub.2 OCO cyclohexyl      129 NOCH.sub.3 CH.sub.2 OCO phenyl 130 NOCH.sub.3 CH.sub.2 OCO 2-pyridyl      131 NOCH.sub.3 COOCH.sub.2 H 132 NOCH.sub.3 COOCH.sub.2 CH.sub.3 133      NOCH.sub.3 COOCH.sub.2 cyclohexyl 134 NOCH.sub.3 COOCH.sub.2 phenyl 135      NOCH.sub.3 COOCH.sub.2 2-pyridyl 136 NOCH.sub.3 OCOCH.sub.2 H 137      NOCH.sub.3 OCOCH.sub.2 CH.sub.3 138 NOCH.sub.3 OCOCH.sub.2 cyclohexyl      139 NOCH.sub.3 OCOCH.sub.2 phenyl 140 NOCH.sub.3 OCOCH.sub.2 2-pyridyl      141 NOCH.sub.3 OCO phenyl 142 NOCH.sub.3 OCH.sub.2 COO CH.sub.3 143      NOCH.sub.3 O(CH.sub.2).sub.3       COO CH.sub.3 144 NOCH.sub.3 O(CH.sub.2).sub.7       COO CH.sub.3 145 NOCH.sub.3 O(CH.sub.2).sub.2 O H 146 NOCH.sub.3      O(CH.sub.2).sub.2 O CH.sub.3 147 NOCH.sub.3 O(CH.sub.2).sub.2       O cyclohexyl 148 NOCH.sub.3 O(CH.sub.2).sub.2 O phenyl 149 NOCH.sub.3      O(CH.sub.2).sub.2 O 2-pyridyl 150 NOCH.sub.3 O(CH.sub.2).sub.3 O H 151      NOCH.sub.3 O(CH.sub.2).sub.3 O CH.sub.3 152 NOCH.sub.3 O(CH.sub.2).sub.3 O       cyclohexyl 153 NOCH.sub.3 O(CH.sub.2).sub.3 O phenyl 154 NOCH.sub.3      O(CH.sub.2).sub.3 O 2-pyridyl 155 NOCH.sub.3 O(CH.sub.2).sub.4 O H 156      NOCH.sub.3 O(CH.sub.2).sub.4       O CH.sub.3 157 NOCH.sub. 3 O(CH.sub.2).sub.4       O cyclohexyl 158 NOCH.sub.3 O(CH.sub.2).sub.4 O phenyl 159 NOCH.sub.3      O(CH.sub.2).sub.4 O 2-pyridyl 160 NOCH.sub.3 O(CH.sub.2).sub.5 O H 161      NOCH.sub.3 O(CH.sub.2).sub.5 O CH.sub.3 162 NOCH.sub.3 O(CH.sub.2).sub.5 O       cyclohexyl 163 NOCH.sub.3 O(CH.sub.2).sub.5 O phenyl 164 NOCH.sub.3      O(CH.sub.2).sub.5 O 2-pyridyl 165 NOCH.sub.3 O(CH.sub.2).sub.6 O H 166      NOCH.sub.3 O(CH.sub.2).sub.6 O CH.sub.3 167 NOCH.sub.3 O(CH.sub.2).sub.6 O       cyclohexyl 168 NOCH.sub.3 O(CH.sub.2).sub.6 O phenyl 169 NOCH.sub.3      O(CH.sub.2).sub.6 O 2-pyridyl 170 NOCH.sub.3 O(CH.sub.2).sub.8 O H 171      NOCH.sub.3 O(CH.sub.2).sub.8 O CH.sub.3 172 NOCH.sub.3 O(CH.sub.2).sub.8 O       cyclohexyl 173 NOCH.sub.3 O(CH.sub.2).sub.8 O phenyl 174 NOCH.sub.3      O(CH.sub.2).sub.8 O 2-pyridyl 175 NOCH.sub.3 O(CH.sub.2).sub.10 O H 176      NOCH.sub.3 O(CH.sub.2).sub.10       O CH.sub.3 177 NOCH.sub.3 O(CH.sub.2).sub.10       O cyclohexyl 178 NOCH.sub.3 O(CH.sub.2).sub.10 O phenyl 179 NOCH.sub.3  (      OCH.sub.2).sub.10 O 2-pyridyl 180 NOCH.sub.3 CH.sub.2 O H 181 NOCH.sub.3      CH.sub.2 O CH.sub.3 182 NOCH.sub.3 CH.sub.2 O cyclohexyl 183 NOCH.sub.3      CH.sub.2 O phenyl 184 NOCH.sub.3 CH.sub.2 O pyridyl 185 NOCH.sub.3      CH.sub.2 SCH.sub.2 H 186 NOCH.sub.3 CH.sub.2 SCH.sub.2 CH.sub.3 187      NOCH.sub.3 CH.sub.2 SCH.sub.2 cyclohexyl 188 NOCH.sub.3 CH.sub.2      SCH.sub.2 phenyl 189 NOCH.sub.3 CH.sub.2 SCH.sub.2 2-pyridyl 190      NOCH.sub.3 CH.sub.2 N(CH.sub.3) H 191 NOCH.sub.3 CH.sub.2 N(CH.sub.3)      CH.sub.3 192 NOCH.sub.3 CH.sub.2 N(CH.sub.3) cyclohexyl 193 NOCH.sub.3      CH.sub.2 N(CH.sub.3) phenyl 194 NOCH.sub.3 CH.sub.2 N(CH.sub. 3)      2-pyridyl 195 NOCH.sub.3 CH(CN)OCOCH.sub.2 H 196 NOCH.sub.3 CH(CN)OCOCH.s      ub.2 CH.sub.3 197 NOCH.sub.3 CH(CN)OCOCH.sub.2 cyclohexyl 198 NOCH.sub.3      CH(CN)OCOCH.sub.2 phenyl 199 NOCH.sub.3 CH(CN)OCOCH.sub.2 pyridyl 200      NOCH.sub.3 CH(CN)OCO phenyl 201 NOCH.sub.3 CHN H 202 NOCH.sub.3 CHN      CH.sub.3 203 NOCH.sub.3 CHN cyclohexyl 204 NOCH.sub.3 CHN phenyl 205      NOCH.sub.3 CHN 2-pyridyl 206 NOCH.sub.3 CHNOCH.sub.2 H 207 NOCH.sub.3    O     C      CHNH.sub.2 CH.sub.3 208 NOCH.sub.3 CHNOCH.sub.2 cyclohexyl 209 NOCH.sub.3       CHNOCH.sub.2 phenyl 210 NOCH.sub.3 CHNOCH.sub.2 2-pyridyl 211 HCCH.sub.3       CH.sub.2 CH.sub.2 H 212 HCCH.sub.3 CH.sub.2 CH.sub.2 CH.sub.3 213      HCCH.sub.3 CH.sub.2 CH.sub.2 cyclohexyl 214 HCCH.sub.3 CH.sub.2 CH.sub.2      phenyl 215 HCCH.sub.3 CH.sub.2 CH.sub.2 2-pyridyl 216 HCCH.sub.3 CHCH H      217 HCCH.sub.3 CHCH CH.sub.3 218 HC CH.sub.3 CHCH cyclohexyl 219      HCCH.sub.3 CHCH phenyl 220 HCCH.sub.3 CHCH 2-pyridyl 221 HCCH.sub.3      OCH.sub.2 H 222 HCCH.sub.3 OCH.sub.2 CH.sub.3 223 HCCH.sub.3 OCH.sub.2      cyclohexyl 224 HCCH.sub.3 OCH.sub.2 phenyl 225 HCCH.sub.3 OCH.sub.2      2-pyridyl 226 HCCH.sub.3 OCH.sub.2 CO H 227 HCCH.sub.3 OCH.sub.2 CO      CH.sub.3 228 HCCH.sub.3 OCH.sub.2 CO cyclohexyl 229 HCCH.sub.3 OCH.sub.2 C      O phenyl 230 HCCH.sub.3 OCH.sub.2 CO 2-pyridyl 231 HCCH.sub.3 CH.sub.2      OCO H 232 HCCH.sub.3 CH.sub.2 OCO CH.sub.3 233 HCCH.sub.3 CH.sub.2 OCO      cyclohexyl 234 HCCH.sub.3 CH.sub.2 OCO phenyl 235 HCCH.sub.3 CH.sub.2      OCO 2-pyridyl 236 HCCH.sub.3 COOCH.sub.2 H 237 HCCH.sub.3 COOCH.sub.2      CH.sub.3 238 HCCH.sub.3 COOCH.sub.2 cyclohexyl 239 HCCH.sub.3 COOCH.sub.2       phenyl 240 HCCH.sub.3 COO CH.sub.2 2-pyridyl 241 HCCH.sub.3 OCOCH.sub.2      H 242 HCCH.sub.3 OCOCH.sub.2 CH.sub.3 243 HCCH.sub.3 OCOCH.sub.2      cyclohexyl 244 HCCH.sub.3 OCOCH.sub.2 phenyl 245 HCCH.sub.3 OCOCH.sub.2      2-pyridyl 246 HCCH.sub.3 OCO phenyl 247 HCCH.sub.3 OCOCOO CH.sub.3 248   C      HCH.sub.3 O(CH.sub.2).sub.3       COO CH.sub.3 249 HCCH.sub.3 O(CH.sub.2).sub.3       COO CH.sub.3 250 HCCH.sub.3 O(CH.sub.2).sub.2 O H 251 HCCH.sub.3      O(CH.sub.2).sub.2 O CH.sub.3 252 HCCH.sub.3 O(CH.sub.2).sub.2       O cyclohexyl 253 HCCH.sub.3 O(CH.sub.2).sub.2 O phenyl 254 HCCH.sub.3      O(CH.sub.2).sub.2 O 2-pyridyl 255 HCCH.sub.3 O(CH.sub.2).sub.3 O H 256   C      HCH.sub.3 O(CH.sub.2).sub.3 O CH.sub.3 257 HCCH.sub.3 O(CH.sub.2).sub.3      O cyclohexyl 258 HCCH.sub.3 O(CH.sub.2).sub.3  O phenyl 259 HCCH.sub.3      O(CH.sub.2).sub.3 O 2-pyridyl 260 HCCH.sub.3 O(CH.sub.2).sub.4 O H 261   C      HCH.sub.3 O(CH.sub.2).sub.4 O CH.sub.3 262 HCCH.sub.3 O(CH.sub.2).sub.4      O cyclohexyl 263 HCCH.sub.3 O(CH.sub.2).sub.4 O phenyl 264 HCCH.sub.3      O(CH.sub.2).sub.4 O 2-pyridyl 265 HCCH.sub.3 O(CH.sub.2).sub.5 O H 266   C      HCH.sub.3 O(CH.sub.2).sub.5 O CH.sub.3 267 HCCH.sub.3 O(CH.sub.2).sub.5      O cyclohexyl 268 HCCH.sub.3 O(CH.sub.2).sub.5 O phenyl 269 HCCH.sub.3      O(CH.sub.2).sub.5 O 2-pyridyl 270 HCCH.sub.3 O(CH.sub.2).sub.6 O H 271   C      HCH.sub.3 O(CH.sub.2).sub.6 O CH.sub.3 272 HCCH.sub.3 O(CH.sub.2).sub.6      O cyclohexyl 273 HCCH.sub.3 O(CH.sub.2).sub.6 O phenyl 274 HCCH.sub.3      O(CH.sub.2).sub.6 O 2-pyridyl 275 HCCH.sub. 3 O(CH.sub.2).sub.8 O H 276      HCCH.sub.3 O(CH.sub.2).sub.8 O CH.sub.3 277 HCCH.sub.3 O(CH.sub.2).sub.8 O       cyclohexyl 278 HCCH.sub.3 O(CH.sub.2).sub.8 O phenyl 279 HCCH.sub.3      O(CH.sub.2).sub.8 O 2-pyridyl 280 HCCH.sub.3 O(CH.sub.2).sub.10 O H 281      HCCH.sub.3 O(CH.sub.2).sub.10       O CH.sub.3 282 HCCH.sub.3 O(CH.sub.2).sub.10       O cyclohexyl 283 HCCH.sub.3 O(CH.sub.2).sub.10 O phenyl 284 HCCH.sub.3  (      OCH.sub.2).sub.10 O 2-pyridyl 285 HCCH.sub.3 CH.sub.2 O H 286 HCCH.sub.3      CH.sub.2 O CH.sub.3 287 HCCH.sub.3 CH.sub.2 O cyclohexyl 288 HCCH.sub.3      CH.sub.2 O phenyl oil 1.75(d, J=8Hz, 3H); 3.75/S, 3H);      5.1(S, 2H)      289 HCCH.sub.3 CH.sub.2 O pyridyl 290 HCCH.sub.3 CH.sub.2 SCH.sub.2 H      291 HCCH.sub.3 CH2 SCH2 CH3 292 HCCH.sub.3 CH2SCH2 cyclohexyl 293      HCCH.sub.3 CH2SCH2 phenyl 294 HCCH.sub.3 CH2SCH2 2-pyridyl 295 HCCH.sub.3       CH2N(CH3) H 296 HCCH.sub.3 CH2N(CH3) CH3 297 HCCH.sub.3 CH2N(CH3)      cyclohexyl 298 HCCH.sub.3 CH2N(CH3) phenyl 299 HCCH.sub.3 CH2N(CH3)      2-pyridyl 300 HCCH.sub.3 CH(CN)OCOCH.sub.2 H 301 HCCH.sub.3 CH(CN)OCOCH.s      ub.2 CH.sub.3 302 HCCH.sub.3 CH(CN)OCOCH.sub.2 cyclohexyl 303 HCCH.sub.3      CH(CN)OCOCH.sub.2 phenyl 304 HCCH.sub.3 CH(CN)OCOCH.sub.2 pyridyl 305      HCCH.sub.3 CH(CN)OCO phenyl 306 HCCH.sub.3 CHN H 307 HCCH.sub.3 CHN      CH.sub.3 308 HCCH.sub.3 CHN cyclohexyl 309 HCCH.sub.3 CHN phenyl 310      HCCH.sub.3 CHN 2-pyridyl 311 HCCH.sub.3 CHNOCH.sub.2 H 312 HCCH.sub.3    O     C      CHNH.sub.2 CH.sub.3 313 HCCH.sub.3 CHNOCH.sub.2 cyclohexyl 314 HCCH.sub.3       CHNOCH.sub.2 phenyl 315 HCCH.sub.3 CHNOCH.sub.2 2-pyridyl 316 O      CH.sub.2 CH.sub.2 H 317 O CH.sub.2 CH.sub.2 CH.sub.3 318 O CH.sub.2      CH.sub.2 cyclohexyl 319 O CH.sub.2 CH.sub.2 phenyl 320 O CH.sub.2      CH.sub.2 2-pyridyl 321 O CHCH H 322 O CHCH CH.sub.3 323 O CHCH cyclohexyl       324 O CHCH phenyl 325 O CHCH 2-pyridyl 326 O OCH.sub.2 H 327 O OCH.sub.2       CH.sub.3 328 O OCH.sub.2 cyclohexyl 329 O OCH.sub.2 phenyl 330 O      OCH.sub.2 2-pyridyl 331 O CH.sub.2 O H 332 O CH.sub.2 O CH.sub.3 333 O      CH.sub.2 O cyclohexyl 334 O CH.sub.2 O phenyl 335 O CH.sub.2 O 2-pyridyl      336 O CH.sub.2 OCO H 337 O CH.sub.2 OCO CH.sub.3 338 O CH.sub.2 OCO      cyclohexyl 339 O CH.sub.2 OCO phenyl 340 O CH.sub.2 OCO 2-pyridyl 341      NNHCH.sub.3 CH.sub.2 CH.sub.2 H 342 NNHCH.sub.3 CH.sub.2 CH.sub.2      CH.sub.3 343 NNHCH.sub.3 CH.sub.2 CH.sub.2 cyclohexyl 344 NNHCH.sub.3      CH.sub.2 CH.sub.2 phenyl 345 NNHCH.sub.3 CH.sub.2 CH.sub.2 2-pyridyl 346      NNHCH.sub.3 CHCH H 347 NNHCH.sub.3 CHCH CH.sub.3 348 NNHCH.sub.3 CHCH      cyclohexyl 349 NNHCH.sub.3 CHCH phenyl 350 NNHCH.sub.3 CHCH 2-pyridyl      351 NNHCH.sub.3 OCH.sub.2 H 352 NNHCH.sub.3 OCH.sub.2 CH.sub.3 353      NNHCH.sub.3 OCH.sub.2 cyclohexyl 354 NNHCH.sub.3 OCH.sub.2 phenyl 355      NNHCH.sub.3 OCH.sub.2 2-pyridyl 356 NNHCH.sub.3 CH.sub.2 O H 357      NNHCH.sub.3 CH.sub.2 O CH.sub.3 358 NNHCH.sub.3 CH.sub.2 O cyclohexyl      359 NNHCH.sub.3 CH.sub.2 O phenyl 360 NNHCH.sub.3 CH.sub.2 O 2-pyridyl      361 NNHCH.sub.3 CH.sub.2 OCO H 362 NNHCH.sub.3 CH.sub.2 OCO CH.sub.3 363      NNHCH.sub.3 CH.sub.2 OCO cyclohexyl 364 NNHCH.sub.3 CH.sub.2 OCO phenyl      365 NNHCH.sub.3 CH.sub.2 OCO 2-pyridyl 366 CH.sub.2 CH.sub.2 CH.sub.2 H      367 CH.sub.2 CH.sub.2 CH.sub.2 CH.sub.3 368 CH.sub.2 CH.sub.2 CH.sub.2      cyclohexyl 369 CH.sub.2 CH.sub.2 CH.sub.2 phenyl 370 CH.sub.2 CH.sub.2      CH.sub.2 2-pyridyl 371 CH.sub.2 CHCH H 372 CH.sub.2 CHCH CH.sub.3 373      CH.sub.2 CHCH cyclohexyl 374 CH.sub.2 CHCH phenyl 375 CH.sub.2 CHCH      2-pyridyl 376 CH.sub.2 OCH.sub.2 H 377 CH.sub.2 OCH.sub.2 CH.sub.3 378      CH.sub.2 OCH.sub.2 cyclohexyl 379 CH.sub.2 OCH.sub.2 phenyl 380 CH.sub.2      OCH.sub.2 2-pyridyl 381 CH.sub.2 CH.sub.2 O H 382 CH.sub.2 CH.sub.2 O      CH.sub.3 383 CH.sub.2 CH.sub.2 O cyclohexyl 384 CH.sub.2 CH.sub.2 O      phenyl 385 CH.sub.2 CH.sub.2 O 2-pyridyl 386 CH.sub.2 CH.sub.2 OCO H 387      CH.sub.2 CH.sub.2 OCO CH.sub.3 388 CH.sub.2 CH.sub.2 OCO cyclohexyl 389      CH.sub.2 CH.sub.2 O CO phenyl 390 CH.sub.2 CH.sub.2 OCO 2-pyridyl 391      CHCH.sub.2 CH.sub.3 CH.sub.2 CH.sub.2 H 392 CHCH.sub.2 CH.sub.3 CH.sub.2 C      H.sub.2 CH.sub.3 393 CHCH.sub.2 CH.sub.3 CH.sub.2 CH.sub.2 cyclohexyl      394 CHCH.sub.2 CH.sub.3 CH.sub.2 CH.sub.2 phenyl 395 CHCH.sub.2 CH.sub.3      CH.sub.2 CH.sub.2 2-pyridyl 396 CHCH.sub.2       CH.sub.3 CHCH H 397 CHCH.sub.2 CH.sub.3 CHCH CH.sub.3 398 CHCH.sub.2      CH.sub.3 CHCH cyclohexyl 399 CHCH.sub.2 CH.sub.3 CHCH phenyl 400      CHCH.sub.2 CH.sub.3 CHCH 2-pyridyl 401 CHCH.sub.2 CH.sub.3 OCH.sub.2 H      402 CHCH.sub.2 CH.sub.3 OCH.sub.2 CH.sub.3 403 CHCH.sub.2 CH.sub.3      OCH.sub.2 cyclohexyl 404 CHCH.sub.2 CH.sub.3 OCH.sub.2 phenyl 405      CHCH.sub.2 CH.sub.3 OCH.sub.2 2-pyridyl 406 CHCH.sub.2 CH.sub.3 CH.sub.2 O       H 407 CHCH.sub.2 CH.sub.3 CH.sub.2 O CH.sub.3 408 CHCH.sub.2 CH.sub.3      CH.sub.2 O cyclohexyl 409 CHCH.sub.2 CH.sub.3 CH.sub.2 O phenyl 410      CHCH.sub.2 CH.sub.3 CH.sub.2 O 2-pyridyl 411 CHCH.sub.2 CH.sub.3      CH.sub.2 OCO H 412 CHCH.sub.2 CH.sub.3 CH.sub.2 OCO CH.sub.3 413      CHCH.sub.2 CH.sub.3 CH.sub.2 OCO cyclohexyl 414 CHCH.sub.2 CH.sub.3      CH.sub.2 OCO phenyl 415 CHCH.sub.2 CH.sub.3 CH.sub.2 OCO 2-pyridyl 416   S     C      CHH.sub.3 CH.sub.2 CH.sub.2 H 417 CHSCH.sub.3 CH.sub.2 CH.sub.2 CH.sub.3      418 CHSCH.sub.3 CH.sub.2 CH.sub.2 cyclohexyl 419 CHSCH.sub.3 CH.sub.2      CH.sub.2 phenyl 420 CHSCH.sub.3 CH.sub.2       CH.sub.2 2-pyridyl 421 CHSCH.sub.3 CHCH H 422 CHSCH.sub.3 CHCH CH.sub.3      423 CHSCH.sub.3 CHCH cyclohexyl 424 CHSCH.sub.3 CHCH phenyl 425 CHSCH.sub      .3 CHCH 2-pyridyl 426 CHSCH.sub.3 OCH.sub.2 H 427 CHSCH.sub.3 OCH.sub.2      CH.sub.3 428 CHSCH.sub.3 OCH.sub.2 cyclohexyl 429 CHSCH.sub.3 OCH.sub.2      phenyl 430 CHSCH.sub.3 OCH.sub.2 2-pyridyl 431 CHSCH.sub.3 CH.sub.2 O H      432 CHSCH.sub.3 CH.sub.2 O CH.sub.3 433 CHSCH.sub.3 CH.sub.2       O cyclohexyl 434 CHSCH.sub.3 CH.sub.2 O phenyl 435 CHSCH.sub.3 CH.sub.2 O       2-pyridyl 436 CHSCH.sub.3 CH.sub.2 OCO H 437 CHSCH.sub.3 CH.sub.2 OCO      CH.sub.3 438 CHSCH.sub.3 CH.sub.2 OCO cyclohexyl 439 CHSCH.sub.3      CH.sub.2 OCO phenyl 440 CHSCH.sub.3 CH.sub.2       OCO 2-pyridyl 441 HCOCH.sub.3 CH.sub.2 OCO 1-(4-methoxy- 66-69      phenyl)-cyclopropyl 442 HCOCH.sub.3 CH.sub.2 OCO 2-pyridyl 70-74 443      HCOCH.sub.3 CH.sub.2 OCO 3-pyridyl 444 HCOCH.sub.3 CH.sub. 2 OCO      4-pyridyl oil 5.45(S, 2H); 7.55(S, 1H) 445 HCOCH.sub.3 CH.sub.2 OCO      1-phenyl- 79-81    cyclopropyl 446 HCOCH.sub.3 CH.sub.2 OCO 1-(4-chloro-      102-103    phenyl)-cyclopropyl 447 HCOCH.sub.3 CH.sub.2 OCO 1-Indanyl-      oil 5.15(S, 2H); 7.55(S, 1H) 448 HCOCH.sub.3 CH.sub.2       OCO 4-phenyl-phenyl 132 449 HCOCH.sub.3 CH.sub.2 OCO 4-phenyl-benzyl      oil 5.15(S, 2H); .55(S, 1H) 450 HCOCH.sub.3 CH.sub.2 OCO 2-phenyl-phenyl      85-87 451 HCOCH.sub.3 CH.sub.2 OCO 2-phenoxyphenyl oil 5.3(S, 2H);      7.55(S, 1H) 452 HCOCH.sub.3 CH.sub.2 OCO 2-naphthyl oil 5.45(S, 2H);      7.6(S, 1H) 453 HCOCH.sub.3 CH.sub.2 OCO 2-naphthylmethyl oil 5.15(S,      2H); 7.5(S, 1H) 454 HCOCH.sub.3 CH.sub.2 OCO 1-naphthyl 123-124 455      HCOCH.sub.3 CH.sub.2 OCO 1-naphthylmethyl oil 5.15(S, 2H); 7.55(S, 1H)      456 HCOCH.sub.3 CH.sub.2 OCO 3-phenoxyphenyl oil 5.35(S, 2H); 7.55(S,      1H) 457 HCOCH.sub.3 CH.sub.2 OCO n-heptodecyl 38-40 458 HCOCH.sub.3      CH.sub.2 OCO n-heptyl oil 5.1(S, 2H); 7.55(S, 1H) 459 HCOCH.sub.3      CH.sub.2 OCO t-butyl oil 5.1(S, 2H); 7.55(S, 1H) 460 HCOCH.sub.3      CH.sub.2 OCO iso-butyl oil 5.1(S, 2H); 7.55(S, 1H) 461 HCOCH.sub.3      CH.sub.2 OCO n-butyl oil 5.1(S, 2H); 7.55(S, 1H) 462 HCOCH.sub.3      CH.sub.2 OCO n-Propyl oil 5.1(S, 2H); 7.55(S, 1H) 463 HCOCH.sub.3      CH.sub.2 OCO Ethyl oil 5.1(S, 2H); 7.55(S, 1H) 464 HCOCH.sub.3 CH.sub.2  C      OOCH.sub.2 phenyl oil 5.15(S, 2H); 7.6(S, 1H) 465 HCOCH.sub.3 CH.sub.2      OCO(CH.sub.2).sub.2 phenyl oil 5.1(S, 2H); 7.55(S, 1H) 466 HCOCH.sub.3      CH.sub.2 OCO(CH.sub.2).sub.3 phenyl oil 5.15(S, 2H); 7.55(S, 1H) 467      HCOCH.sub.3 CH.sub.2 OCO 1-methylcyclo- 45-47    propyl 468 HCOCH.sub.3      CH.sub.2 OCO n-pentyl oil 5.1(S, 2H); 7.55(S, 1H) 469 HCOCH.sub.3      CH.sub.2 OCO n-hexyl oil 5.1(S, 2H); 7.55(S, 1H) 470 HCOCH.sub.3      CH.sub.2 OCO n-nonyl oil 5.1(S, 2H); 7.55(S, 1H) 471 HCOCH.sub.3      CH.sub.2 OCO n-undecyl oil 5.1(S, 2H); 7.55(S, 1H) 472 HCOCH.sub.3      CH.sub.2       S n-octyl oil 3.7(S, 2H); 7.55(S, 1H) 473 HCOCH.sub.3 O(CH.sub.2).sub.2      phenyl oil 4.2(t, J=7Hz.2H); 7.55(S, 1H) 474 HCOCH.sub.3 O(CH.sub.2).sub.      3 phenyl oil 3.95(t, J=7Hz, 2H); 7.55(S, 1H) 475 HCOCH.sub.3 CH.sub.2 O      2-naphthyl 164-165 476 HCOCH.sub.3 OCH.sub.2 2-naphthyl 74-75 477      HCOCH.sub.3 O(CH.sub.2).sub.2 CH.sub.3 oil 3.9(t, J=8Hz, 2H); 7.55(S,      1H) 478 HCOCH.sub.3 O(CH.sub.2).sub.3 CH.sub.3 oil 3.95(t, J=8Hz, 2H);      7.55(S, 1H) 479 HCOCH.sub.3 O(CH.sub.2).sub.5 CH.sub.3 oil 3.95(t,      J=7Hz, 2H); 7.55(S, 1H) 480 HCOCH.sub.3 O(CH.sub.2).sub.7 CH.sub.3 38-39      481 HCOCH.sub.3 O(CH.sub.2).sub.9 CH.sub.3 53-54 482 HCOCH.sub.3      O(CH.sub.2).sub.19 CH.sub.3 62-63 483 HCOCH.sub.3 OCH.sub.2 2,6-dimethylh      eptyl oil 4.0(m, 2H); 7.55(S, 1H) 484 HCOCH.sub.3 OCH.sub.2 2,6-dimethyl-       oil 4.0(m, 2H); 7.55(S, 1H)    heptenyl-(5) 485 HCOCH.sub.3 OCH.sub.2      (trans)-2,6- oil 4.5(d, J=7Hz, 2H); 7.55(S, 1H)    dimethyl-heptadienyl-(      1,5) 486 HCOCH.sub.3 OCH.sub.2 (cis)-2,6- oil 4.5(d, J=7Hz, 2H); 7.55(S,      1H)    dimethyl-heptadienyl-(1,5) 487 HCOCH.sub.3 OCH.sub.2 (trans,      trans)- oil 4.5(d, J=7Hz, 2H); 7.55(S, 1H) (isomer mixture)   2,6,10-tri-          methylundecatrienyl-(1,5,9) 488 HCOCH.sub.3 OCH.sub.2 (trans)-1,5,9,1      3- oil 4.5(d, J=7Hz, 2H); 7.55(S, 1H) (isomer mixture)   tetramethylpenta      decen-(1) 489 HCOCH.sub.3 OCH.sub.2 1-[2-methyl-3- oil 3.75(d, J=7Hz,      2H); 7.55(S, 1H)    (4-fluorophenyl]-propenyl 490 O CH.sub.2       O 2-methylphenyl oil 5.1(s, 2H) 491 O CH.sub.2 O 3-methylphenyl 492 O      CH.sub.2 O 4-methylphenyl 493 O CH.sub.2 O 2,3-dimethylphenyl 494 O      CH.sub.2 O 2,4-dimethylphenyl 495 O CH.sub.2 O 2,5-dimethylphenyl 496 O      CH.sub.2 O 2,6-dimethylphenyl 497 O CH.sub.2 O 3,4-dimethylphenyl 498 O      CH.sub.2       O 3,5-dimethylphenyl

                                      TABLE 3                                      __________________________________________________________________________      ##STR30##                                                                     No.                                                                               U        A           B      mp  NMR: δ(ppm)                           __________________________________________________________________________      1 HCOCH.sub.3                                                                             CH.sub.2 CH.sub.2                                                                          H                                                       2 HCOCH.sub.3                                                                             CH.sub.2 CH.sub.2                                                                          CH.sub.3                                                3 HCOCH.sub.3                                                                             CH.sub.2 CH.sub.2                                                                          cyclohexyl                                              4 HCOCH.sub.3                                                                             CH.sub.2 CH.sub.2                                                                          phenyl                                                  5 HCOCH.sub.3                                                                             CH.sub.2 CH.sub.2                                                                          2-pyridyl                                               6 HCOCH.sub.3                                                                             CHCH        H                                                       7 HCOCH.sub.3                                                                             CHCH        CH.sub.3                                                8 HCOCH.sub.3                                                                             CHCH        cyclohexyl                                              9 HCOCH.sub.3                                                                             CHCH        2-naphthyl                                              10                                                                               HCOCH.sub.3                                                                             CHCH        2-pyridyl                                               11                                                                               HCOCH.sub.3                                                                             OCH.sub.2   H                                                       12                                                                               HCOCH.sub.3                                                                             OCH.sub.2   CH.sub.3                                                13                                                                               HCOCH.sub.3                                                                             OCH.sub.2   cyclohexyl                                              14                                                                               HCOCH.sub.3                                                                             OCH.sub.2   phenyl 77-79                                            15                                                                               HCOCH.sub.3                                                                             OCH.sub.2   2-pyridyl                                               16                                                                               HCOCH.sub.3                                                                             OCH.sub.2 CO                                                                               H                                                       17                                                                               HCOCH.sub.3                                                                             OCH.sub.2 CO                                                                               CH.sub. 3                                               18                                                                               HCOCH.sub.3                                                                             OCH.sub.2 CO                                                                               cyclohexyl                                              19                                                                               HCOCH.sub.3                                                                             OCH.sub.2 CO                                                                               phenyl                                                  20                                                                               HCOCH.sub.3                                                                             OCH.sub.2 CO                                                                               2-pyridyl                                               21                                                                               HCOCH.sub.3                                                                             CH.sub.2 OCO                                                                               H      oil  5.2(S, 2H); 7.6(S, 1H)                      22                                                                               HCOCH.sub.3                                                                             CH.sub.2 OCO                                                                               CH.sub.3                                                                              69-70                                            23                                                                               HCOCH.sub.3                                                                             CH.sub.2 OCO                                                                               cyclohexyl                                              24                                                                               HCOCH.sub.3                                                                             CH.sub.2 OCO                                                                               phenyl 74-75                                            25                                                                               HCOCH.sub.3                                                                             CH.sub.2 OCO                                                                               2-pyridyl                                               26                                                                               HCOCH.sub.3                                                                             COOCH.sub.2 H      81-84                                            27                                                                               HCOCH.sub.3                                                                             COOCH.sub.2 CH.sub.3                                                28                                                                               HCOCH.sub.3                                                                             COOCH.sub.2 cyclohexyl                                              29                                                                               HCOCH.sub.3                                                                             COOCH.sub.2 phenyl                                                  30                                                                               HCOCH.sub.3                                                                             COOCH.sub.2 2-pyridyl                                               31                                                                               HCOCH.sub.3                                                                             OCOCH.sub.2 H                                                       32                                                                               HCOCH.sub.3                                                                             OCOCH.sub.2 CH.sub.3                                                33                                                                               HCOCH.sub.3                                                                             OCOCH.sub.2 cyclohexyl                                              34                                                                               HCOCH.sub.3                                                                             OCOCH.sub.2 phenyl                                                  35                                                                               HCOCH.sub.3                                                                             OCOCH.sub.2 2-pyridyl                                               36                                                                               HCOCH.sub.3                                                                             OCO         phenyl                                                  37                                                                               HCOCH.sub.3                                                                             OCH.sub.2 COO                                                                              CH.sub.3                                                38                                                                               HCOCH.sub.3                                                                             O(CH.sub.2).sub.3 COO                                                                      CH.sub.3                                                                              57-58                                            39                                                                               HCOCH.sub.3                                                                             O(CH.sub.2).sub.7 COO                                                                      CH.sub.3                                                                              44                                               40                                                                               HCOCH.sub.3                                                                             O(CH.sub.2).sub.2 O                                                                        H                                                       41                                                                               HCOCH.sub.3                                                                             O(CH.sub.2).sub.2 O                                                                        CH.sub.3                                                42                                                                               HCOCH.sub.3                                                                             O(CH.sub.2).sub.2 O                                                                        cyclohexyl                                              43                                                                               HCOCH.sub.3                                                                             O(CH.sub.2).sub.2 O                                                                        phenyl                                                  44                                                                               HCOCH.sub.3                                                                             O(CH.sub.2).sub.2 O                                                                        2-pyridyl                                               45                                                                               HCOCH.sub.3                                                                             O(CH.sub.2).sub.3 O                                                                        H                                                       46                                                                               HCOCH.sub.3                                                                             O(CH.sub.2).sub.3 O                                                                        CH.sub.3                                                47                                                                               HCOCH.sub.3                                                                             O(CH.sub.2).sub.3 O                                                                        cyclohexyl                                              47                                                                               HCOCH.sub.3                                                                             O(CH.sub.2).sub.3 O                                                                        cyclohexyl                                              48                                                                               HCOCH.sub.3                                                                             O(CH.sub.2).sub.3 O                                                                        phenyl                                                  49                                                                               HCOCH.sub.3                                                                             O(CH.sub.2).sub.3 O                                                                        2-pyridyl                                               50                                                                               HCOCH.sub.3                                                                             O(CH.sub.2).sub.4 O                                                                        H                                                       51                                                                               HCOCH.sub.3                                                                             O(CH.sub.2).sub.4 O                                                                        CH.sub.3                                                52                                                                               HCOCH.sub.3                                                                             O(CH.sub.2).sub. 4 O                                                                       cycloheyl                                               53                                                                               HCOCH.sub.3                                                                             O(CH.sub.2).sub.4 O                                                                        phenyl                                                  54                                                                               HCOCH.sub.3                                                                             O(CH.sub.2).sub.4 O                                                                        2-pyridyl                                               55                                                                               HCOCH.sub.3                                                                             O(CH.sub.2).sub.5 O                                                                        H                                                       56                                                                               HCOCH.sub.3                                                                             O(CH.sub.2).sub.5 O                                                                        CH.sub.3                                                57                                                                               HCOCH.sub.3                                                                             O(CH.sub.2).sub.5 O                                                                        cyclohexyl                                              58                                                                               HCOCH.sub.3                                                                             O(CH.sub.2).sub.5 O                                                                        phenyl                                                  59                                                                               HCOCH.sub.3                                                                             O(CH.sub.2).sub.5 O                                                                        2-pyridyl                                               60                                                                               HCOCH.sub.3                                                                             O(CH.sub.2).sub.6 O                                                                        H                                                       61                                                                               HCOCH.sub.3                                                                             O(CH.sub.2).sub.6 O                                                                        CH.sub.3                                                62                                                                               HCOCH.sub.3                                                                             O(CH.sub.2).sub.6 O                                                                        cyclohexyl                                              63                                                                               HCOCH.sub.3                                                                             O(CH.sub.2).sub.6 O                                                                        phenyl                                                  64                                                                               HCOCH.sub.3                                                                             O(CH.sub.2).sub.6 O                                                                        2-pyridyl                                               65                                                                               HCOCH.sub.3                                                                             O(CH.sub.2).sub.8 O                                                                        H                                                       66                                                                               HCOCH.sub.3                                                                             O(CH.sub.2).sub.8 O                                                                        CH.sub.3                                                67                                                                               HCOCH.sub.3                                                                             O(CH.sub.2).sub.8 O                                                                        cyclohexyl                                              68                                                                               HCOCH.sub.3                                                                             O(CH.sub.2).sub.8 O                                                                        phenyl                                                   69                                                                              HCOCH.sub.3                                                                             O(CH.sub.2).sub.8 O                                                                        2-pyridyl                                               70                                                                               HCOCH.sub.3                                                                             O(CH.sub.2).sub.10 O                                                                       H                                                       71                                                                               HCOCH.sub.3                                                                             O(CH.sub.2).sub.10 O                                                                       CH.sub.3                                                72                                                                               HCOCH.sub.3                                                                             O(CH.sub.2).sub.10 O                                                                       cyclohexyl                                              73                                                                               HCOCH.sub.3                                                                             O(CH.sub.2).sub.10 O                                                                       phenyl                                                  74                                                                               HCOCH.sub.3                                                                             O(CH.sub.2).sub.10 O                                                                       2-pyridyl                                               75                                                                               HCOCH.sub.3                                                                             O           phenyl  99-100                                          76                                                                               HCOCH.sub.3                                                                             CH.sub.2 O  CH.sub.3                                                77                                                                               HCOCH.sub.3                                                                             CH.sub.2 O  cyclohexyl                                              78                                                                               HCOCH.sub.3                                                                             CH.sub.2 O  phenyl                                                  79                                                                               HCOCH.sub.3                                                                             CH.sub.2 O  pyridyl                                                 80                                                                               HCOCH.sub.3                                                                             CH.sub.2 SCH.sub.2                                                                         H                                                       81                                                                               HCOCH.sub.3                                                                             CH.sub.2 SCH.sub.2                                                                         CH.sub.3                                                82                                                                               HCOCH.sub.3                                                                             CH.sub.2 SCH.sub.2                                                                         cyclohexyl                                              83                                                                               HCOCH.sub.3                                                                             CH.sub.2 SCH.sub.2                                                                         phenyl                                                  84                                                                               HCOCH.sub.3                                                                             CH.sub.2 SCH.sub.2                                                                         2-pyridyl                                               85                                                                               HCOCH.sub.3                                                                             CH.sub.2 N(CH.sub.3)                                                                       H                                                       86                                                                               HCOCH.sub.3                                                                             CH.sub.2 N(CH.sub.3)                                                                       CH.sub.3                                                87                                                                               HCOCH.sub. 3                                                                            CH.sub.2 N(CH.sub.3)                                                                       cyclohexyl                                              88                                                                               HCOCH.sub.3                                                                             CH.sub.2 N(CH.sub.3)                                                                       phenyl                                                  89                                                                               HCOCH.sub.3                                                                             CH.sub.2 N(CH.sub.3)                                                                       2-pyridyl                                               90                                                                               HCOCH.sub.3                                                                             CH(CN)OCOCH.sub.2                                                                          H                                                       91                                                                               HCOCH.sub.3                                                                             CH(CN)OCOCH.sub.2                                                                          CH.sub.3                                                92                                                                               HCOCH.sub.3                                                                             CH(CN)OCOCH.sub.2                                                                          cyclohexyl                                              93                                                                               HCOCH.sub.3                                                                             CH(CN)OCOCH.sub.2                                                                          phenyl                                                  94                                                                               HCOCH.sub.3                                                                             CH(CN)OCOCH.sub.2                                                                          pyridyl                                                 95                                                                               HCOCH.sub.3                                                                             CH(CN)OCO   phenyl                                                  96                                                                               HCOCH.sub.3                                                                             CHN         H                                                       97                                                                               HCOCH.sub.3                                                                             CHN         CH.sub.3                                                98                                                                               HCOCH.sub.3                                                                             CHN         cyclohexyl                                              99                                                                               HCOCH.sub.3                                                                             CHN         phenyl                                                 100                                                                               HCOCH.sub.3                                                                             CHN         2-pyridyl                                              101                                                                               HCOCH.sub.3                                                                             CHNOCH.sub.2                                                                               H                                                      102                                                                               HCOCH.sub.3                                                                             CHNOCH.sub.2                                                                               CH.sub.3                                               103                                                                               HCOCH.sub.3                                                                             CHNOCH.sub.2                                                                               cyclohexyl                                             104                                                                               HCOCH.sub.3                                                                             CHNOCH.sub.2                                                                               phenyl                                                 105                                                                               HCOCH.sub.3                                                                             CHNOCH.sub.2                                                                               2-pyridyl                                              106                                                                               NOCH.sub.3                                                                              CH.sub.2 CH.sub.2                                                                          H                                                      107                                                                               NOCH.sub.3                                                                              CH.sub.2 CH.sub.2                                                                          CH.sub.3                                               108                                                                               NOCH.sub.3                                                                              CH.sub.2 CH.sub.2                                                                          cyclohexyl                                             109                                                                               NOCH.sub.3                                                                              CH.sub.2 CH.sub.2                                                                          phenyl                                                 110                                                                               NOCH.sub.3                                                                              CH.sub.2 CH.sub.2                                                                          2-pyridyl                                              111                                                                               NOCH.sub.3                                                                              CHCH        H                                                      112                                                                               NOCH.sub.3                                                                              CHCH        CH.sub.3                                               113                                                                               NOCH.sub.3                                                                              CHCH        cyclohexyl                                             114                                                                               NOCH.sub.3                                                                              CHCH        phenyl                                                 115                                                                               NOCH.sub.3                                                                              CHCH        2-pyridyl                                              116                                                                               NOCH.sub.3                                                                              OCH.sub.2   H                                                      117                                                                               NOCH.sub.3                                                                              OCH.sub.2   CH.sub.3                                               118                                                                               NOCH.sub.3                                                                              OCH.sub.2   cyclohexyl                                             119                                                                               NOCH.sub.3                                                                              OCH.sub.2   phenyl                                                 120                                                                               NOCH.sub.3                                                                              OCH.sub.2   2-pyridyl                                              121                                                                               NOCH.sub.3                                                                              OCH.sub.2 CO                                                                               H                                                      122                                                                               NOCH.sub.3                                                                              OCH.sub.2 CO                                                                               CH.sub.3                                               123                                                                               NOCH.sub.3                                                                              OCH.sub.2 CO                                                                               cyclohexyl                                             124                                                                               NOCH.sub.3                                                                              OCH.sub.2 CO                                                                               phenyl                                                 125                                                                               NOCH.sub.3                                                                              OCH.sub.2 CO                                                                               2-pyridyl                                              126                                                                               NOCH.sub.3                                                                              CH.sub.2 OCO                                                                               H                                                      127                                                                               NOCH.sub.3                                                                              CH.sub.2 OCO                                                                               CH.sub.3                                               128                                                                               NOCH.sub.3                                                                              CH.sub.2 OCO                                                                               cyclohexyl                                             129                                                                               NOCH.sub.3                                                                              CH.sub.2 OCO                                                                               phenyl                                                 130                                                                               NOCH.sub.3                                                                              CH.sub.2 OCO                                                                               2-pyridyl                                              131                                                                               NOCH.sub.3                                                                              COOCH.sub.2 H                                                      132                                                                               NOCH.sub.3                                                                              COOCH.sub.2 CH.sub.3                                               133                                                                               NOCH.sub.3                                                                              COOCH.sub.2 cyclohexyl                                             134                                                                               NOCH.sub.3                                                                              COOCH.sub.2 phenyl                                                 135                                                                               NOCH.sub.3                                                                              COOCH.sub.2 2-pyridyl                                              136                                                                               NOCH.sub.3                                                                              OCOCH.sub.2 H                                                      137                                                                               NOCH.sub.3                                                                              OCOCH.sub.2 CH.sub.3                                               138                                                                               NOCH.sub.3                                                                              OCOCH.sub.2 cyclohexyl                                             139                                                                               NOCH.sub.3                                                                              OCOCH.sub.2 phenyl                                                 140                                                                               NOCH.sub.3                                                                              OCOCH.sub.2 2-pyridyl                                              141                                                                               NOCH.sub.3                                                                              OCO         phenyl                                                 142                                                                               NOCH.sub.3                                                                              OCH.sub.2 COO                                                                              CH.sub.3                                               143                                                                               NOCH.sub.3                                                                              O(CH.sub.2).sub.3 COO                                                                      CH.sub.3                                               144                                                                               NOCH.sub.3                                                                              O(CH.sub.2).sub.7 COO                                                                      CH.sub.3                                               145                                                                               NOCH.sub.3                                                                              O(CH.sub.2).sub.2 O                                                                        H                                                      146                                                                               NOCH.sub.3                                                                              O(CH.sub.2).sub.2 O                                                                        CH.sub.3                                               147                                                                               NOCH.sub.3                                                                              O(CH.sub.2).sub.2 O                                                                        cyclohexyl                                             148                                                                               NOCH.sub.3                                                                              O(CH.sub.2).sub.2 O                                                                        phenyl                                                 149                                                                               NOCH.sub.3                                                                              O(CH.sub.2).sub.2 O                                                                        2-pyridyl                                              150                                                                               NOCH.sub.3                                                                              O(CH.sub.2).sub.3 O                                                                        H                                                      151                                                                               NOCH.sub.3                                                                              O(CH.sub.2).sub.3 O                                                                        CH.sub.3                                               152                                                                               NOCH.sub.3                                                                              O(CH.sub.2).sub.3 O                                                                        cyclohexyl                                             153                                                                               NOCH.sub.3                                                                              O(CH.sub.2).sub.3 O                                                                        phenyl                                                 154                                                                               NOCH.sub. 3                                                                             O(CH.sub.2).sub.3 O                                                                        2-pyridyl                                              155                                                                               NOCH.sub.3                                                                              O(CH.sub.2).sub.4 O                                                                        H                                                      156                                                                               NOCH.sub.3                                                                              O(CH.sub.2).sub.4 O                                                                        CH.sub.3                                               157                                                                               NOCH.sub.3                                                                              O(CH.sub.2).sub.4 O                                                                        cyclohexyl                                             158                                                                               NOCH.sub.3                                                                              O(CH.sub.2).sub.4 O                                                                        phenyl                                                 159                                                                               NOCH.sub.3                                                                              O(CH.sub.2).sub.4 O                                                                        2-pyridyl                                              160                                                                               NOCH.sub.3                                                                              O(CH.sub.2).sub.5 O                                                                        H                                                      161                                                                               NOCH.sub.3                                                                              O(CH.sub.2).sub.5 O                                                                        CH.sub.3                                               162                                                                               NOCH.sub.3                                                                              O(CH.sub.2).sub.5 O                                                                        cyclohexyl                                             163                                                                               NOCH.sub.3                                                                              O(CH.sub.2).sub.5 O                                                                        phenyl                                                 164                                                                               NOCH.sub.3                                                                              O(CH.sub.2).sub.5 O                                                                        2-pyridyl                                              165                                                                               NOCH.sub.3                                                                              O(CH.sub.2).sub.6 O                                                                        H                                                      166                                                                               NOCH.sub.3                                                                              O(CH.sub.2).sub.6 O                                                                        CH.sub.3                                               167                                                                               NOCH.sub.3                                                                              O(CH.sub.2).sub.6 O                                                                        cyclohexyl                                             168                                                                               NOCH.sub.3                                                                              O(CH.sub.2).sub.6 O                                                                        phenyl                                                 169                                                                               NOCH.sub.3                                                                              O(CH.sub.2).sub.6 O                                                                        2-pyridyl                                              170                                                                               NOCH.sub.3                                                                              O(CH.sub.2).sub.8 O                                                                        H                                                      171                                                                               NOCH.sub.3                                                                              O(CH.sub.2).sub.8 O                                                                        CH.sub.3                                               172                                                                               NOCH.sub.3                                                                              O(CH.sub.2).sub.8 O                                                                        cyclohexyl                                             173                                                                               NOCH.sub.3                                                                              O(CH.sub.2).sub.8 O                                                                        phenyl                                                 174                                                                               NOCH.sub.3                                                                              O(CH.sub.2).sub.8 O                                                                        2-pyridyl                                              175                                                                               NOCH.sub.3                                                                              O(CH.sub.2).sub.10 O                                                                       H                                                      176                                                                               NOCH.sub.3                                                                              O(CH.sub.2).sub.10 O                                                                       CH.sub.3                                               177                                                                               NOCH.sub.3                                                                              O(CH.sub.2).sub.10 O                                                                       cyclohexyl                                             178                                                                               NOCH.sub.3                                                                              O(CH.sub.2).sub.10 O                                                                       phenyl                                                 179                                                                               NOCH.sub.3                                                                              O(CH.sub.2).sub.10 O                                                                       2-pyridyl                                              180                                                                               NOCH.sub.3                                                                              CH.sub.2 O  H                                                      181                                                                               NOCH.sub.3                                                                              CH.sub.2 O  CH.sub.3                                               182                                                                               NOCH.sub.3                                                                              CH.sub.2 O  cyclohexyl                                             183                                                                               NOCH.sub.3                                                                              CH.sub.2 O  phenyl                                                 184                                                                               NOCH.sub.3                                                                              CH.sub.2 O  pyridyl                                                185                                                                               NOCH.sub.3                                                                              CH.sub.2 SCH.sub.2                                                                         H                                                      186                                                                               NOCH.sub.3                                                                              CH.sub.2 SCH.sub.2                                                                         CH.sub.3                                               187                                                                               NOCH.sub.3                                                                              CH.sub.2 SCH.sub.2                                                                         cyclohexyl                                             188                                                                               NOCH.sub.3                                                                              CH.sub.2 SCH.sub.2                                                                         phenyl                                                 189                                                                               NOCH.sub.3                                                                              CH.sub.2 SCH.sub.2                                                                         2-pyridyl                                              190                                                                               NOCH.sub.3                                                                              CH.sub.2 N(CH.sub.3)                                                                       H                                                      191                                                                               NOCH.sub.3                                                                              CH.sub. 2 N(CH.sub.3)                                                                      CH.sub.3                                               192                                                                               NOCH.sub.3                                                                              CH.sub.2 N(CH.sub.3)                                                                       cyclohexyl                                             193                                                                               NOCH.sub.3                                                                              CH.sub.2 N(CH.sub.3)                                                                       phenyl                                                 194                                                                               NOCH.sub.3                                                                              CH.sub.2 N(CH.sub.3)                                                                       2-pyridyl                                              195                                                                               NOCH.sub.3                                                                              CH(CN)OCOCH.sub.2                                                                          H                                                      196                                                                               NOCH.sub.3                                                                              CH(CN)OCOCH.sub.2                                                                          CH.sub.3                                               197                                                                               NOCH.sub.3                                                                              CH(CN)OCOCH.sub.2                                                                          cyclohexyl                                             198                                                                               NOCH.sub.3                                                                              CH(CN)OCOCH.sub.2                                                                          phenyl                                                 199                                                                               NOCH.sub.3                                                                              CH(CN)OCOCH.sub.2                                                                          pyridyl                                                200                                                                               NOCH.sub.3                                                                              CH(CN)OCO   phenyl                                                 201                                                                               NOCH.sub.3                                                                              CHN         H                                                      202                                                                               NOCH.sub.3                                                                              CHN         CH.sub.3                                               203                                                                               NOCH.sub.3                                                                              CHN         cyclohexyl                                             204                                                                               NOCH.sub.3                                                                              CHN         phenyl                                                 205                                                                               NOCH.sub.3                                                                              CHN         2-pyridyl                                              206                                                                               NOCH.sub.3                                                                              CHNOCH.sub.2                                                                               H                                                      207                                                                               NOCH.sub.3                                                                              CHNOCH.sub.2                                                                               CH.sub.3                                               208                                                                               NOCH.sub.3                                                                              CHNOCH.sub.2                                                                               cyclohexyl                                             209                                                                               NOCH.sub.3                                                                              CHNOCH.sub.2                                                                               phenyl                                                 210                                                                               NOCH.sub.3                                                                              CHNOCH.sub.2                                                                               2-pyridyl                                              211                                                                               HCCH.sub.3                                                                              CH.sub.2 CH.sub.2                                                                          H                                                      212                                                                               HCCH.sub.3                                                                              CH.sub.2 CH.sub.2                                                                          CH.sub.3                                               213                                                                               HCCH.sub.3                                                                              CH.sub.2 CH.sub.2                                                                          cyclohexyl                                             214                                                                               HCCH.sub. 3                                                                             CH.sub.2 CH.sub.2                                                                          phenyl                                                 215                                                                               HCCH.sub.3                                                                              CH.sub.2 CH.sub.2                                                                          2-pyridyl                                              216                                                                               HCCH.sub.3                                                                              CHCH        H                                                      217                                                                               HCCH.sub.3                                                                              CHCH        CH.sub.3                                               218                                                                               HCCH.sub.3                                                                              CHCH        cyclohexyl                                             219                                                                               HCCH.sub.3                                                                              CHCH        phenyl                                                 220                                                                               HCCH.sub.3                                                                              CHCH        2-pyridyl                                              221                                                                               HCCH.sub.3                                                                              OCH.sub.2   H                                                      222                                                                               HCCH.sub.3                                                                              OCH.sub.2   CH.sub.3                                               223                                                                               HCCH.sub.3                                                                              OCH.sub.2   cyclohexyl                                             224                                                                               HCCH.sub.3                                                                              OCH.sub.2   phenyl                                                 225                                                                               HCCH.sub.3                                                                              OCH.sub.2   2-pyridyl                                              226                                                                               HCCH.sub.3                                                                              OCH.sub.2 CO                                                                               H                                                      227                                                                               HCCH.sub.3                                                                              OCH.sub.2 CO                                                                               CH.sub.3                                               228                                                                               HCCH.sub.3                                                                              OCH.sub.2 CO                                                                               cyclohexyl                                             229                                                                               HCCH.sub.3                                                                              OCH.sub.2 CO                                                                               phenyl                                                 230                                                                               HCCH.sub.3                                                                              OCH.sub.2 CO                                                                               2-pyridyl                                              231                                                                               HCCH.sub.3                                                                              CH.sub.2 OCO                                                                               H                                                      232                                                                               HCCH.sub.3                                                                              CH.sub.2 OCO                                                                               CH.sub.3                                               233                                                                               HCCH.sub.3                                                                              CH.sub.2 OCO                                                                               cyclohexyl                                             234                                                                               HCCH.sub.3                                                                              CH.sub.2 OCO                                                                               phenyl                                                 235                                                                               HCCH.sub.3                                                                              CH.sub.2 OCO                                                                               2-pyridyl                                              236                                                                               HCCH.sub.3                                                                              COOCH.sub.2 H                                                      237                                                                               HCCH.sub.3                                                                              COOCH.sub.2 CH.sub.3                                               238                                                                               HCCH.sub.3                                                                              COOCH.sub.2 cyclohexyl                                             239                                                                               HCCH.sub.3                                                                              COOCH.sub.2 phenyl                                                 240                                                                               HCCH.sub.3                                                                              COOCH.sub.2 2-pyridyl                                              241                                                                               HCCH.sub.3                                                                              OCOCH.sub.2 H                                                      242                                                                               HCCH.sub.3                                                                              OCOCH.sub.2 CH.sub.3                                               243                                                                               HCCH.sub.3                                                                              OCOCH.sub.2 cyclohexyl                                             244                                                                               HCCH.sub.3                                                                              OCOCH.sub.2 phenyl                                                 245                                                                               HCCH.sub.3                                                                              OCOCH.sub.2 2-pyridyl                                              246                                                                               HCCH.sub.3                                                                              OCO         phenyl                                                 247                                                                               HCCH.sub.3                                                                              OCH.sub.2 COO                                                                              CH.sub.3                                               248                                                                               HCCH.sub.3                                                                              O(CH.sub.2).sub.3 COO                                                                      CH.sub.3                                               249                                                                               HCCH.sub.3                                                                              O(CH.sub.2).sub.7 COO                                                                      CH.sub.3                                               250                                                                               HCCH.sub.3                                                                              O(CH.sub.2).sub.2 O                                                                        H                                                      251                                                                               HCCH.sub.3                                                                              O(CH.sub.2).sub.2 O                                                                        CH.sub.3                                               252                                                                               HCCH.sub.3                                                                              O(CH.sub.2).sub.2 O                                                                        cyclohexyl                                             253                                                                               HCCH.sub.3                                                                              O(CH.sub.2).sub.2 O                                                                        phenyl                                                 254                                                                               HCCH.sub.3                                                                              O(CH.sub.2).sub.2 O                                                                        2-pyridyl                                              255                                                                               HCCH.sub.3                                                                              O(CH.sub.2).sub.3 O                                                                        H                                                      256                                                                               HCCH.sub.3                                                                              O(CH.sub.2).sub.3 O                                                                        CH.sub.3                                               257                                                                               HCCH.sub.3                                                                              O(CH.sub.2).sub.3 O                                                                        cyclohexyl                                             258                                                                               HCCH.sub.3                                                                              O(CH.sub.2).sub.3 O                                                                        phenyl                                                 259                                                                               HCCH.sub.3                                                                              O(CH.sub.2).sub.3 O                                                                        2-pryidyl                                              260                                                                               HCCH.sub.3                                                                              O(CH.sub.2).sub.4 O                                                                        H                                                      261                                                                               HCCH.sub.3                                                                              O(CH.sub.2).sub.4 O                                                                        CH.sub.3                                               262                                                                               HCCH.sub.3                                                                              O(CH.sub.2).sub.4 O                                                                        cyclohexyl                                             263                                                                               HCCH.sub.3                                                                              O(CH.sub.2).sub.4 O                                                                        phenyl                                                 264                                                                               HCCH.sub.3                                                                              O(CH.sub.2).sub.4 O                                                                        2-pyridyl                                              265                                                                               HCCH.sub.3                                                                              O(CH.sub.2).sub.5 O                                                                        H                                                      266                                                                               HCCH.sub.3                                                                              O(CH.sub.2).sub.5 O                                                                        CH.sub.3                                               267                                                                               HCCH.sub.3                                                                              O(CH.sub.2).sub.5 O                                                                        cyclohexyl                                             268                                                                               HCCH.sub.3                                                                              O(CH.sub.2).sub.5 O                                                                        phenyl                                                 269                                                                               HCCH.sub.3                                                                              O(CH.sub.2).sub.5 O                                                                        2-pyridyl                                              270                                                                               HCCH.sub.3                                                                              O(CH.sub.2).sub.6 O                                                                        H                                                      271                                                                               HCCH.sub.3                                                                              O(CH.sub.2).sub.6 O                                                                        CH.sub.3                                               272                                                                               HCCH.sub. 3                                                                             O(CH.sub.2).sub.6 O                                                                        cyclohexyl                                             273                                                                               HCCH.sub.3                                                                              O(CH.sub.2).sub.6 O                                                                        phenyl                                                 274                                                                               HCCH.sub.3                                                                              O(CH.sub.2).sub.6 O                                                                        2-pyridyl                                              275                                                                               HCCH.sub.3                                                                              O(CH.sub.2).sub.8 O                                                                        H                                                      276                                                                               HCCH.sub.3                                                                              O(CH.sub.2).sub.8 O                                                                        CH.sub.3                                               277                                                                               HCCH.sub.3                                                                              O(CH.sub.2).sub.8 O                                                                        cyclohexyl                                             278                                                                               HCCH.sub.3                                                                              O(CH.sub.2).sub.8 O                                                                        phenyl                                                 279                                                                               HCCH.sub.3                                                                              O(CH.sub.2).sub.8 O                                                                        2-pyridyl                                              280                                                                               HCCH.sub.3                                                                              O(CH.sub.2).sub.10 O                                                                       H                                                      281                                                                               HCCH.sub.3                                                                              O(CH.sub.2).sub.10 O                                                                       CH.sub.3                                               282                                                                               HCCH.sub.3                                                                              O(CH.sub.2).sub.10 O                                                                       cyclohexyl                                             283                                                                               HCCH.sub.3                                                                              O(CH.sub.2).sub.10 O                                                                       phenyl                                                 284                                                                               HCCH.sub.3                                                                              O(CH.sub.2).sub.10 O                                                                       2-pyridyl                                              285                                                                               HCCH.sub.3                                                                              CH.sub.2 O  H                                                      286                                                                               HCCH.sub.3                                                                              CH.sub.2 O  CH.sub.3                                               287                                                                               HCCH.sub.3                                                                              CH.sub.2 O  cyclohexyl                                             288                                                                               HCCH.sub.3                                                                              CH.sub.2 O  phenyl                                                 289                                                                               HCCH.sub.3                                                                              CH.sub.2 O  pyridyl                                                290                                                                               HCCH.sub.3                                                                              CH.sub.2 SCH.sub.2                                                                         H                                                      291                                                                               HCCH.sub.3                                                                              CH.sub.2 SCH.sub.2                                                                         CH.sub.3                                               292                                                                               HCCH.sub.3                                                                              CH.sub.2 SCH.sub.2                                                                         cyclohexyl                                             293                                                                               HCCH.sub.3                                                                              CH.sub.2 SCH.sub.2                                                                         phenyl                                                 294                                                                               HCCH.sub.3                                                                              CH.sub.2 SCH.sub.2                                                                         2-pyridyl                                              295                                                                               HCCH.sub.3                                                                              CH.sub.2 N(CH.sub.3)                                                                       H                                                      296                                                                               HCCH.sub.3                                                                              CH.sub.2 N(CH.sub.3)                                                                       CH.sub.3                                               297                                                                               HCCH.sub.3                                                                              CH.sub.2 N(CH.sub.3)                                                                       cyclohexyl                                             298                                                                               HCCH.sub.3                                                                              CH.sub.2 N(CH.sub.3)                                                                       phenyl                                                 299                                                                               HCCH.sub.3                                                                              CH.sub.2 N(CH.sub.3)                                                                       2-pyridyl                                              300                                                                               HCCH.sub.3                                                                              CH(CN)OCOCH.sub.2                                                                          H                                                      301                                                                               HCCH.sub.3                                                                              CH(CN)OCOCH.sub.2                                                                          CH.sub.3                                               302                                                                               HCCH.sub.3                                                                              CH(CN)OCOCH.sub.2                                                                          cyclohexyl                                             303                                                                               HCCH.sub.3                                                                              CH(CN)OCOCH.sub.2                                                                          phenyl                                                 304                                                                               HCCH.sub.3                                                                              CH(CN)OCOCH.sub.2                                                                          pyridyl                                                305                                                                               HCCH.sub.3                                                                              CH(CN)OCO   phenyl                                                 306                                                                               HCCH.sub.3                                                                              CHN         H                                                      307                                                                               HCCH.sub.3                                                                              CHN         CH.sub.3                                               308                                                                               HCCH.sub.3                                                                              CHN         cyclohexyl                                             309                                                                               HCCH.sub.3                                                                              CHN         phenyl                                                 310                                                                               HCCH.sub.3                                                                              CHN         2-pyridyl                                              311                                                                               HCCH.sub.3                                                                              CHNOCH.sub.2                                                                               H                                                      312                                                                               HCCH.sub.3                                                                              CHNOCH.sub.2                                                                               CH.sub.3                                               313                                                                               HCCH.sub.3                                                                              CHNOCH.sub.2                                                                               cyclohexyl                                             314                                                                               HCCH.sub.3                                                                              CHNOCH.sub.2                                                                               phenyl                                                 315                                                                               HCCH.sub.3                                                                              CHNOCH.sub.2                                                                               2-pyridyl                                              316                                                                               O        CH.sub.2 CH.sub.2                                                                          H                                                      317                                                                               O        CH.sub.2 CH.sub.2                                                                          CH.sub.3                                               318                                                                               O        CH.sub.2 CH.sub.2                                                                          cyclohexyl                                             319                                                                               O        CH.sub.2 CH.sub.2                                                                          phenyl                                                 320                                                                               O        CH.sub.2 CH.sub.2                                                                          2-pyridyl                                              312                                                                               O        CHCH        H                                                      322                                                                               O        CHCH        CH.sub.3                                               323                                                                               O        CHCH        cyclohexyl                                             324                                                                               O        CHCH        phenyl                                                 325                                                                               O        CHCH        2-pyridyl                                              326                                                                               O        OCH.sub.2   H                                                      327                                                                               O        OCH.sub.2   CH.sub.3                                               328                                                                               O        OCH.sub.2   cyclohexyl                                             329                                                                               O        OCH.sub.2   phenyl                                                 330                                                                               O        OCH.sub.2   2-pyridyl                                              331                                                                               O        CH.sub.2 O  H                                                      332                                                                               O        CH.sub.2 O  CH.sub.3                                               333                                                                               O        CH.sub.2 O  cyclohexyl                                             334                                                                               O        CH.sub.2 O  phenyl                                                 335                                                                               O        CH.sub.2 O  2-pyridyl                                              336                                                                               O        CH.sub. 2 OCO                                                                              H                                                      337                                                                               O        CH.sub.2 OCO                                                                               CH.sub.3                                               338                                                                               O        CH.sub.2 OCO                                                                               cyclohexyl                                             339                                                                               O        CH.sub.2 OCO                                                                               phenyl                                                 340                                                                               O        CH.sub.2 OCO                                                                               2-pyridyl                                              341                                                                               NNHCH.sub.3                                                                             CH.sub.2 CH.sub.2                                                                          H                                                      342                                                                               NNHCH.sub.3                                                                             CH.sub.2 CH.sub.2                                                                          CH.sub.3                                               343                                                                               NNHCH.sub.3                                                                             CH.sub.2 CH.sub.2                                                                          cyclohexyl                                             344                                                                               NNHCH.sub.3                                                                             CH.sub.2 CH.sub.2                                                                          phenyl                                                 345                                                                               NNHCH.sub.3                                                                             CH.sub.2 CH.sub.2                                                                          2-pyridyl                                              346                                                                               NNHCH.sub.3                                                                             CHCH        H                                                      347                                                                               NNHCH.sub.3                                                                             CHCH        CH.sub.3                                               348                                                                               NNHCH.sub.3                                                                             CHCH        cyclohexyl                                             349                                                                               NNHCH.sub.3                                                                             CHCH        phenyl                                                 350                                                                               NNHCH.sub.3                                                                             CHCH        2-pyridyl                                              351                                                                               NNHCH.sub.3                                                                             OCH.sub.2   H                                                      352                                                                               NNHCH.sub.3                                                                             OCH.sub.2   CH.sub.3                                               353                                                                               NNHCH.sub.3                                                                             OCH.sub.2   cyclohexyl                                             354                                                                               NNHCH.sub.3                                                                             OCH.sub.2   phenyl                                                 355                                                                               NNHCH.sub.3                                                                             OCH.sub.2   2-pyridyl                                              356                                                                               NNHCH.sub.3                                                                             CH.sub.2 O  H                                                      357                                                                               NNHCH.sub.3                                                                             CH.sub.2 O  CH.sub.3                                               358                                                                               NNHCH.sub.3                                                                             CH.sub.2 O  cyclohexyl                                             359                                                                               NNHCH.sub.3                                                                             CH.sub.2 O  phenyl                                                 360                                                                               NNHCH.sub.3                                                                             CH.sub.2 O  2-pyridyl                                              361                                                                               NNHCH.sub.3                                                                             CH.sub.2 OCO                                                                               H                                                      362                                                                               NNHCH.sub.3                                                                             CH.sub.2 OCO                                                                               CH.sub.3                                               363                                                                               NNHCH.sub.3                                                                             CH.sub.2 OCO                                                                               cyclohexyl                                             364                                                                               NNHCH.sub.3                                                                             CH.sub.2 OCO                                                                               phenyl                                                 365                                                                               NNHCH.sub.3                                                                             CH.sub.2 OCO                                                                               2-pyridyl                                              366                                                                               CH.sub.2 CH.sub.2 CH.sub.2                                                                          H                                                      367                                                                               CH.sub.2 CH.sub.2 CH.sub.2                                                                          CH.sub.3                                               368                                                                               CH.sub.2 CH.sub.2 CH.sub.2                                                                          cyclohexyl                                             369                                                                               CH.sub.2 CH.sub.2 CH.sub.2                                                                          phenyl                                                 370                                                                               CH.sub.2 CH.sub.2 CH.sub.2                                                                          2-pyridyl                                              371                                                                               CH.sub.2 CHCH        H                                                      372                                                                               CH.sub.2 CHCH        CH.sub.3                                               373                                                                               CH.sub.2 CHCH        cyclohexyl                                             374                                                                               CH.sub.2 CHCH        phenyl                                                 375                                                                               CH.sub.2 CHCH        2-pyridyl                                              376                                                                               CH.sub.2 OCH.sub.2   H                                                      377                                                                               CH.sub.2 OCH.sub.2   CH.sub.3                                               378                                                                               CH.sub.2 OCH.sub.2   cyclohexyl                                             379                                                                               CH.sub.2 OCH.sub.2   phenyl                                                 380                                                                               CH.sub.2 OCH.sub.2   2-pyridyl                                              381                                                                               CH.sub.2 CH.sub.2 O  H                                                      382                                                                               CH.sub.2 CH.sub.2 O  CH.sub.3                                               383                                                                               CH.sub.2 CH.sub.2 O  cyclohexyl                                             384                                                                               CH.sub.2 CH.sub.2 O  phenyl                                                 385                                                                               CH.sub.2 CH.sub.2 O  2-pyridyl                                              386                                                                               CH.sub.2 CH.sub.2 OCO                                                                               H                                                      387                                                                               CH.sub.2 CH.sub.2 OCO                                                                               CH.sub.3                                               388                                                                               CH.sub.2 CH.sub.2 OCO                                                                               cyclohexyl                                             389                                                                               CH.sub.2 CH.sub.2 OCO                                                                               phenyl                                                 390                                                                               CH.sub.2 CH.sub.2 OCO                                                                               2-pyridyl                                              391                                                                               CHCH.sub.2 CH.sub.3                                                                     CH.sub.2 CH.sub.2                                                                          H                                                      392                                                                               CHCH.sub.2 CH.sub.3                                                                     CH.sub.2 CH.sub.2                                                                          CH.sub.3                                               393                                                                               CHCH.sub.2 CH.sub.3                                                                     CH.sub.2 CH.sub.2                                                                          cyclohexyl                                             394                                                                               CHCH.sub.2 CH.sub.3                                                                     CH.sub.2 CH.sub.2                                                                          phenyl                                                 395                                                                               CHCH.sub.2 CH.sub.3                                                                     CH.sub.2 CH.sub.2                                                                          2-pyridyl                                              396                                                                               CHCH.sub.2 CH.sub.3                                                                     CHCH        H                                                      397                                                                               CHCH.sub.2 CH.sub.3                                                                     CHCH        CH.sub.3                                               398                                                                               CHCH.sub.2 CH.sub.3                                                                     CHCH        cyclohexyl                                             399                                                                               CHCH.sub.2 CH.sub.3                                                                     CHCH        phenyl                                                 400                                                                               CHCH.sub.2 CH.sub.3                                                                     CHCH        2-pyridyl                                              401                                                                               CHCH.sub.2 CH.sub.3                                                                     OCH.sub.2   H                                                      402                                                                               CHCH.sub.2 CH.sub.3                                                                     OCH.sub. 2  CH.sub.3                                               403                                                                               CHCH.sub.2 CH.sub.3                                                                     OCH.sub.2   cyclohexyl                                             404                                                                               CHCH.sub.2 CH.sub.3                                                                     OCH.sub.2   phenyl                                                 405                                                                               CHCH.sub.2 CH.sub.3                                                                     OCH.sub.2   2-pyridyl                                              406                                                                               CHCH.sub.2 CH.sub.3                                                                     CH.sub.2 O  H                                                      407                                                                               CHCH.sub.2 CH.sub.3                                                                     CH.sub.2 O  CH.sub.3                                               408                                                                               CHCH.sub.2 CH.sub.3                                                                     CH.sub.2 O  cyclohexyl                                             409                                                                               CHCH.sub.2 CH.sub.3                                                                     CH.sub.2 O  phenyl                                                 410                                                                               CHCH.sub.2 CH.sub.3                                                                     CH.sub.2 O  2-pyridyl                                              411                                                                               CHCH.sub.2 CH.sub.3                                                                     CH.sub.2 OCO                                                                               H                                                      412                                                                               CHCH.sub.2 CH.sub.3                                                                     CH.sub.2 OCO                                                                               CH.sub.3                                               413                                                                               CHCH.sub.2 CH.sub.3                                                                     CH.sub.2 OCO                                                                               cyclohexyl                                             414                                                                               CHCH.sub.2 CH.sub.3                                                                     CH.sub.2 OCO                                                                               phenyl                                                 415                                                                               CHCH.sub.2 CH.sub.3                                                                     CH.sub.2 OCO                                                                               2-pyridyl                                              416                                                                               CHSCH.sub.3                                                                             CH.sub.2 CH.sub.2                                                                          H                                                      417                                                                               CHSCH.sub.3                                                                             CH.sub.2 CH.sub.2                                                                          CH.sub.3                                               418                                                                               CHSCH.sub.3                                                                             CH.sub.2 CH.sub.2                                                                          cyclohexyl                                             419                                                                               CHS CH.sub.3                                                                            CH.sub.2 CH.sub.2                                                                          phenyl                                                 420                                                                               CHSCH.sub.3                                                                             CH.sub.2 CH.sub.2                                                                          2-pyridyl                                              421                                                                               CHSCH.sub.3                                                                             CHCH        H                                                      422                                                                               CHSCH.sub.3                                                                             CHCH        CH.sub.3                                               423                                                                               CHSCH.sub.3                                                                             CHCH        cyclohexyl                                             424                                                                               CHSCH.sub.3                                                                             CHCH        phenyl                                                 425                                                                               CHSCH.sub.3                                                                             CHCH        2-pyridyl                                              426                                                                               CHSCH.sub.3                                                                             OCH.sub.2   H                                                      427                                                                               CHSCH.sub.3                                                                             OCH.sub.2   CH.sub.3                                               428                                                                               CHSCH.sub.3                                                                             OCH.sub.2   cyclohexyl                                             429                                                                               CHSCH.sub.3                                                                             OCH.sub.2   phenyl                                                 430                                                                               CHSCH.sub.3                                                                             OCH.sub.2   2-pyridyl                                              431                                                                               CHSCH.sub.3                                                                             CH.sub.2 O  H                                                      432                                                                               CHSCH.sub.3                                                                             CH.sub.2 O  CH.sub.3                                               433                                                                               CHSCH.sub.3                                                                             CH.sub.2 O  cyclohexyl                                             434                                                                               CHSCH.sub.3                                                                             CH.sub.2 O  phenyl                                                 435                                                                               CHSCH.sub.3                                                                             CH.sub.2 O  2-pyridyl                                              436                                                                               CHSCH.sub.3                                                                             CH.sub.2 OCO                                                                               H                                                      437                                                                               CHSCH.sub.3                                                                             CH.sub.2 OCO                                                                               CH.sub.3                                               438                                                                               CHSCH.sub.3                                                                             CH.sub.2 OCO                                                                               cyclohexyl                                             439                                                                               CHSCH.sub.3                                                                             CH.sub.2 O CO                                                                              phenyl                                                 440                                                                               CHSCH.sub.3                                                                             CH.sub.2 OCO                                                                               2-pyridyl                                              441                                                                               HCOCH.sub.3                                                                             CH.sub.2 OCO                                                                               n-heptadecyl                                                                          37-38                                           442                                                                               HCOCH.sub.3                                                                             CH.sub.2 OCO                                                                               n-heptyl                                                                              oil  5.1(S, 2H); 7.55(S, 1H)                    443                                                                               HCOCH.sub.3                                                                             CH.sub.2 OCO                                                                               t-butyl                                                                               oil  5.1(S, 2H); 7.6(S, 1H)                     444                                                                               HCOCH.sub.3                                                                             CH.sub.2 OCO                                                                               iso-butyl                                                                             oil  5.1(S, 2H); 7.55(S, 1H)                    445                                                                               HCOCH.sub.3                                                                             CH.sub.2 OCO                                                                               n-butyl                                                                               oil  5.1(S, 2H); 7.55(S, 1H)                    446                                                                               HCOCH.sub.3                                                                             CH.sub.2 OCO                                                                               n-propyl                                                                              oil  5.1(S, 2H); 7.55(S, 1H)                    447                                                                               HCOCH.sub.3                                                                             CH.sub.2 OCO                                                                               n-ethyl                                                                               oil  5.1(S, 2H); 7.55(S, 1H)                    448                                                                               HCOCH.sub.3                                                                             CH.sub.2 OCOCH.sub.2                                                                       phenyl 59-60                                           449                                                                               HCOCH.sub.3                                                                             CH.sub.2 OCO(CH.sub.2).sub.2                                                               phenyl oil  5.1(S, 2H); 7.55(S, 1H)                    450                                                                               HCOCH.sub.3                                                                             CH.sub.2 OCO(CH.sub.2).sub.3                                                               phenyl oil  5.1(S, 2H); 7.55(S, 1H)                    451                                                                               HCOCH.sub.3                                                                             O(CH.sub.2).sub.2 O                                                                        A      oil  4.1(t, J=5Hz, 2H); 7.55(S, 1H)             452                                                                               HCOCH.sub.3                                                                             O(CH.sub.2).sub.3 O                                                                        H      oil  4.1(t, J=6Hz, 2H); 7.55(S, 1H)             453                                                                               HCOCH.sub.3                                                                             O(CH.sub.2).sub. 4 O                                                                       H      oil  4.0(t, J=6Hz, 2H); 7.55(S, 1H)             454                                                                               HCOCH.sub.3                                                                             O(CH.sub.2).sub.8 O                                                                        H      54-55                                           __________________________________________________________________________

                  TABLE 4                                                          ______________________________________                                          ##STR31##                                                                     No.  X.sub.m            mp       NMR: δ(ppm)                             ______________________________________                                          1   2-F                oil      5.15(S, 2H);                                                                   7.55(S, 1H)                                    2   3-F                                                                        3   4-F                                                                        4   2,4-F.sub.2                                                                5   2,4,6-F.sub.3                                                              6   2,3,4,5,6-F.sub.5                                                          7   2,3-F.sub.2                                                                8   2-Cl               oil      5.15(S, 2H);                                                                   7.55(S, 1H)                                    9   3-Cl               oil      5.05(S, 2H);                                                                   7.55(S, 1H)                                    10  4-Cl               64-67                                                   11  2,3-Cl.sub.2       106-108                                                 12  2,4-Cl.sub.2                                                               13  2,5-Cl.sub.2                                                               14  2,6-Cl.sub.2                                                              205  3,4-Cl.sub.2                                                               16  3,5-Cl.sub.2                                                               17  2,3,4-Cl.sub.3                                                             18  2,3,5-Cl.sub.3                                                             19  2,3,6-Cl.sub.3                                                             20  2,4,5-Cl.sub.3                                                             21  2,4,6-Cl.sub.3                                                             22  3,4,5-Cl.sub.3                                                             23  2,3,4,6-Cl.sub.4                                                           24  2,3,5,6-Cl.sub.4                                                           25  2,3,4,5,6-Cl.sub.5                                                         26  2-Br                                                                       27  3-Br                                                                       28  4-Br                                                                       29  2,4-Br.sub.2                                                               30  2,5-Br.sub.5                                                               31  2,6-Br.sub.2                                                               32  2,4,6-Br.sub.3                                                              33 2,3,4,5,6-Br.sub.5                                                         34  2-J                                                                        35  3-I                                                                        36  4-I                                                                        37  2,4-I.sub.2                                                                38  2-Cl, 3-F                                                                  39  2-Cl, 4-F                                                                  40  2-Cl, 5-F                                                                  41  2-Cl, 6-F                                                                  42  2-Cl, 3-Br                                                                 43  2-Cl, 4-Br                                                                 44  2-Cl, 6-Br                                                                 45  2-Cl, 6-Br                                                                 46  2-Br, 3-Cl                                                                 47  2-Br, 4-Cl                                                                 48  2-Br, 5-Cl                                                                 49  2-Br, 3-F                                                                  50  2-Br, 4-F                                                                  51  2-Br, 5-F                                                                  52  2-Br, 6-F                                                                  53  2-F, 3-Cl                                                                  54  2-F, 4-Cl                                                                  55  2-F, 5-Cl                                                                  56  3-Cl, 4-F                                                                  57  3-Cl, 5-F                                                                  58  3-Cl, 4-Br                                                                 59  3-Cl, 5-Br                                                                 60  3-F, 4-Cl                                                                  61  3-F, 4-Br                                                                  62  3-Br, 4-Cl                                                                 63  3-Br, 4-F                                                                  64  2,6-Cl.sub.2, 4-Br                                                         65  2-CH.sub.3         78-79                                                   66  3-CH.sub.3         88-90                                                   67  4-CH.sub.3         116-118                                                 68  2,3-(CH.sub.3).sub.2                                                                              69-71                                                   69  2,4-(CH.sub.3).sub.2                                                                              79-82                                                   70  2,5-(CH.sub.3).sub.2                                                                              82-84                                                   71  2,6-(CH.sub.3).sub.2                                                                              59-61                                                   72  3,4-(CH.sub.3).sub.2                                                                              83-84                                                   73  3,5-(CH.sub.3).sub.2                                                                              76-77                                                   74  3,5-(CH.sub.3).sub.2                                                       75  2,3,4-(CH.sub.3).sub.3                                                     76  2,3,6-(CH.sub.3).sub.3                                                     77  2,4,5-(CH.sub.3).sub.3                                                     78  2,3,6-(CH.sub.3).sub.3                                                     79  2,3,4-(CH.sub.3).sub.3                                                     80  2,3,4,6-(CH.sub.3).sub.4                                                   81  2,3,5,6-(CH.sub.3).sub.4                                                   82  2,3,4,5,6-(CH.sub.3).sub.5                                                 83  2-C.sub.2 H.sub.5                                                          84  3-C.sub.2 H.sub.5                                                          85  4-C.sub.2 H.sub.5                                                          86  2,4-(C.sub.2 H.sub.5).sub.2                                                87  2,6-(C.sub.2 H.sub.5).sub.2                                                88  3,5-(C.sub.2 H.sub.5).sub.2                                                89  2,4,6-(C.sub.2 H.sub.5).sub.3                                              90  2-n-C.sub.3 H.sub.7                                                        91  3-n-C.sub.3 H.sub.7                                                        92  4-n-C.sub.3 H.sub.7                                                        93  2-i-C.sub.3 H.sub.7                                                        94  3-i-C.sub.3 H.sub.7                                                        95  4-i-C.sub.3 H.sub.7                                                        96  2,4-(i-C.sub.3 H.sub.7).sub.2                                              97  2,6-(i-C.sub.3 H.sub.7).sub.2                                              98  3,5-(i-C.sub.3 H.sub.7).sub.2                                              99  2,4,6-(i-C.sub.3 H.sub.7).sub.3                                           100  2-SC.sub.4 H.sub.9                                                        101  3-SC.sub.4 H.sub.9                                                        102  4-SC.sub.4 H.sub.9                                                        103  2-t-C.sub.4 H.sub.9                                                       104  3-t-C.sub.4 H.sub.9                                                       105  4-t-C.sub.4 H.sub.9                                                       106  2,3-(t-C.sub.4 H.sub.9).sub. 2                                            107  2,4-(t-C.sub.4 H.sub.9).sub.2                                             108  2,5-(t-C.sub.4 H.sub.9).sub.2                                             109  2,6-(t-C.sub.4 H.sub.9).sub.2                                             110  3,4-(t-C.sub.4 H.sub.9).sub.2                                             111  2,4,6-(t-C.sub.4 H.sub.9).sub.3                                           112  4-n-C.sub.9 H.sub.19                                                      113  4-n-C.sub.12 H.sub.25                                                     114  3-n-C.sub.15 H.sub.31                                                     115  4-(1,1,3,3-tetramethylbutyl)                                              116  4-(2,4,4-trimethylpropyl)                                                 117  2-t-C.sub.4 H.sub.9, 4-CH.sub.3                                           118  2-t-C.sub.4 H.sub.9, 5-CH.sub.3                                           119  2,6-(t-C.sub.4 H.sub.9), 4-CH.sub.3                                       120  2-CH.sub.3, 4-t-C.sub.4 H.sub.9                                           121  2-CH.sub.3, 6-t-C.sub.4 H.sub.9                                           122  2-CH.sub.3, 4-i-C.sub.3 H.sub.7                                           123  2-CH.sub.3, 5-i-C.sub.3 H.sub.7                                           124  3-CH.sub.3, 4-i-C.sub.3 H.sub.7                                           125  2-i-C.sub.3 H.sub.7, 5 CH.sub.3                                           126  2,4-(t-C.sub.4 H.sub.9), 6-i-C.sub.3 H.sub.7                              127  2-allyl                                                                   128  3-allyl                                                                   129  4-allyl                                                                   130  2-allyl, 6-CH.sub.3                                                       131  2-cyclo-C.sub.6 H.sub.11                                                  132  3-cyclo-C.sub.6 H.sub.11                                                  133  4-cyclo-C.sub.6 H.sub.11                                                  134  2,4-(cyclo-C.sub.6 H.sub.11).sub.2, 6-CH.sub.3                            135  2-CH.sub.3, 4-cyclo-C.sub.6 H.sub.11                                      136  2-CH.sub.2 C.sub.6 H.sub.5                                                137  3-CH.sub.2 C.sub.6 H.sub.5                                                138  4-CH.sub.2 C.sub.6 H.sub.5                                                139  2-CH.sub.2 C.sub.6 H.sub.5, 4-CH.sub.3                                    140  2-CH.sub.3, 4-CH.sub.2 C.sub.6 H.sub.5                                    141  2-C.sub.6 H.sub.5                                                         142  3-C.sub.6 H.sub.5                                                         143  4-C.sub.6 H.sub.5  149-150                                                144  4-(2-i-C.sub.3 H.sub.7 C.sub.6 H.sub.4)                                   145  4-C.sub.6 H.sub.5, 2,6-(CH.sub.3).sub.2                                   146  2-Cl, 4-C.sub.6 H.sub.5                                                   147  2-Br, 4-C.sub.6 H.sub.5                                                   148  2-C.sub.6 H.sub.5, 4-Cl                                                   149  2-C.sub.6 H.sub.5, 4-Br                                                   150  2-CH.sub.2 C.sub.6 H.sub.5, 4-Cl                                          151  2-CH.sub.2 C.sub.6 H.sub.5, 4-Br                                          152  2-Cl, 4-CH.sub.2 C.sub.6 H.sub.5                                          153  2-Br, 4-CH.sub.2 C.sub.6 H.sub.5                                          154  2-cyclo-C.sub.6 H.sub.11, 4-Cl                                            155  2-cyclo-C.sub.6 H.sub.11, 4-Br                                            156  2-Cl, 4-cyclo-C.sub.6 H.sub.11                                            157  2-Br, 4-cyclo-C.sub.6 H.sub.11                                            158  2-OCH.sub.3        oil      5.15(S, 2H);                                                                   7.55(S, 1H)                                   159  3-OCH.sub.3        oil      5.05(S, 2H);                                                                   7.55(S, 1H)                                   200  4-OCH.sub.3        107-109                                                161  2-OC.sub.2 H.sub.5                                                        162  3-OC.sub.2 H.sub.5                                                        163  4-OC.sub.2 H.sub.5                                                        164  2-O-n-C.sub.3 H.sub.7                                                     165  3-O-n-C.sub.3 H.sub.7                                                     166  4-O-n-C.sub.3 H.sub.7                                                     167  2-O-i-C.sub.3 H.sub.7                                                     168  3-O-i-C.sub.3 H.sub.7                                                     169  4-O-i-C.sub.3 H.sub.7                                                     170  2-O-n-C.sub.6 H.sub.13                                                    171  3-O-n-C.sub.6 H.sub.13                                                    172  4-O-n-C.sub.6 H.sub.13                                                    173  2-O-n-C.sub.8 H.sub.17                                                    174  3-O-n-C.sub.8 H.sub.17                                                    175  4-O-n-C.sub.8 H.sub.17                                                    176  2-OCH.sub.2 C.sub.6 H.sub.5                                               177  3-OCH.sub.2 C.sub.6 H.sub.5                                               178  4-OCH.sub.2 C.sub.6 H.sub.5                                               179  2-O(CH.sub.2).sub.3 C.sub.6 H.sub.5                                       180  3-O(CH.sub.2).sub.3 C.sub.6 H.sub.5                                       181  4-O(CH.sub.2).sub.3 C.sub.6 H.sub.5                                       182  2,4-(OCH.sub.3).sub.2                                                     183  2-CF.sub.3         oil      5.2(S, 2H);                                                                    7.55(S, 1H)                                   184  3-CF.sub.3                                                                185  4-CF.sub.3                                                                186  2-OCF.sub.3                                                               187  3-OCF.sub.3                                                               188  4-OCF.sub.3                                                               189  3-OCH.sub.2 CHF.sub.2                                                     190  2-NO.sub.2                                                                191  3-NO.sub.2                                                                192  4-NO.sub.2                                                                193  2-CN                                                                      194  3-CN                                                                      195  4-CN                                                                      196  2-CH.sub.3, 3-Cl                                                          197  2-CH.sub.3, 4-Cl                                                          198  2-CH.sub.3, 5-Cl                                                          199  2-CH.sub.3, 6-Cl                                                          200  2-CH.sub.3, 3-F                                                           201  2-CH.sub.3, 4-F                                                           202  2-CH.sub.3, 5-F                                                           203  2-CH.sub.3, 6-F                                                           204  2-CH.sub.3, 3-Br                                                          205  2-CH.sub.3, 4-Br                                                          206  2-CH.sub.3, 5-Br                                                          207  2-CH.sub.3, 6-Br                                                          208  2-Cl, 3-CH.sub.3                                                          209  2-Cl, 4-CH.sub.3                                                          210  2-Cl, 5-CH.sub.3                                                          211  2-F, 3-CH.sub.3                                                           212  2-F, 4-CH.sub.3                                                           213  2-F, 5-CH.sub.3                                                           214  2-Br, 3-CH.sub.3                                                          215  2-Br, 4-CH.sub.3                                                          216  2-Br, 5-CH.sub.3                                                          217  3-CH.sub.3, 4-Cl                                                          218  3-CH.sub.3, 5-Cl                                                          219  3-CH.sub.3, 4-F                                                           220  3-CH.sub.3, 4-Br                                                          221  3-CH.sub.3, 4-Br                                                          222  3-CH.sub.3, 5-Br                                                          223  3-F, 4-CH.sub.3                                                           224  3-Cl, 4-CH.sub.3                                                          225  3-Br, 4-CH.sub.3                                                          226  2-Cl, 4,5-(CH.sub.3).sub.2                                                227  2-Br, 4,5-(CH.sub.3).sub.2                                                228  2-Cl, 3,5-(CH.sub.3).sub.2                                                229  2-Br, 3,5-(CH.sub.3).sub.2                                                230  2,6-Cl.sub.2, 4-CH.sub.3                                                  231  2,6-F.sub.2, 4-CH.sub.3                                                   232  2,6-Br.sub.2, 4-CH.sub.3                                                  233  2,4-Cl.sub.2, 6-CH.sub.3                                                  234  2,4-F.sub.2, 6-CH.sub.3                                                   235  2,4-Br.sub.2, 6-CH.sub.3                                                  236  2,6-(CH.sub.3).sub.2, 4-F                                                 237  2,6-(CH.sub.3).sub.2, 4-Cl                                                238  2,6-(CH.sub.3).sub.2, 4-Br                                                239  3,5-(CH.sub.3).sub.2, 4-F                                                 240  3,5-(CH.sub.3).sub.2, 4-Cl                                                241  3,5-(CH.sub.3).sub.2, 4-Br                                                242  2,3,6-(CH.sub.3).sub.3, 4-F                                               243  2,3,6-(CH.sub.3).sub.3, 4-Cl                                              244  2,3,6-(CH.sub.3).sub.3, 4-Br                                              245  2,4-(CH.sub.3).sub.2, 6-F                                                 246  2,4-(CH.sub.3).sub.2, 6-Cl                                                247  2,4-(CH.sub.3).sub.2, 6-Br                                                248  2-i-C.sub.3 H.sub.7, 4-Cl, 5-CH.sub.3                                     249  2-Cl, 4-NO.sub.2                                                          250  2-NO.sub.2, 4-Cl                                                          251  2-OCH.sub.3, 5-NO.sub.2                                                   252  2,4-Cl.sub.2, 5-NO.sub.2                                                  253  2,4-Cl.sub.2, 6-NO.sub.2                                                  254  2,6-Cl.sub.2, 4-NO.sub.2                                                  255  2,6-Br.sub.2, 4-NO.sub.2                                                  256  2,6-I.sub.2, 4-NO.sub.2                                                   257  2-CH.sub.3, 5-i-C.sub.3 H.sub.7, 4-Cl                                     258  2-C.sub.6 H.sub.5 O                                                       259  3-C.sub.6 H.sub.5 O                                                       260  4-C.sub.6 H.sub.5 O                                                       261  2-CHNOCH.sub.3     oil      5.1(s, 2H);                                                                    7.6(s, 1H)                                    262  3-CHNOCH.sub.3     65-68                                                  263  4-CHNOCH.sub.3     69-72                                                  264  2-CHNOC.sub.2 H.sub.5                                                     265  3-CHNOC.sub.2 H.sub.5                                                     266  4-CHNOC.sub.2 H.sub.5                                                     267  2-CHNO(n-C.sub.3 H.sub.7)                                                 268  3-CHNO(n-C.sub.3 H.sub.7)                                                 269  4-CHNO(n-C.sub.3 H.sub.7)                                                 270  2-CHNO(i-C.sub.3 H.sub.7)                                                 271  3-CHNO(i-C.sub.3 H.sub.7)                                                 272  4-CHNO(i-C.sub.3 H.sub.7)                                                 273  2-CHNO(n-C.sub.6 H.sub. 13)                                                                       oil      5.1(s, 2H);                                                                    7.6(s, 1H)                                    274  3-CHNO(n-C.sub.6 H.sub.13)                                                                        oil      5.1(s, 2H);                                                                    7.6(s, 1H)                                    275  4-CHNO(n-C.sub.6 H.sub.13)                                                                        oil      5.1(s, 2H);                                                                    7.6(s, 1H)                                    276  2-CHNO(n-C.sub.8 H.sub.17)                                                277  3-CHNO(n-C.sub.8 H.sub.17)                                                278  4-CHNO(n-C.sub.8 H.sub.17)                                                279  2-CHNOCH.sub.2 (C.sub.6 H.sub.5)                                                                  oil      5.1(s, 2H).                                                                    7.55(s, 1H)                                   280  3-CHNOCH.sub.2 (C.sub.6 H.sub.5)                                                                  oil      5.1(s, 2H);                                                                    7.6(s, 1H)                                    281  4-CHNOCH.sub.2 (C.sub.6 H.sub.5)                                                                  93-96                                                  282  2-CO.sub.2 CH.sub.3                                                                               65-66                                                  283  3-CO.sub.2 CH.sub.3                                                                               69-72                                                  284  4-CO.sub.2 CH.sub.3                                                                               106-107                                                285  2-CO.sub.2 (C.sub.2 H.sub.5)                                              286  3-CO.sub.2 (C.sub.2 H.sub.5)                                              287  4-CO.sub.2 (C.sub.2 H.sub.5)                                              288  2-CO.sub.2 (n-C.sub.3 H.sub.7)                                            289  3-CO.sub.2 (n-C.sub.3 H.sub.7)                                            290  4-CO.sub.2 (n-C.sub.3 H.sub.7)                                            291  2-CO.sub.2 (i-C.sub.3 H.sub.7)                                            292  3-CO.sub.2 (i-C.sub.3 H.sub.7)                                            293  4-CO.sub.2 (i-C.sub.3 H.sub.7)                                            294  2-CO.sub.2 (n-C.sub.6 H.sub.13)                                           295  3-CO.sub.2 (n-C.sub.6 H.sub.13)                                           296  4-CO.sub.2 (n-C.sub.6 H.sub.13)                                           297  2-CO.sub.2 (n-C.sub.8 H.sub.17)                                           298  3-CO.sub.2 (n-C.sub.8 H.sub.17)                                           299  4-CO.sub.2 (n-C.sub.8 H.sub.17)                                           300  2-CHNOCH.sub.2 CHCH.sub.2                                                                         oil      5.1(s, 2H);                                                                    7.6(s, 1H)                                    301  3-CHNOCH.sub.2 CHCH.sub.2                                                                         oil      5.1(s, 2H);                                                                    7.6(s, 1H)                                    302  4-CHNOCH.sub.2 CHCH.sub.2                                                                         oil      5.1(s, 2H);                                                                    7.6(s, 1H)                                    303  2-CHNO(CH.sub.2).sub.3 (C.sub.6 H.sub.5)                                  304  3-CHNO(CH.sub.2).sub.3 (C.sub.6 H.sub.5)                                  305  4-CHNO(CH.sub.2).sub.3 (C.sub.6 H.sub.5)                                  306  2-CH.sub.2 OCH.sub.3                                                      307  3-CH.sub.2 OCH.sub.3                                                      308  4-CH.sub.2 OCH.sub.3                                                      309  2-CH.sub.2 O(C.sub.2 H.sub.5)                                             310  3-CH.sub.2 O(C.sub.2 H.sub.5)                                             311  4-CH.sub.2 O(C.sub.2 H.sub.5)                                             312  2-CH.sub.2 O(n-C.sub.3 H.sub.7)                                           313  3-CH.sub.2 O(n-C.sub.3 H.sub.7)                                           314  4-CH.sub.2 O(n-C.sub.3 H.sub.7)                                           315  2-CH.sub.2 O(i-C.sub.3 H.sub.7)                                           316  3-CH.sub.2 O(i-C.sub.3 H.sub.7)                                           317  4-(CH.sub.2 O(i-C.sub.3 H.sub.7)                                          318  2-CH.sub.2 O(n-C.sub.6 H.sub.13)                                          319  3-CH.sub.2 O(n-C.sub.6 H.sub.13)                                          320  4-CH.sub.2 O(n-C.sub.6 H.sub.13)                                          321  2-CH.sub.2 O(n-C.sub.8 H.sub.17)                                          322  3-CH.sub.2 O(n-C.sub.8 H.sub.17)                                          323  4-CH.sub.2 O(n-C.sub.8 H.sub.17)                                          324  2-CH.sub.2 OCH.sub.2 (C.sub.6 H.sub.5)                                    325  3-CH.sub.2 OCH.sub.2 (C.sub.6 H.sub.5)                                    326  4-CH.sub.2 OCH.sub.2 (C.sub.6 H.sub.5)                                    327  2-CH.sub.2 O(CH.sub.2).sub.3                                              328  3-CH.sub.2 O(CH.sub.2).sub.3 (C.sub.6 H.sub.5)                            329  4-CH.sub.2 O(CH.sub.2).sub.3 (C.sub.6 H.sub.5)                            330  2-CHO              95-96                                                  331  3-CHO                                                                     332  4-CHO              123-125                                                333  2-CH.sub.3 -4-CHNO-allyl                                                                          oil      5.1(s, 2H);                                                                    7.55(s, 1H)                                   334  2-CH.sub.3 -5-CHNO-allyl                                                                          oil      5.1(s, 2H);                                                                    7.6(s, 1H)                                    335  2-CH.sub.3 -6-CHNO-allyl                                                                          oil      4.85(s, 2H);                                                                   7.6(s, 1H)                                    336  3-CH.sub.3 -6-CHNO-allyl                                                                          97-98                                                  337  4-CH.sub.3 -6-CHNO-allyl                                                                          oil      5.05(s, 2H);                                                                   7.6(s, 1H)                                    ______________________________________                                    

                  TABLE 5                                                          ______________________________________                                          ##STR32##                                                                     No.   X.sub.m        mp      NMR: δ (ppm)                                ______________________________________                                          1    2-F                                                                       2    3-F                                                                       3    4-F                                                                       4    2,4-F.sub.2                                                               5    2,4,6-F.sub.3                                                             6    2,3,4,5,6-F.sub.5                                                         7    2,3-F.sub.2                                                               8    2-Cl                                                                      9a)  3-Cl;          oil     3.95(s, 3H); 4.05(s, 3H);                               non-polar isomer       5.05(s, 2H)                                        9b   3-Cl;          82-85                                                           polar isomer                                                              10   4-Cl                                                                      11   2,3-Cl.sub.2                                                              12   2,4-Cl.sub.2                                                              13   2,5-Cl.sub.2                                                              14   2,6-Cl.sub.2                                                              15   3,4-Cl.sub.2                                                              16   3,5-Cl.sub.2                                                              17   2,3,4-Cl.sub.3                                                            18   2,3,5-Cl.sub.3                                                            19   2,3,6-Cl.sub.3                                                            20   2,4,5-Cl.sub.3                                                            21   2,4,6-Cl.sub.3                                                            22   3,4,5-Cl.sub.3                                                            23   2,3,4,6-Cl.sub.4                                                          24   2,3,5,6-Cl.sub.4                                                          25   2,3,4,5,6-Cl.sub.5                                                        26   2-Br                                                                      27   3-Br                                                                      28   4-Br                                                                      29   2,4-Br.sub.2                                                              30   2,5-Br.sub.5                                                              31   2,6-Br.sub.2                                                              32   2,4,6-Br.sub.3                                                            33   2,3,4,5,6-Br.sub.5                                                        34   2-I                                                                       35   3-I                                                                       36   4-I                                                                       37   2,4-I.sub.2                                                               38   2-Cl, 3-F                                                                 39   2-Cl, 4-F                                                                 40   2-Cl, 5-F                                                                 41   2-Cl, 6-F                                                                 42   2-Cl, 3-Br                                                                43   2-Cl, 4-Br                                                                44   2-Cl, 6-Br                                                                45   2-Cl, 6-Br                                                                46   2-Br, 3-Cl                                                                47   2-Br, 4-Cl                                                                48   2-Br, 5-Cl                                                                49   2-Br, 3-F                                                                 50   2-Br, 4-F                                                                 51   2-Br, 5-F                                                                 52   2-Br, 6-F                                                                 53   2-F, 3-Cl                                                                 54   2-F, 4-Cl                                                                 55   2-F, 5-Cl                                                                 56   3-Cl, 4-F                                                                 57   3-Cl, 5-F                                                                 58   3-Cl, 4-Br                                                                59   3-Cl, 5-Br                                                                60   3-F, 4-Cl                                                                 61   3-F, 4-Br                                                                 62   3-Br, 4-Cl                                                                63   3-Br, 4-F                                                                 64   2,6-Cl.sub.2, 4-Br                                                        65a) 2-CH.sub.3 :non-polar                                                                         oil     3.95(S, 3H); 4.05(S, 3H);                               isomer                 5.05(S, 2H)                                        65b) 2-CH.sub.3 :polar isomer                                                                       99-100                                                    66a) 3-CH.sub.3 :non-polar                                                                         oil     3.9(S, 3H); 4.0(S, 3H);                                 isomer                 5.05(S, 2H)                                        66b) 3-CH.sub.3 :polar isomer                                                                      51-54                                                      67a) 4-CH.sub.3 :non-polar                                                                         oil     3.9(S, 3H); 4.0(S, 3H);                                 isomer                 5.0(S, 2H)                                         67b) 4-CH.sub.3 :polar isomer                                                                      102-103                                                    68a) non-polar isomer;                                                                             oil     3.95(s, 3H); 4.05(s, 3H);                               2,3-(CH.sub.3 ).sub.2  5.05(s, 2H)                                        68b) polar isomer;  86-89                                                           2,3-(CH.sub.3).sub.2                                                      69a) non-polar isomer;                                                                             oil     3.95(s, 3H); 4.05(s, 3H);                               2,4-(CH.sub.3).sub.2   5.05(s, 2H)                                        69b) polar isomer;  oil     3.90(s, 3H); 4.05(s, 3H);                               2,4-(CH.sub.3).sub.2   5.05(s, 2H)                                        70a) non-polar isomer;                                                                             oil     3.95(s, 3H); 4.05(s, 3H);                               2,5-(CH.sub.3).sub.2   5.05(s, 2H)                                        70b) polar isomer;  85-88                                                           2,5-(CH.sub.3).sub.2                                                      71a) non-polar isomer;                                                                             oil     3.95(s, 3H); 4.05(s, 3H);                               2,6-(CH.sub.3).sub.2   4.80(s, 2H)                                        71b) polar isomer;  79-81                                                           2,6-(CH.sub.3).sub.2                                                      72a) non-polar isomer;                                                                             oil     3.95(s, 3H); 4.05(s, 3H);                               3,4-(CH.sub.3).sub.2   5.05(s, 2H)                                        72b) polar isomer;  oil     3.90(s, 3H); 4.05(s, 3H);                               3,4-(CH.sub.3).sub.2   5.05(s, 2H)                                        73a) non-polar isomer;                                                                             oil     3.95(s, 3H); 4.05(s, 3H);                               3,5-(CH.sub.3).sub.2   5.05(s, 2H)                                        73b) polar isomer;  oil     3.90(s, 3H); 4.05(s, 3H);                               3,5-(CH.sub.3).sub.2   5.05(s, 2H)                                        74   3,5-(CH.sub.3).sub.2                                                      75   2,3,4-(CH.sub.3).sub.3                                                    76   2,3,6-(CH.sub.3).sub.3                                                    77   2,4,5-(CH.sub.3).sub.3                                                    78   2,4,6-(CH.sub.3).sub.3                                                    79   3,4,5-(CH.sub.3).sub.3                                                    80   2,3,4,6-(CH.sub.3).sub.4                                                  81   2,3,5,6,-(CH.sub.3).sub.4                                                 82   2,3,4,5,6-(CH.sub.3).sub.5                                                83   2-C.sub.2 H.sub.5                                                         84   3-C.sub.2 H.sub.5                                                         85   4-C.sub.2 H.sub.5                                                         86   2,4-(C.sub.2 H.sub.5).sub.2                                               87   2,6-(C.sub.2 H.sub.5).sub.2                                               88   3,5-(C.sub.2 H.sub.5).sub.2                                               89   2,4,6-(C.sub.2 H.sub.5).sub.3                                             90   2-n-C.sub.3 H.sub.7                                                       91   3-n-C.sub.3 H.sub.7                                                       92   4-n-C.sub.3 H.sub.7                                                       93   2-i-C.sub.3 H.sub.7                                                       94   3-i-C.sub.3 H.sub.7                                                       95   4-i-C.sub.3 H.sub.7                                                       96   2,4-(i-C.sub.3 H.sub.7).sub.2                                             97   2,6-(i-C.sub.3 H.sub.7).sub.2                                             98   3,5-(i-C.sub.3 H.sub.7).sub.2                                             99   2,4,6-(i-C.sub.3 H.sub.7).sub.3                                          100   2-S-C.sub.4 H.sub.9                                                      101   3-S-C.sub.4 H.sub.9                                                      102   4-S-C.sub.4 H.sub.9                                                      103   2-t-C.sub.4 H.sub.9                                                      104   3-t-C.sub.4 H.sub.9                                                      105   4-t-C.sub.4 H.sub.9                                                      106   2,3-(t-C.sub.4 H.sub.9).sub.2                                            107   2,4-(t-C.sub.4 H.sub.9).sub.2                                            108   2,5-(t-C.sub.4 H.sub.9).sub.2                                            109   2,6-(t-C.sub.4 H.sub.9).sub.2                                            110   3,4-(t-C.sub.4 H.sub.9).sub.2                                            111   2,4,6-(t-C.sub.4 H.sub.9).sub.3                                          112   4-n-C.sub.9 H.sub.19                                                     113   4-n-C.sub.12 H.sub.25                                                    114   3-n-C.sub.15 H.sub.31                                                    115   4-(1,1,3,3-tetramethyl-                                                        butyl)                                                                   116   4-(2,4,4-trimethylpropyl                                                 117   2-t-C.sub.4 H.sub.9, 4-CH.sub.3                                          118   2-t-C.sub.4 H.sub.9, 5-CH.sub.3                                          119   2,6-(t-C.sub.4 H.sub.9), 4-CH.sub.3                                      120   2-CH.sub.3, 4-t-C.sub.4 H.sub.9                                          121   2-CH.sub.3, 6-t-C.sub.4 H.sub.9                                          122   2-CH.sub.3, 4-i-C.sub.3 H.sub.7                                          123   2-CH.sub.3, 5-i-C.sub.3 H.sub.7                                          124   3-CH.sub.3, 4-i-C.sub.3 H.sub.7                                          125   2-i-C.sub.3 H.sub.7, 5 CH.sub.3                                          126   2,4-(t-C.sub.4 H.sub.9), 6-i-C.sub.3 H.sub.7                             127   2-allyl                                                                  128   3-allyl                                                                  129   4-allyl                                                                  130   2-allyl, 6-CH.sub.3                                                      131   2-cyclo-C.sub.6 H.sub.11                                                 132   3-cyclo-C.sub.6 H.sub.11                                                 133   4-cyclo-C.sub.6 H.sub.11                                                 134   2,4-(cyclo-C.sub.6 H.sub.11).sub.2,                                            6-CH.sub.3                                                               135   2-CH.sub.3, 4-cyclo-C.sub.6 H.sub.11                                     136   2-CH.sub.2, C.sub.6 H.sub.5                                              137   3-CH.sub.2, C.sub.6 H.sub.5                                              138   4-CH.sub.2, C.sub.6 H.sub.5                                              139   2-CH.sub.2 C.sub.6 H.sub.5, 4-CH.sub.3                                   140   2-CH.sub. 3, 4-CH.sub.2 C.sub.6 H.sub.5                                  141   2-C.sub.6 H.sub.5                                                        142   3-C.sub.6 H.sub.5                                                        143   4-C.sub.6 H.sub.5                                                        144   4-(2-i-C.sub.3 H.sub.7 C.sub.6 H.sub.4)                                  145   4-C.sub.6 H.sub.5, 2,6-(CH.sub.3).sub.2                                  146   2-Cl, 4-C.sub.6 H.sub.5                                                  147   2-Br, 4-C.sub.6 H.sub.5                                                  148   2-C.sub.6 H.sub.5, 4-Cl                                                  149   2-C.sub.6 H.sub.5, 4-Br                                                  150   2-CH.sub.2 C.sub.6 H.sub.5, 4-Cl                                         151   2-CH.sub.2 C.sub.6 H.sub.5, 4-Br                                         152   2-Cl, 4-CH.sub.2 C.sub.6 H.sub.5                                         153   2-Br, 4-CH.sub.2 C.sub.6 H.sub.5                                         154   2-cyclo-C.sub.6 H.sub.11, 4-Cl                                           155   2-cyclo-C.sub.6 H.sub.11, 4-Br                                           156   2-Cl, 4-cyclo-C.sub.6 H.sub.11                                           157   2-Br, 4-cyclo-C.sub.6 H.sub.11                                           158a) 2-OCH.sub.3 ;  oil     3.85; 3.90; 5.0(3s, 3H                                  non-polar isomer       in each case); 5.1(s, 2H)                         158b) 2-OCH.sub.3    63-67                                                           polar isomer                                                             159a) 3-OCH.sub.3 ;  oil     3.80; 3,95; 4.05(3s, 3H                                 non-polar isomer       in each case); 5.1(s, 2H)                         159b) 3-OCH.sub.3    35                                                              polar isomer                                                             160a) 4-OCH.sub.3 ;  oil     3.75; 3.95; 4.05(3s, 3H                                 non-polar isomer       in each case); 5.05(s, 2H)                        160b) 4-OCH.sub.3    75-78                                                           polar isomer                                                             161   3-OC.sub.2 H.sub.5                                                       162   3-O-C.sub.2 H.sub.5                                                      163   4-O-C.sub.2 H.sub.7                                                      164   2-O-n-C.sub.3 H.sub.7                                                    165   3-O-n-C.sub.3 H.sub.7                                                    166   4-O-n-C.sub.3 H.sub.7                                                    167   2-O-i-C.sub.3 H.sub.7                                                    168   3-O-i-C.sub.3 H.sub.7                                                    169   4-O-i-C.sub.3 H.sub.7                                                    170   2-O-n-C.sub.6 H.sub.13                                                   171   3-O-n-C.sub.6 H.sub.13                                                   172   4-O-n-C.sub.6 H.sub.13                                                   173   2-O-n-C.sub.8 H.sub.17                                                   174   3-O-n-C.sub.8 H.sub.17                                                   175   4-O-n-C.sub.8 H.sub.17                                                   176   2-O-CH.sub.2 C.sub.6 H.sub.5                                             177   3-O-CH.sub.2 C.sub.6 H.sub.5                                             178   4-O-CH.sub.2 C.sub.6 H.sub.5                                             179   2-O-(CH.sub.2).sub.3 C.sub.6 H.sub.5                                     180   3-O-(CH.sub.2).sub.3 C.sub.6 H.sub.5                                     181   4-O-(CH.sub.2).sub.3 C.sub.6 H.sub.5                                     182   2,4-(OCH.sub.3).sub.2                                                    183   2-CF.sub.3                                                               184   3-CF.sub.3                                                               185   4-CF.sub.3                                                               186   2-OCF.sub.3                                                              187   3-OCF.sub.3                                                              188   4-OCF.sub.3                                                              189   3-OCH.sub.2 CHF.sub.2                                                    190   2-NO.sub.2                                                               191   3-NO.sub.2                                                               192   4-NO.sub.2                                                               193   2-CN                                                                     194   3-CN                                                                     195   4-CN                                                                     196   2-CH.sub.3, 3-Cl                                                         197   2-CH.sub.3, 4-Cl                                                         198   2-CH.sub.3, 5-Cl                                                         199   2-CH.sub.3, 6-Cl                                                         200   2-CH.sub.3, 3-F                                                          201   2-CH.sub. 3, 4-F                                                         202   2-CH.sub.3, 5-F                                                          203   2-CH.sub.3, 6-F                                                          204   2-CH.sub.3, 3-Br                                                         205   2-CH.sub.3, 4-Br                                                         206   2-CH.sub.3, 5-Br                                                         207   2-CH.sub.3, 6-Br                                                         208   2-Cl, 3-CH.sub.3                                                         209   2-Cl, 4-CH.sub.3                                                         210   2-Cl, 5-CH.sub.3                                                         211   2-F, 3-CH.sub.3                                                          212   2-F, 4-CH.sub.3                                                          213   2-F, 5-CH.sub.3                                                          214   2-Br, 3-CH.sub.3                                                         215   2-Br, 4-CH.sub.3                                                         216   2-Br, 5-CH.sub.3                                                         217   3-CH.sub.3, 4-Cl                                                         218   3-CH.sub.3, 5-Cl                                                         219   3-CH.sub.3, 3-F                                                          220   3-CH.sub.3, 4-Br                                                         221   3-CH.sub.3, 4-Br                                                         222   3-CH.sub.3, 5-Br                                                         223   3-F, 4-CH.sub.3                                                          224   3-Cl, 4-CH.sub.3                                                         225   3-Br, 4-CH.sub.3                                                         226   2-Cl, 4,5-(CH.sub.3).sub.2                                               227   2-Br, 4,5-(CH.sub.3).sub.2                                               228   2-Cl, 3,5-(CH.sub.3).sub.2                                               229   2-Br, 3,5-(CH.sub.3).sub.2                                               230   2,6-Cl.sub.2, 4-CH.sub.3                                                 231   2,6-F.sub.2, 4-CH.sub.3                                                  232   2,6-Br.sub.2, 4-CH.sub.3                                                 233   2,4-Cl.sub.2, 6-CH.sub.3                                                 234   2,4-F.sub.2, 6-CH.sub.3                                                  235   2,4-Br.sub.2, 6-CH.sub.3                                                 236   2,6-(CH.sub.3).sub.2, 4-F                                                237   2,6-(CH.sub.3).sub.2, 4-Cl                                               238   2,6-(CH.sub.3).sub.2, 4-Br                                               239   3,5-(CH.sub.3).sub.2, 4-F                                                240   3,5-(CH.sub.3).sub.2, 4-Cl                                               241   3,5-(CH.sub.3).sub.2, 4-Br                                               242   2,3,6-(CH.sub.3).sub.3, 4-F                                              243   2,3,6-(CH.sub.3).sub.3, 4-Cl                                             244   2,3,6-(CH.sub.3).sub.3, 4-Br                                             245   2,4-(CH.sub.3).sub.2, 6-F                                                246   2,4-(CH.sub.3).sub.2, 6-Cl                                               247   2,4-(CH.sub.3).sub.2, 6-Br                                               248   2-i-C.sub.3 H.sub.7, 4-Cl, 5-CH.sub.3                                    249   2-Cl, 4-NO.sub.2                                                         250   2-NO.sub.2, 4-Cl                                                         251   2-OCH.sub.3, 5-NO.sub.2                                                  252   2,4-Cl.sub.2, 5-NO.sub.2                                                 253   2,4-Cl.sub.2, 6-NO.sub.2                                                 254   2,6-Cl.sub.2, 4-NO.sub.2                                                 255   2,6-Br.sub.2, 4-NO.sub.2                                                 256   2,6-I.sub.2, 4-NO.sub.2                                                  257   2-CH.sub.3, 5-i-C.sub.3 H.sub.7, 4-Cl                                    258   2-C.sub.6 H.sub.5 O                                                      259   3-C.sub.6 H.sub.5 O                                                      260   4-C.sub.6 H.sub.5 O                                                      261   2-CHNOCH.sub.3                                                           262   3-CHNOCH.sub.3                                                           263   4-CHNOCH.sub.3 ;                                                         264   2-CHNOC.sub.2 H.sub.5                                                    265   3-CHNOC.sub.2 H.sub.5                                                    266   4-CHNOC.sub.2 H.sub.5                                                    267   2-CHNO(n-C.sub.3 H.sub.7)                                                268   3-CHNO(n-C.sub.3 H.sub.7)                                                269   4-CHNO(n-C.sub.3 H.sub.7)                                                270a) 2-CHNO(n-C.sub.4 H.sub.9);                                                                    oil     3.95(s, 3H); 4.05(s, 3H);                               non-polar isomer       5.1(s, 2H)                                        270b) 2-CHNO(n-C.sub.4 H.sub.9):                                                                    oil     3.90(s, 3H); 4.05(s, 3H);                               polar isomer           5.1(s, 2H)                                        271a) 3-CHNO(n-C.sub.4 H.sub.9):                                                                    oil     3.95(s, 3H); 4.05(s, 3H);                               non-polar isomer       5.1(s, 2H)                                        271b) 3-CHNO(n-C.sub.4 H.sub.9):                                                                    oil     3.90(s, 3H); 4.05(s, 3H);                               polar isomer           5.1(s, 2H)                                        272a) 4-CHNO(n-C.sub.4 H.sub.9):                                                                    oil     3.95(s, 3H); 4.05(s, 3H);                               non-polar isomer       5.05(s, 2H)                                       272b) 4-CHNO(n-C.sub.4 H.sub.9):                                                                    88-89                                                           polar isomer                                                             273a) 2-CHNO(n-C.sub.6 H.sub.13):                                                                   oil     3.95(s, 3H); 4.05(s, 3H);                               non-polar isomer       5.1(s, 2H)                                        273b) 2-CHNO(n-C.sub.6 H.sub.13):                                                                   oil     3.90(s, 3H); 4.05(s, 3H);                               polar isomer           5.1(s, 2H)                                        274a) 3-CHNO(n-C.sub.6 H.sub.13):                                                                   oil     3.95(s, 3H); 4.05(s, 3H);                               non-polar isomer       5.1(s, 2H)                                        274b) 3-CHNO(n-C.sub.6 H.sub.13):                                                                   oil     3.90(s, 3H); 4.05(s, 3H);                               polar isomer           5.1(s, 2H)                                        275a) 4-CHNO(n-C.sub.6 H.sub.13):                                                                   oil     3.95(s, 3H); 4.05(s, 3H);                               non-polar isomer       5.1(s, 2H)                                        275b) 4-CHNO(n-C.sub.6 H.sub.13):                                                                   77-80                                                           polar isomer                                                             276   2-CHNO(n-C.sub.8 H.sub.17)                                               277   3-CHNO(n-C.sub.8 H.sub.17)                                               278   4-CHNO(n-C.sub.8 H.sub.17)                                               279   2-CHNOCH.sub.2 (C.sub.6 H.sub.5)                                         280   3-CHNOCH.sub. 2 (C.sub.6 H.sub.5)                                        281   4-CHNOCH.sub.2 (C.sub.6 H.sub.5)                                         282   2-CO.sub.2 CH.sub.3                                                      283   3-CO.sub.2 CH.sub.3                                                      284   4-CO.sub.2 CH.sub.3                                                      285   2-CO.sub.2 (C.sub.2 H.sub.5)                                             286   3-CO.sub.2 (C.sub.2 H.sub.5)                                             287   4-CO.sub.2 (C.sub.2 H.sub.5)                                             288   2-CO.sub.2 (n-C.sub.3 H.sub.7)                                           289   3-CO.sub.2 (n-C.sub.3 H.sub.7)                                           290   4-CO.sub.2 (n-C.sub.3 H.sub.7)                                           291   2-CO.sub.2 (i-C.sub.3 H.sub.7)                                           292   3-CO.sub.2 (i-C.sub.3 H.sub.7)                                           293   4-CO.sub.2 (i-C.sub.3 H.sub.7)                                           294   2-CO.sub.2 (n-C.sub.6 H.sub.13)                                          295   3-CO.sub.2 (n-C.sub.6 H.sub.13)                                          296   4-CO.sub.2 (n-C.sub.6 H.sub.13)                                          297   2-CO.sub.2 (n-C.sub.8 H.sub.17)                                          298   3-CO.sub.2 (n-C.sub.8 H.sub.17)                                          299   4-CO.sub.2 (n-C.sub.8 H.sub.17)                                          300a) 2-CHNO-allyl:  oil     3.95(s, 3H); 4.05(s, 3H);                               non-polar isomer       5.1(s, 2H)                                        300b) 2-CHNO-allyl:  oil     3.90(s, 3H); 4.10(s, 3H);                               polar isomer           5.1(s, 2H)                                        301a) 3-CHNO-allyl:  oil     3.95(s, 3H); 4.05(s, 3H);                               non-polar isomer       5.1(s, 2H)                                        301b) 3-CHNO-allyl:  oil     3.90(s, 3H); 4.05(s, 3H);                               polar isomer           5.1(s, 2H)                                        302a) 4-CHNO-allyl:  oil     3.90(s, 3H); 4.0(s, 3H);                                non-polar isomer       5.1(s, 2H)                                        302b) 4-CHNO-allyl:  89                                                              polar isomer                                                             303   2-CHNO(CH.sub.2).sub.3                                                         (C.sub.6 H.sub.5)                                                        304   3-CHNO(CH.sub.2).sub.3                                                         (C.sub.6 H.sub.5)                                                        305   4-CHNO(CH.sub.2).sub.3                                                         (C.sub.6 H.sub.5)                                                        306   2-CH.sub.2 OCH.sub.3                                                     307   3-CH.sub.2 OCH.sub.3                                                     308   4-CH.sub.2 OCH.sub.3                                                     309   2-CH.sub.2 O(C.sub.2 H.sub.5)                                            310   3-CH.sub.2 O(C.sub.2 H.sub.5)                                            311   4-CH.sub.2 O(C.sub.2 H.sub.5)                                            312   2-CH.sub.2 O(n-C.sub.3 H.sub.7)                                          313   3-CH.sub.2 O(n-C.sub.3 H.sub.7)                                          314   4-CH.sub.2 O(n-C.sub.3 H.sub.7)                                          315   2-CH.sub.2 O(i-C.sub.3 H.sub.7)                                          316   3-CH.sub.2 O(i-C.sub.3 H.sub.7)                                          317   4-(CH.sub.2 O(i-C.sub.3 H.sub.7)                                         318   2-CH.sub.2 O(n-C.sub.6 H.sub.13)                                         319   3-CH.sub.2 O(n-C.sub.6 H.sub.13)                                         320   2-CH.sub.2 O(n-C.sub.6 H.sub.13)                                         321   2-CH.sub.2 O(n-C.sub.8 H.sub.17)                                         322   3-CH.sub.2 O(n-C.sub.8 H.sub.17)                                         323   4-CH.sub.2 O(n-C.sub.8 H.sub.7)                                          324   2-CH.sub.2 OCH.sub.2 (C.sub. 6 H.sub.5)                                  325   3-CH.sub.2 OCH.sub.2 (C.sub.6 H.sub.5)                                   325   4-CH.sub.2 OCH.sub.2 (C.sub.6 H.sub.5)                                   327   2-CH.sub.2 O(CH.sub.2).sub.3                                             328   3-CH.sub.2 O(CH.sub.2).sub.3 (C.sub.6 H.sub.5)                           329   4-CH.sub.2 O(CH.sub.2).sub.3 (C.sub.6 H.sub.5)                           330   2-CHO                                                                    331   3-CHO                                                                    332   4-CHO                                                                    ______________________________________                                    

                  TABLE 6                                                          ______________________________________                                          ##STR33##                                                                     No.  X.sub.m           mp    NMR: δ(ppm)                                 ______________________________________                                          1   2-F                                                                        2   3-F                                                                        3   4-F                                                                        4   2,4-F.sub.2                                                                5   2,4,6-F.sub.3                                                              6   2,3,4,5,6-F.sub.5                                                          7   2,3-F.sub.2                                                                8   2-Cl                                                                       9   3-Cl                                                                       10  4-Cl                                                                       11  2,3-Cl.sub.2                                                               12  2,4-Cl.sub.2                                                               13  2,5-Cl.sub.2                                                               14  2,6-Cl.sub.2                                                               15  3,4-Cl.sub.2                                                               16  3,5-Cl.sub.2                                                               17  2,3,4-Cl.sub.3                                                             18  2,3,5-Cl.sub.3                                                             19  2,3,6-Cl.sub.3                                                             20  2,4,5-Cl.sub.3                                                             21  2,4,6-Cl.sub.3                                                             22  3,4,5-Cl.sub.3                                                             23  2,3,4,6-Cl.sub.4                                                           24  2,3,5,6-Cl.sub.4                                                           25  2,3,4,5,6-Cl.sub.5                                                         26  2-Br                                                                       27  3-Br                                                                       28  4-Br                                                                       29  2,4-Br.sub.2                                                               30  2,5-Br.sub.5                                                               31  2,6-Br.sub.2                                                               32  2,4,6-Br.sub.3                                                             33  2,3,4,5,6-Br.sub.5                                                         34  2-I                                                                        35  3-I                                                                        36  4-I                                                                        37  2,4-I.sub.2                                                                38  2-Cl, 3-F                                                                  39  2-Cl, 4-F                                                                   40 2-Cl, 5-F                                                                  41  2-Cl, 6-F                                                                  42  2-Cl, 3-Br                                                                 43  2-Cl, 4-Br                                                                 44  2-Cl, 6-Br                                                                 45  2-Cl, 6-Br                                                                 46  2-Br, 3-Cl                                                                 47  2-Br, 4-Cl                                                                 48  2-Br, 5-Cl                                                                 49  2-Br, 3-F                                                                  50  2-Br, 4-F                                                                  51  2-Br, 5-F                                                                  52  2-Br, 6-F                                                                  53  2-F, 3-Cl                                                                  54  2-F, 4-Cl                                                                  55  2-F, 5-Cl                                                                  56  3-Cl, 4-F                                                                  57  3-Cl, 5-F                                                                  58  3-Cl, 4-Br                                                                 59  3-Cl, 5-Br                                                                 60  3-F, 4-Cl                                                                  61  3-F, 4-Br                                                                  62  3-Br, 4-Cl                                                                 63  3-Br, 4-F                                                                  64  2,6-Cl.sub.2, 4-Br                                                         65  2-CH.sub.3        oil   1.75(d, J=8Hz, 3H);                                                            3.7(S, 3H); 5.1(S, 2H)                             66  3-CH.sub.3                                                                 67  4-CH.sub.3                                                                 68  2,3-(CH.sub.3).sub.2                                                       69  2,4-(CH.sub.3).sub.2                                                       70  2,5-(CH.sub.3).sub.2                                                       71  2,6-(CH.sub.3).sub.2                                                       72  3,4-(CH.sub.3).sub.2                                                       73  3,5-(CH.sub.3).sub.2                                                       74  3,5-(CH.sub.3).sub.2                                                       75  2,3,4-(CH.sub.3).sub.3                                                     76  2,3,6-(CH.sub.3).sub.3                                                     77  2,4,5-(CH.sub.3).sub.3                                                     78  2,4,6-(CH.sub.3).sub.3                                                     79  3,4,5-(CH.sub.3).sub.3                                                     80  2,3,4,6-(CH.sub. 3).sub.4                                                  81  2,3,5,6-(CH.sub.3).sub.4                                                   82  2,3,4,5,6-(CH.sub.3).sub.5                                                 83  2-C.sub.2 H.sub.5                                                          84  3-C.sub.2 H.sub.5                                                          85  4-C.sub.2 H.sub.5                                                          86  2,4-(C.sub.2 H.sub.5).sub.2                                                87  2,6-(C.sub.2 H.sub.5).sub.2                                                88  3,5-(C.sub.2 H.sub.5).sub.2                                                89  2,4,6-(C.sub.2 H.sub.5).sub.3                                              90  2-n-C.sub.3 H.sub.7                                                        91  3-n-C.sub.3 H.sub.7                                                        92  4-n-C.sub.3 H.sub.7                                                        93  2-i-C.sub.3 H.sub.7                                                        94  3-i-C.sub.3 H.sub.7                                                        95  4-i-C.sub.3 H.sub.7                                                        96  2,4-(i-C.sub.3 H.sub.7).sub.2                                              97  2,6-(i-C.sub.3 H.sub.7).sub.2                                              98  3,5-(i-C.sub.3 H.sub.7).sub.2                                              99  2,4,6-(i-C.sub.3 H.sub.7).sub.3                                           100  2-SC.sub.4 H.sub.9                                                        101  3-SC.sub.4 H.sub.9                                                        102  4-SC.sub.4 H.sub.9                                                        103  2-t-C.sub.4 H.sub.9                                                       104  3-t-C.sub.4 H.sub.9                                                       105  4-t-C.sub.4 H.sub.9                                                       106  2,3-(t-C.sub.4 H.sub.9).sub.2                                             107  2,4-(t-C.sub.4 H.sub.9).sub.2                                             108  2,5-(t-C.sub.4 H.sub.9).sub.2                                             109  2,6-(t-C.sub.4 H.sub.9).sub.2                                             110  3,4-(t-C.sub.4 H.sub.9).sub.2                                             111  2,4,6-(t-C.sub. 4 H.sub.9).sub.3                                          112  4-n-C.sub.9 H.sub.19                                                      113  4-n-C.sub.12 H.sub.25                                                     114  3-n-C.sub.15 H.sub.31                                                     115  4-(1,1,3,3-tetramethylbutyl)                                              116  4-(2,4,4-trimethylpropyl                                                  117  2-t-C.sub.4 H.sub.9, 4-CH.sub.3                                           118  2-t-C.sub.4 H.sub.9, 5-CH.sub.3                                           119  2,6-(t-C.sub.4 H.sub.9), 4-CH.sub.3                                       120  2-CH.sub.3, 4-t-C.sub.4 H.sub.9                                           121  2-CH.sub.3, 6-t-C.sub.4 H.sub.9                                           122  2-CH.sub.3, 4-i-C.sub.3 H.sub.7                                           123  2-CH.sub.3, 5-i-C.sub.3 H.sub.7                                           124  3-CH.sub.3, 4-i-C.sub.3 H.sub.7                                           125  2-i-C.sub.3 H.sub.7, 5 CH.sub.3                                           126  2,4-(t-C.sub.4 H.sub.9), 6-i-C.sub.3 H.sub.7                              127  2-allyl                                                                   128  3-allyl                                                                   129  4-allyl                                                                   130  2-allyl, 6-CH.sub.3                                                       131  2-cyclo-C.sub.6 H.sub.11                                                  132  3-cyclo-C.sub.6 H.sub.11                                                  133  4-cyclo-C.sub.6 H.sub.11                                                  134  2,4-(cyclo-C.sub.6 H.sub.11).sub.2, 6-CH.sub.3                            135  2-CH.sub.3, 4-cyclo-C.sub.6 H.sub.11                                      136  2-CH.sub.2 C.sub.6 H.sub.5                                                137  3-CH.sub.2 C.sub.6 H.sub.5                                                138  4-CH.sub.2 C.sub.6 H.sub.5                                                139  2-CH.sub.2 C.sub.6 H.sub.5, 4-CH.sub.3                                    140  2-CH.sub.3, 4-CH.sub.2 C.sub.6 H.sub.5                                    141  2-C.sub.6 H.sub. 5                                                        142  3-C.sub.6 H.sub.5                                                         143  4-C.sub.6 H.sub.5                                                         144  4-(2-i-C.sub.3 H.sub.7 C.sub.6 H.sub.4)                                   145  4-C.sub.6 H.sub.5, 2,6-(CH.sub.3).sub.2                                   146  2-Cl, 4-C.sub.6 H.sub.5                                                   147  2-Br, 4-C.sub.6 H.sub.5                                                   148  2-C.sub.6 H.sub.5, 4-Cl                                                   149  2-C.sub.6 H.sub.5, 4-Br                                                   150  2-CH.sub.2 C.sub.6 H.sub.5, 4-Cl                                          151  2-CH.sub.2 C.sub.6 H.sub.5, 4-Br                                          152  2-Cl, 4-CH.sub.2 C.sub.6 H.sub.5                                          153  2-Br, 4-CH.sub.2 C.sub.6 H.sub.5                                          154  2-cyclo-C.sub.6 H.sub.11, 4-Cl                                            155  2-cyclo-C.sub.6 H.sub.11, 4-Br                                            156  2-Cl, 4-cyclo-C.sub.6 H.sub.11                                            157  2-Br, 4-cyclo-C.sub.6 H.sub.11                                            158  2-OCH.sub.3                                                               159  3-OCH.sub.3                                                               160  4-OCH.sub.3                                                               161  2-OC.sub.2 H.sub.5                                                        162  3-OC.sub.2 H.sub.5                                                        163  4-OC.sub.2 H.sub.5                                                        164  2-O-n-C.sub.3 H.sub.7                                                     165  3-O-n-C.sub.3 H.sub.7                                                     166  4-O-n-C.sub.3 H.sub.7                                                     167  2-O-i-C.sub.3 H.sub.7                                                     168  3-O-i-C.sub.3 H.sub.7                                                     169  4-O-i-C.sub.3 H.sub.7                                                     170  2-O-n-C.sub.6 H.sub.13                                                    171  3-O-n-C.sub.6 H.sub.13                                                    172  4-O-n-C.sub.6 H.sub.13                                                    173  2-O-n-C.sub.8 H.sub.17                                                    174  3-O-n-C.sub.8 H.sub.17                                                    175  4-O-n-C.sub. 8 H.sub.17                                                   176  2-OCH.sub.2 C.sub.6 H.sub.5                                               177  3-OCH.sub.2 C.sub.6 H.sub.5                                               178  4-OCH.sub.2 C.sub.6 H.sub.5                                               179  2-O(CH.sub.2).sub.3 C.sub.6 H.sub.5                                       180  3-O(CH.sub.2).sub.3 C.sub.6 H.sub.5                                       181  4-O(CH.sub.2).sub.3 C.sub.6 H.sub.5                                       182  2,4-(OCH.sub.3).sub.2                                                     183  2-CF.sub.3                                                                184  3-CF.sub.3                                                                185  4-CF.sub.3                                                                186  2-OCF.sub.3                                                               187  3-OCF.sub.3                                                               188  4-OCF.sub.3                                                               189  3-OCH.sub.2 CHF.sub.2                                                     190  2-NO.sub.2                                                                191  3-NO.sub.2                                                                192  4-NO.sub.2                                                                193  2-CN                                                                      194  3-CN                                                                      195  4-CN                                                                      196  2-CH.sub.3, 3-Cl                                                          197  2-CH.sub.3, 4-Cl                                                          198  2-CH.sub.3, 5-Cl                                                          199  2-CH.sub.3, 6-Cl                                                          200  2-CH.sub.3, 3-F                                                           201  2-CH.sub.3, 4-F                                                           202  2-CH.sub.3, 5-F                                                           203  2-CH.sub.3, 6-F                                                           204  2-CH.sub.3, 3-Br                                                          205  2-CH.sub.3, 4-Br                                                          206  2-CH.sub.3, 5-Br                                                          207  2-CH.sub.3, 6-Br                                                          208  2-Cl, 3-CH.sub.3                                                          209  2-Cl, 4-CH.sub.3                                                          210  2-Cl, 5-CH.sub.3                                                          211  2-F, 3-CH.sub.3                                                           212  2-F, 4-CH.sub.3                                                           213  2-F, 5-CH.sub.3                                                           214  2-Br, 3-CH.sub.3                                                          215  2-Br, 4-CH.sub.3                                                          216  2-Br, 5-CH.sub.3                                                          217  3-CH.sub.3, 4-Cl                                                          218  3-CH.sub.3, 5-Cl                                                          219  3-CH.sub.3, 4-F                                                           220  3-CH.sub.3, 4-Br                                                          221  3-CH.sub.3, 4-Br                                                          222  3-CH.sub.3, 5-Br                                                          223  3-F, 4-CH.sub.3                                                           224  3-Cl, 4-CH.sub.3                                                          225  3-Br, 4-CH.sub.3                                                          226  2-Cl, 4,5-(CH.sub.3).sub.2                                                227  2-Br, 4,5-(CH.sub.3).sub.2                                                228  2-Cl, 3,5-(CH.sub.3).sub.2                                                229  2-Br, 3,5-(CH.sub.3).sub.2                                                230  2,6-Cl.sub.2, 4-CH.sub.3                                                  231  2,6-F.sub.2, 4-CH.sub.3                                                   232  2,6-Br.sub.2, 4-CH.sub.3                                                  233  2,4-Cl.sub.2, 6-CH.sub.3                                                  234  2,4-F.sub.2, 6-CH.sub.3                                                   235  2,4-Br.sub.2, 6-CH.sub.3                                                  236  2,6-(CH.sub.3).sub.2, 4-F                                                 237  2,6-(CH.sub.3).sub.2, 4-Cl                                                238  2,6-(CH.sub.3).sub.2, 4-Br                                                239  3,5-(CH.sub.3).sub.2, 4-F                                                 240  3,5-(CH.sub.3).sub.2, 4-Cl                                                241  3,5-(CH.sub.3).sub.2, 4-Br                                                242  2,3,6-(CH.sub.3).sub.3, 4-F                                               243  2,3,6-(CH.sub.3).sub.3, 4-Cl                                              244  2,3,6-(CH.sub.3).sub.3, 4-Br                                              245  2,4-(CH.sub.3).sub.2, 6-F                                                 246  2,4-(CH.sub.3).sub.2, 6-Cl                                                247  2,4-(CH.sub.3).sub.62, 6-Br                                               248  2-i-C.sub.3 H.sub.7, 4-Cl, 5-CH.sub.3                                     249  2-Cl, 4-NO.sub.2                                                          250  2-NO.sub.2, 4-Cl                                                          251  2-OCH.sub.3, 5-NO.sub.2                                                   252  2,4-Cl.sub.2, 5-NO.sub.2                                                  253  2,4-Cl.sub.2, 6-NO.sub.2                                                  254  2,6-Cl.sub.2, 4-NO.sub.2                                                  255  2,6-Br.sub.2, 4-NO.sub.2                                                  256  2,6-I.sub.2, 4-NO.sub.2                                                   257  2-CH.sub.3, 5-i-C.sub.3 H.sub.7, 4-Cl                                     258  2-C.sub.6 H.sub.5 O                                                       259  3-C.sub.6 H.sub.5 O                                                       260  4-C.sub.6 H.sub.5 O                                                       261  2-CHNOCH.sub.3                                                            262  3-CHNOCH.sub.3                                                            263  4-CHNOCH.sub.3                                                            264  2-CHNOC.sub.2 H.sub.5                                                     265  3-CHNOC.sub.2 H.sub.5                                                     266  4-CHNOC.sub.2 H.sub.5                                                     267  2-CHNO(n-C.sub.3 H.sub.7)                                                 268  3-CHNO(n-C.sub.3 H.sub.7)                                                 269  4-CHNO(n-C.sub.3 H.sub.7)                                                 270  2-CHNO(i-C.sub.3 H.sub.7)                                                 271  3-CHNO(i-C.sub.3 H.sub.7)                                                 272  4-CHNO(i-C.sub.3 H.sub.7)                                                 273  2-CHNO(n-C.sub.6 H.sub.13)                                                274  3-CHNO(n-C.sub.6 H.sub.13)                                                275  4-CHNO(n-C.sub.6 H.sub.13)                                                276  2-CHNO(n-C.sub.8 H.sub.17)                                                277  3-CHNO(n-C.sub.8 H.sub.17)                                                278  4-CHNO(n-C.sub.8 H.sub.17)                                                279  2-CHNOCH.sub.2 (C.sub.6 H.sub.5)                                          280  3-CHNOCH.sub.2 (C.sub.6 H.sub.5)                                          281  4-CHNOCH.sub.2 (C.sub.6 H.sub.5)                                          282  2-CO.sub.2 CH.sub.3                                                       283  3-CO.sub.2 CH.sub.3                                                       284  4-CO.sub.2 CH.sub.3                                                       285  2-CO.sub.2 (C.sub.2 H.sub.5)                                              286  3-CO.sub.2 (C.sub.2 H.sub.5)                                              287  4-CO.sub.2 (C.sub.2 H.sub.5)                                              288  2-CO.sub.2 (n-C.sub.3 H.sub.7)                                            289  3-CO.sub.2 (n-C.sub.3 H.sub.7)                                            290  4-CO.sub.2 (n-C.sub.3 H.sub.7)                                            291  2-CO.sub.2 (i-C.sub.3 H.sub.7)                                            292  3-CO.sub.2 (i-C.sub.3 H.sub.7)                                            293  4-CO.sub.2 (i-C.sub.3 H.sub.7)                                            294  2-CO.sub.2 (n-C.sub.6 H.sub.13)                                           295  3-CO.sub.2 (n-C.sub.6 H.sub.13)                                           296  4-CO.sub.2 (n-C.sub.6 H.sub.13)                                           297  2-CO.sub.2 (n-C.sub.8 H.sub.17)                                           298  3-CO.sub.2 (n-C.sub.8 H.sub.17)                                           299  4-CO.sub.2 (n-C.sub.8 H.sub.17)                                           300  2-CHNOCH.sub.2 CHCH.sub.2                                                 301  3-CHNOCH.sub.2 CHCH.sub.2                                                 302  4-CHNOCH.sub.2 CHCH.sub.2                                                 303  2-CHNO(CH.sub.2).sub.3 (C.sub.6 H.sub.5)                                  304  3-CHNO(CH.sub.2).sub.3 (C.sub.6 H.sub.5)                                  305  4-CHNO(CH.sub.2).sub.3 (C.sub.6 H.sub.5)                                  306  2-CH.sub.2 OCH.sub.3                                                      307  3-CH.sub.2 OCH.sub.3                                                      308  4-CH.sub.2 OCH.sub.3                                                      309  2-CH.sub.2 O(C.sub.2 H.sub.5)                                             310  3-CH.sub.2 O(C.sub. 2 H.sub.5)                                            311  4-CH.sub.2 O(C.sub.2 H.sub.5)                                             312  2-CH.sub.2 O(n-C.sub.3 H.sub.7)                                           313  3-CH.sub.2 O(n-C.sub.3 H.sub.7)                                           314  4-CH.sub.2 O(n-C.sub.3 H.sub.7)                                           315  2-CH.sub.2 O(i-C.sub.3 H.sub.7)                                           316  3-CH.sub.2 O(i-C.sub.3 H.sub.7)                                           317  4-(CH.sub.2 O(i-C.sub.3 H.sub.7)                                          318  2-CH.sub.2 O(n-C.sub.6 H.sub.13)                                          319  3-CH.sub.2 O(n-C.sub.6 H.sub.13)                                          320  4-CH.sub.2 O(n-C.sub.6 H.sub.13)                                          321  2-CH.sub.2 O(n-C.sub.8 H.sub.17)                                          322  3-CH.sub.2 O(n-C.sub.8 H.sub.17)                                          323  4-CH.sub.2 O(n-C.sub.8 H.sub.7)                                           324  2-CH.sub.2 OCH.sub.2 (C.sub.6 H.sub.5)                                    325  3-CH.sub.2 OCH.sub.2 (C.sub.6 H.sub.5)                                    326  4-CH.sub.2 OCH.sub.2 (C.sub.6 H.sub.5)                                    327  2-CH.sub.2 O(CH.sub.2).sub.3                                              328  3-CH.sub.2 O(CH.sub.2).sub.3 (C.sub.6 H.sub.5)                            329  4-CH.sub.2 O(CH.sub.2).sub.3 (C.sub.6 H.sub.5)                            330  2-CHO                                                                     331  3-CHO                                                                     332  4-CHO                                                                     ______________________________________                                    

                  TABLE 7                                                          ______________________________________                                          ##STR34##                                                                     No.   X.sub.m           mp       NMR: δ(ppm)                             ______________________________________                                          1    2-F                                                                       2    3-F                                                                       3    4-F                                                                       4    2,4-F.sub.2                                                               5    2,4,6-F.sub.3                                                             6    2,3,4,5,6-F.sub.4                                                         7    2,3-F.sub.2                                                               8    2-Cl              72-74                                                   9    3-Cl              oil      5.0(S, 2H);                                                                    7.55(S, 1H)                                    10   4-Cl              80-81                                                   11   2,3-Cl.sub.2                                                              12   2,4-Cl.sub.2      59-61                                                   13   2,5-Cl.sub.2                                                              14   2,6-Cl.sub.2                                                              15   3,4-Cl.sub.2      oil      5.0(S, 2H);                                                                    7.55(S, 1H)                                    16   3,5-Cl.sub.2      93-95                                                   17   2,3,4-Cl.sub.3                                                            18   2,3,5-Cl.sub.3                                                            19   2,3,6-Cl.sub.3                                                            20   2,4,5-Cl.sub.3                                                            21   2,4,6-Cl.sub.3                                                            22   3,4,5-Cl.sub.3                                                            23   2,3,4,6-Cl.sub.4                                                          24   2,3,5,6-Cl.sub.4                                                          25   2,3,4,5,6-Cl.sub.5                                                        26   2-Br                                                                      27   3-Br                                                                      28   4-Br                                                                      29   2,4-Br.sub.2                                                              30   2,5-Br.sub.5                                                              31   2,6-Br.sub.2                                                              32   2,4,6-Br.sub.3                                                            33   2,3,4,5,6-Br.sub.5                                                        34   2-I                                                                       35   3-I                                                                       36   4-I                                                                       37   2,4-I.sub.2                                                               38   2-Cl, 3-F                                                                 39   2-Cl, 4-F                                                                 40   2-Cl, 5-F                                                                 41   2-Cl, 6-F                                                                 42   2-Cl, 3-Br                                                                43   2-Cl, 4-Br                                                                44   2-Cl, 6-Br                                                                45   2-Cl, 6-Br                                                                46   2-Br, 3-Cl                                                                47   2-Br, 4-Cl                                                                48   2-Br, 5-Cl                                                                49   2-Br, 3-F                                                                 50   2-Br, 4-F                                                                 51   2-Br, 5-F                                                                 52   2-Br, 6-F                                                                 53   2-F, 3-Cl                                                                 54   2-F, 4-Cl                                                                 55   2-F, 5-Cl                                                                 56   3-Cl, 4-F                                                                 57   3-Cl, 5-F                                                                 58   3-Cl, 4-Br                                                                59   3-Cl, 5-Br                                                                60   3-F, 4-Cl                                                                 61   3-F, 4-Br                                                                 62   3-Br, 4-Cl                                                                63   3-Br, 4-F                                                                 64   2,6-Cl.sub.2, 4-Br                                                        65   2-CH.sub.3        oil      5.0(S, 2H);                                                                    7.55(S, 1H)                                    66   3-CH.sub.3        oil      5.0(S, 2H);                                                                    7.55(S, 1H)                                    67   4-CH.sub.3        69-71                                                   68   2,3-(CH.sub.3).sub.2                                                      69   2,4-(CH.sub.3).sub.2                                                      70   2,5-(CH.sub.3).sub.2                                                      71   2,6-(CH.sub.3).sub.2                                                      72   3,4-(CH.sub.3).sub.2                                                      73   3,5-(CH.sub.3).sub.2                                                      74   3,5-(CH.sub.3).sub.2                                                      75   2,3,4-(CH.sub. 3).sub.3                                                   76   2,3,6-(CH.sub.3).sub.3                                                    77   2,4,5-(CH.sub.3).sub.3                                                    78   2,4,6-(CH.sub.3).sub.3                                                    79   3,4,5-(CH.sub.3).sub.3                                                    80   2,3,4,6-(CH.sub.3).sub.4                                                  81   2,3,5,6-(CH.sub.3).sub.4                                                  82   2,3,4,5,6-(CH.sub.3).sub.5                                                83   2-C.sub.2 H.sub.5                                                         84   3-C.sub.2 H.sub.5                                                         85   4-C.sub.2 H.sub.5                                                         86   2,4-(C.sub.2 H.sub.5).sub.2                                               87   2,6-(C.sub.2 H.sub.5).sub.2                                               88   3,5-(C.sub.2 H.sub.5).sub.2                                               89   2,4,6-(C.sub.2 H.sub.5).sub.3                                             90   2-n-C.sub.3 H.sub.7                                                       91   3-n-C.sub.3 H.sub.7                                                       92   4-n-C.sub.3 H.sub.7                                                       93   2-i-C.sub.3 H.sub.7                                                       94   3-i-C.sub.3 H.sub.7                                                       95   4-i-C.sub.3 H.sub.7                                                       96   2,4-(i-C.sub.3 H.sub.7).sub.2                                             97   2,6-(i-C.sub.3 H.sub.7).sub.2                                             98   3,5-(i-C.sub.3 H.sub.7).sub.2                                             99   2,4,6-(i-C.sub.3 H.sub.7).sub.3                                          100   2-S-C.sub.4 H.sub.9                                                      101   3-S-C.sub.4 H.sub.9                                                      102   4-S-C.sub.4 H.sub.9                                                      103   2-t-C.sub.4 H.sub.9                                                      104   3-t-C.sub.4 H.sub.9                                                      105   4-t-C.sub.4 H.sub.9                                                      106   2,3-(t-C.sub.4 H.sub.9).sub.2                                            107   2,4-(t-C.sub.4 H.sub.9).sub.2                                            108   2,5-(t-C.sub.4 H.sub.9).sub.2                                            109   2,6-(t-C.sub.4 H.sub.9).sub.2                                            110   3,4-(t-C.sub.4 H.sub.9).sub.2                                            111   2,4,6-(t-C.sub.4 H.sub.9).sub.3                                          112   4-n-C.sub.9 H.sub.19                                                     113   4-n-C.sub.12 H.sub.25                                                    114   3-n-C.sub.15 H.sub.31                                                    115   4-(1,1,3,3-tetramethylbutyl)                                             116   4-(2,4,4-trimethylpropyl                                                 117   2-t-C.sub.4 H.sub.9, 4-CH.sub.3                                          118   2-t-C.sub.4 H.sub.9, 5-CH.sub.3                                          119   2,6-(t-C.sub.4 H.sub.9), 4-CH.sub.3                                      120   2-CH.sub.3, 4-t-C.sub.4 H.sub.9                                          121   2-CH.sub.3, 6-t-C.sub.4 H.sub.9                                          122   2-CH.sub.3, 4-i-C.sub.3 H.sub.7                                          123   2-CH.sub.3, 5-i-C.sub.3 H.sub.7                                          124   3-CH.sub.3, 4-i-C.sub.3 H.sub.7                                          125   2-i-C.sub.3 H.sub.7, 5 CH.sub.3                                          126   2,4-(t-C.sub.4 H.sub.9), 6-i-C.sub.3 H.sub.7                             127   2-allyl                                                                  128   3-allyl                                                                  129   4-allyl                                                                  130   2-allyl, 6-CH.sub.3                                                      131   2-cyclo-C.sub.6 H.sub.11                                                 132   3-cyclo-C.sub.6 H.sub.11                                                 133   4-cyclo-C.sub.6 H.sub.11                                                 134   2,4-(cyclo-C.sub.6 H.sub.11).sub.2, 6-CH.sub.3                           135   2-CH.sub.3, 4-cyclo-C.sub.6 H.sub.11                                     136   2-CH.sub.2 C.sub.6 H.sub.5                                               137   3-CH.sub.2 C.sub.6 H.sub.5                                               138   4-CH.sub.2  C.sub.2 H.sub.5                                              139   2-CH.sub.2 C.sub.6 H.sub.5, 4-CH.sub.3                                   140   2-CH.sub.3, 4-CH.sub.2 C.sub.6 H.sub.5                                   141   2-C.sub.6 H.sub.5                                                        142   3-C.sub.6 H.sub.5                                                        143   4-C.sub.6 H.sub.5                                                        144   4-(2-i-C.sub.3 H.sub.7 C.sub.6 H.sub.4)                                  145   4-C.sub.6 H.sub.5, 2,6-(CH.sub.3).sub.2                                  146   2-Cl, 4-C.sub.6 H.sub.5                                                  147   2-Br, 4-C.sub.6 H.sub.5                                                  148   2-C.sub.6 H.sub.5, 4-Cl                                                  149   2-C.sub.6 H.sub.5, 4-Br                                                  150   2-CH.sub.2 C.sub.6 H.sub.5, 4-Cl                                         151   2-CH.sub.2 C.sub.6 H.sub.5, 4-Br                                         152   2-Cl, 4-CH.sub.2 C.sub.6 H.sub.5                                         153   2-Br, 4-CH.sub.2 C.sub.6 H.sub.5                                         154   2-cyclo-C.sub.6 H.sub.11, 4-Cl                                           155   2-cyclo-C.sub.6 H.sub.11, 4-Br                                           156   2-Cl, 4-cyclo-C.sub.6 H.sub.11                                           157   2-Br, 4-cyclo-C.sub.6 H.sub.11                                           158   2-OCH.sub.3                                                              159   3-OCH.sub.3                                                              160   4-OCH.sub.3                                                              161   2-OC.sub.2 H.sub.5                                                       162   3-OC.sub.2 H.sub.5                                                       163   4-OC.sub.2 H.sub.5                                                       164   2-O-n-C.sub.3 H.sub.7                                                    165   3-O-n-C.sub.3 H.sub.7                                                    166   4-O-n-C.sub.3 H.sub.7                                                    167   2-O-i-C.sub.3 H.sub.7                                                    168   3-O-i-C.sub.3 H.sub.7                                                    169   4-O-i-C.sub.3 H.sub.7                                                    170   2-O-n-C.sub.6 H.sub.13                                                   171   3-O-n-C.sub.6 H.sub.13                                                   172   4-O-i-C.sub.6 H.sub.13                                                   173   2-O-n-C.sub.8 H.sub.17                                                   174   3-O-n-C.sub.8 H.sub.17                                                   175   4-O-n-C.sub.8 H.sub.17                                                   176   2-OCH.sub.2 C.sub.6 H.sub.5                                              177   3-OCH.sub.2 C.sub.6 H.sub.5                                              178   4-OCH.sub.2 C.sub.6 H.sub.5                                              179   2-O(CH.sub.2).sub.3 C.sub.6 H.sub.5                                      180   3-O(CH.sub.2).sub.3 C.sub.6 H.sub.5                                      181   4-O(CH.sub.2).sub.3 C.sub.6 H.sub.5                                      182   2,4-(OCH.sub.3).sub.2                                                    183   2-CF.sub.3                                                               184   3-CF.sub.3                                                               185   4-CF.sub.3                                                               186   2-OCF.sub.3                                                              187   3-OCF.sub.3                                                              188   4-OCF.sub.3                                                              189   3-OCH.sub.2 CHF.sub.2                                                    190   2-NO.sub.2                                                               191   3-NO.sub.2                                                               192   4-NO.sub.2                                                               193   2-CN                                                                     194   3-CN                                                                     195   4-CN                                                                     196   2-CH.sub.3, 3-Cl                                                         197   2-CH.sub.3, 4-Cl                                                         198   2-CH.sub.3, 5-Cl                                                         199   2-CH.sub.3, 6-Cl                                                         200   2-CH.sub.3, 3-F                                                          201   2-CH.sub.3, 4-F                                                          202   2-CH.sub.3, 5-F                                                          203   2-CH.sub.3, 6-F                                                          204   2-CH.sub.3, 3-Br                                                         205   2-CH.sub.3, 3-Br                                                         206   2-CH.sub.3, 5-Br                                                         207   2-CH.sub.3, 6-Br                                                         208   2-Cl, 3-CH.sub.3                                                         209   2-Cl, 4-CH.sub.3                                                         210   2-Cl, 5-CH.sub.3                                                         211   2-F, 3-CH.sub.3                                                          212   2-F, 4-CH.sub.3                                                          213   2-F, 5-CH.sub.3                                                          214   2-Br, 3-CH.sub.3                                                         215   2-Br, 4-CH.sub.3                                                         216   2-Br, 5-CH.sub.3                                                         217   3-CH.sub.3, 4-Cl                                                         218   3-CH.sub.3, 5-Cl                                                         219   3-CH.sub.3, 4-F                                                          220   3-CH.sub.3, 4-Br                                                         221   3-CH.sub.3, 4-Br                                                         222   3-CH.sub.3, 5-Br                                                         223   3-F, 4-CH.sub.3                                                          224   3-Cl, 4-CH.sub.3                                                         225   3-Br, 4-CH.sub.3                                                         226   2-Cl, 4,5-(CH.sub.3).sub.2                                               227   2-Br, 4,5-(CH.sub.3).sub.2                                               228   2-Cl, 3,5-(CH.sub.3).sub.2                                               229   2-Br, 3,5-(CH.sub.3).sub.2                                               230   2,6-Cl.sub.2, 4-CH.sub.3                                                 231   2,6-F.sub.2, 4-CH.sub.3                                                  232   2,6-Br.sub.2, 4-CH.sub.3                                                 233   2,4-Cl.sub.2, 6-CH.sub.3                                                 234   2,4-F.sub.2, 6-CH.sub.3                                                  235   2,4-Br.sub.2, 6-CH.sub.3                                                 236   2,6-(CH.sub.3).sub.2, 4-F                                                237   2,6-(CH.sub.3).sub.2, 4-Cl                                               238   2,6-(CH.sub.3).sub.2, 4-Br                                               239   3,5-(CH.sub.3).sub.2, 4-F                                                240   3,5-(CH.sub.3).sub.2, 4-Cl                                               241   3,5-(CH.sub.3).sub.2, 4-Br                                               242   2,3,6-(CH.sub.3).sub.3, 4-F                                              243   2,3,6-(CH.sub.3).sub.3, 4-Cl                                             244   2,3,6-(CH.sub.3).sub.3, 4-Br                                             245   2,4-(CH.sub.3).sub.2, 6-F                                                246   2,4-(CH.sub.3).sub.2, 6-Cl                                               247   2,4-(CH.sub.3).sub.62, 6-Br                                              248   2-i-C.sub.3 H.sub.7, 4-Cl, 5-CH.sub.3                                    249   2-Cl, 4-NO.sub.2                                                         250   2-NO.sub.2, 4-Cl                                                         251   2-OCH.sub.3, 5-NO.sub.2                                                  252   2,4-Cl.sub.2, 5-NO.sub.2                                                 253   2,4-Cl.sub.2, 6-NO.sub.2                                                 254   2,6-Cl.sub.2, 4-NO.sub.2                                                 255   2,6-Br.sub.2, 4-NO.sub.2                                                 256   2,6-J.sub.2, 4-NO.sub.2                                                  257   2-CH.sub.3, 5-i-C.sub.3 H.sub.7, 4-Cl                                    258   2-C.sub.6 H.sub.5 O                                                      259   3-C.sub.6 H.sub.5 O                                                      260   4-C.sub.6 H.sub.5 O                                                      261   2-CHNOCH.sub.3                                                           262   3-CHNOCH.sub.3                                                           263   4-CHNOCH.sub.3                                                           264   2-CHNOC.sub.2 H.sub.5                                                    265   3-CHNOC.sub.2 H.sub.5                                                    266   4-CHNOC.sub.2 H.sub.5                                                    267   2-CHNO(n-C.sub.3 H.sub.7)                                                268   3-CHNO(n-C.sub.3 H.sub.7)                                                269   4-CHNO(n-C.sub.3 H.sub.7)                                                270   2-CHNO(i-C.sub.3 H.sub.7)                                                271   3-CHNO(i-C.sub.3 H.sub.7)                                                272   4-CHNO(i-C.sub.3 H.sub.7)                                                273   2-CHNO(n-C.sub.6 H.sub.13)                                               274   3-CHNO(n-C.sub.6 H.sub.13)                                               275   4-CHNO(n-C.sub.6 H.sub.13)                                               276   2-CHNO(n-C.sub.8 H.sub.17)                                               277   3-CHNO(n-C.sub.8 H.sub.17)                                               278   4-CHNO(n-C.sub.8 H.sub.17)                                               279   2-CHNOCH.sub.2 (C.sub.6 H.sub.5)                                         280   3-CHNOCH.sub.2 (C.sub.6 H.sub.5)                                         281   4-CHNOCH.sub.2 (C.sub.6 H.sub.5)                                         282   2-CO.sub.2 CH.sub.3                                                      283   3-CO.sub.2 CH.sub.3                                                      284   4-CO.sub.2 CH.sub.3                                                      285   2-CO.sub.2 (C.sub.2 H.sub.5)                                             286   3-CO.sub.2 (C.sub.2 H.sub.5)                                             287   4-CO.sub.2 (C.sub.2 H.sub.5)                                             288   2-CO.sub.2 (n-C.sub.3 H.sub.7)                                           289   3-CO.sub.2 (n-C.sub.3 H.sub.7)                                           290   4-CO.sub.2 (n-C.sub.3 H.sub.7)                                           291   2-CO.sub.2 (i-C.sub.3 H.sub.7)                                           292   3-CO.sub.2 (i-C.sub.3 H.sub.7)                                           293   4-CO.sub.2 (i-C.sub.3 H.sub.7)                                           294   2-CO.sub.2 (n-C.sub.6 H.sub.13)                                          295   3-CO.sub.2 (n-C.sub.6 H.sub.13)                                          296   4-CO.sub.2 (n-C.sub.6 H.sub.13)                                          297   2-CO.sub.2 (n-C.sub.8 H.sub.17)                                          298   3-CO.sub.2 (n-C.sub.8 H.sub.17)                                          299   4-CO.sub.2 (n-C.sub.8 H.sub.17)                                          300   2-CHNOCH.sub.2 CHCH.sub.2                                                301   3-CHNOCH.sub.2 CHCH.sub.2                                                302   4-CHNOCH.sub.2 CHCH.sub.2                                                303   2-CHNO(CH.sub.2).sub.3 (C.sub.6 H.sub.5)                                 304   3-CHNO(CH.sub.2).sub.3 (C.sub.6 H.sub.5)                                 305   4-CHNO(CH.sub.2).sub.3 (C.sub. 6 H.sub.5)                                306   2-CH.sub.2 OCH.sub.3                                                     307   3-CH.sub.2 OCH.sub.3                                                     308   4-CH.sub.2 OCH.sub.3                                                     309   2-CH.sub.2 O(C.sub.2 H.sub.5)                                            310   3-CH.sub.2 O(C.sub.2 H.sub.5)                                            311   4-CH.sub.2 O(C.sub.2 H.sub.5)                                            312   2-CH.sub.2 O(n-C.sub.3 H.sub.7)                                          313   3-CH.sub.2 O(n-C.sub.3 H.sub.7)                                          314   4-CH.sub.2 O(n-C.sub.3 H.sub.7)                                          315   2-CH.sub.2 O(i-C.sub.3 H.sub.7)                                          316   3-CH.sub.2 O(i-C.sub.3 H.sub.7)                                          317   4-(CH.sub.2 O(i-C.sub.3 H.sub.7)                                         318   2-CH.sub.2 O(n-C.sub.6 H.sub.13)                                         319   3-CH.sub.2 O(n-C.sub.6 H.sub.13)                                         320   4-CH.sub.2 O(n-C.sub.6 H.sub.13)                                         321   2-CH.sub.2 O(n-C.sub.8 H.sub.17)                                         322   3-CH.sub.2 O(n-C.sub.8 H.sub.17)                                         323   4-CH.sub.2 O(n-C.sub.8 H.sub.17)                                         324   2-CH.sub.2 OCH.sub.2 (C.sub.6 H.sub.5)                                   325   3-CH.sub.2 OCH.sub.2 (C.sub.6 H.sub.5)                                   326   4-CH.sub.2 OCH.sub.2 (C.sub.6 H.sub.5)                                   327   2-CH.sub.2 O(CH.sub.2).sub.3                                             328   3-CH.sub.2 O(CH.sub.2).sub.3 (C.sub.6 H.sub.5)                           329   4-CH.sub.2 O(CH.sub.2).sub.3 (C.sub.6 H.sub.5)                           330   2-CHO                                                                    331   3-CHO                                                                    332   4-CHO                                                                    333   3-benzoyl         oil      5.15(s, 2H);                                                                   7.55 (s, 1H)                                  ______________________________________                                    

                                      TABLE 8                                      __________________________________________________________________________      ##STR35##                                                                     No.                                                                               X.sub.m        mp    NMR: δ (ppm)                                     __________________________________________________________________________      1a)                                                                              2-F: non-polar isomer                                                                         oil   3.9(S, 3H); 4.0(S, 3H);                                                        5.15(S, 2H)                                             1b)                                                                              2-F: polar isomer                                                                             77-79                                                         2 3-F                                                                          3 4-F                                                                          4 2,4-F.sub.2                                                                  5 2,4,6-F.sub.3                                                                6 2,3,4,5,6-F.sub.5                                                            7 2,3-F.sub.2                                                                  8a)                                                                              2-Cl: non-polar isomer                                                                        oil   3.9(S, 3H); 4.0(S, 3H);                                                        5.15(S, 2H)                                             8b)                                                                              2-Cl: polar isomer                                                                            78-80                                                         9a)                                                                              3-Cl: non-polar isomer                                                                        oil   3.9(S, 3H); 4.0(S, 3H);                                                        5.05(S, 2H)                                             9b)                                                                              3-Cl: polar isomer                                                                            64-66                                                         10a)                                                                             4-Cl: non-polar isomer                                                                        58-70 3.9(S, 3H); 4.0(S, 3H);                                                        5.0(S, 2H)                                              10b)                                                                             4-Cl: polar isomer                                                                            112-120                                                                              3.85(S, 3H); 4.05(S, 3H);                                                      5.0(S, 2H)                                              11                                                                               2,3-Cl.sub.2                                                                 12a)                                                                             2,4-Cl.sub.2 : non-polar isomer                                                               89-93                                                         12b)                                                                             2,4-Cl.sub.2 : polar isomer                                                                   83-86                                                         13                                                                               2,5-Cl.sub.2                                                                  14                                                                              2,6-Cl.sub.2                                                                 15                                                                               3,4-Cl.sub.2                                                                 16                                                                               3,5-Cl.sub.2                                                                 17                                                                               2,3,4-Cl.sub.3                                                               18                                                                               2,3,5-Cl.sub.3                                                               19                                                                               2,3,6-Cl.sub.3                                                               20                                                                               2,4,5-Cl.sub.3                                                               21                                                                               2,4,6-Cl.sub.3                                                               22                                                                               3,4,5-Cl.sub.3                                                               23                                                                               2,3,4,6-Cl.sub.4                                                             24                                                                               2,3,5,6-Cl.sub.4                                                             25                                                                               2,3,4,5,6-Cl.sub.5                                                           26                                                                               2-Br                                                                         27                                                                               3-Br                                                                         28                                                                               4-Br                                                                         29                                                                               2,4-Br.sub.2                                                                 30                                                                               2,5-Br.sub.5                                                                 31                                                                               2,6-Br.sub.2                                                                 32                                                                               2,4,6-Br.sub.3                                                               33                                                                               2,3,4,5,6-Br.sub.5                                                           34                                                                               2-I                                                                          35                                                                               3-I                                                                          36                                                                               4-I                                                                          37                                                                               2,4-I.sub.2                                                                  38                                                                               2-Cl, 3-F                                                                    39                                                                               2-Cl, 4-F                                                                    40                                                                               2-Cl, 5-F                                                                    41                                                                               2-Cl, 6-F                                                                    42                                                                               2-Cl, 3-Br                                                                   43                                                                               2-Cl, 4-Br                                                                   44                                                                               2-Cl, 6-Br                                                                   45                                                                               2-Cl, 6-Br                                                                   46                                                                               2-Br, 3-Cl                                                                   47                                                                               2-Br, 4-Cl                                                                   48                                                                               2-Br, 5-Cl                                                                   49                                                                               2-Br, 3-F                                                                    50                                                                               2-Br, 4-F                                                                    51                                                                               2-Br, 5-F                                                                    52                                                                               2-Br, 6-F                                                                    53                                                                               2-F, 3-Cl                                                                    54                                                                               2-F, 4-Cl                                                                    55                                                                               2-F, 5-Cl                                                                    56                                                                               3-Cl, 4-F                                                                    57                                                                               3-Cl, 5-F                                                                    58                                                                               3-Cl, 4-Br                                                                   59                                                                               3-Cl, 5-Br                                                                   60                                                                               3-F, 4-Cl                                                                    61                                                                               3-F, 4-Br                                                                    62                                                                               3-Br, 4-Cl                                                                   63                                                                               3-Br, 4-F                                                                    64                                                                               2,6-Cl.sub.2, 4-Br                                                            65a)                                                                            2-CH.sub.3 : non-polar isomer                                                                 51-53                                                         65b)                                                                             2-CH.sub.3 : polar isomer                                                                     79-83                                                         66a                                                                              3-CH.sub.3 : non-polar isomer                                                                 oil   3.9(s, 3H); 4.0(s, 3H);                                                        5.0(s, 2H)                                              66b                                                                              3-CH.sub.3 : polar isomer                                                                     87-89                                                         67a                                                                              4-CH.sub.3 : non-polar isomer                                                                 oil   3.95(s, 3H); 4.05(s, 3H);                                                      5.05(s, 2H)                                             67b                                                                              3-CH.sub.3 : polar isomer                                                                     78-79                                                         68                                                                               2,3-(CH.sub.3).sub.2                                                         69                                                                               2,4-(CH.sub.3).sub.2                                                         70                                                                               2,5-(CH.sub.3).sub.2                                                         71                                                                               2,6-(CH.sub.3).sub.2                                                         72                                                                               3,4-(CH.sub.3).sub.2                                                         73                                                                               3,5-(CH.sub.3).sub.2                                                         74                                                                               3,5-(CH.sub.3).sub.2                                                         75                                                                               2,3,4-(CH.sub.3).sub.3                                                       76                                                                               2,3,6-(CH.sub.3).sub.3                                                       77                                                                               2,4,5-(CH.sub.3).sub.3                                                       78                                                                               2,4,6-(CH.sub.3).sub.3                                                       79                                                                               3,4,5-(CH.sub.3).sub.3                                                       80                                                                               2,3,4,6-(CH.sub.3).sub.4                                                     81                                                                               2,3,5,6-(CH.sub.3).sub.4                                                     82                                                                               2,3,4,5,6-(CH.sub.3).sub.5                                                   83                                                                               2-C.sub.2 H.sub.5                                                            84                                                                               3-C.sub.2 H.sub.5                                                            85                                                                               4-C.sub.2 H.sub.5                                                            86                                                                               2,4-(C.sub.2 H.sub.5).sub.2                                                  87                                                                               2,6-(C.sub.2 H.sub.5).sub.2                                                  88                                                                               3,5-(C.sub.2 H.sub.5).sub. 2                                                 89                                                                               2,4,6-(C.sub.2 H.sub.5).sub.3                                                90                                                                               2-n-C.sub.3 H.sub.7                                                          91                                                                               3-n-C.sub.3 H.sub.7                                                          92                                                                               4-n-C.sub.3 H.sub.7                                                          93                                                                               2-i-C.sub.3 H.sub.7                                                          94                                                                               3-i-C.sub.3 H.sub.7                                                          95                                                                               4-i-C.sub.3 H.sub.7                                                          96                                                                               2,4-(i-C.sub.3 H.sub.7).sub.2                                                97                                                                               2,6-(i-C.sub.3 H.sub.7).sub.2                                                98                                                                               3,5-(i-C.sub.3 H.sub.7).sub.2                                                99                                                                               2,4,6-(i-C.sub.3 H.sub.7).sub.3                                             100                                                                               2-S-C.sub.4 H.sub.9                                                         101                                                                               3-S-C.sub.4 H.sub.9                                                         102                                                                               4-S-C.sub.4 H.sub.9                                                         103                                                                               2-t-C.sub.4 H.sub.9                                                         104                                                                               3-t-C.sub.4 H.sub.9                                                         105                                                                               4-t-C.sub.4 H.sub.9                                                         106                                                                               2,3-(t-C.sub.4 H.sub.9).sub.2                                               107                                                                               2,4-(t-C.sub.4 H.sub.9).sub.2                                               108                                                                               2,5-(t-C.sub.4 H.sub.9).sub.2                                               109                                                                               2,6-(t-C.sub.4 H.sub.9).sub.2                                               110                                                                               3,4-(t-C.sub.4 H.sub.9).sub.2                                               111                                                                               2,4,6-(t-C.sub.4 H.sub.9).sub.3                                             112                                                                               4-n-C.sub.9 H.sub.19                                                        113                                                                               4-n-C.sub.12 H.sub.25                                                       114                                                                               3-n-C.sub.15 H.sub.31                                                       115                                                                               4-(1,1,3,3-tetramethylbutyl)                                                116                                                                               4-(2,4,4-trimethylpropyl                                                    117                                                                               2-t-C.sub.4 H.sub.9, 4-CH.sub.3                                             118                                                                               2-t-C.sub.4 H.sub.9, 5-CH.sub.3                                             119                                                                               2,6-(t-C.sub.4 H.sub.9), 4-CH.sub.3                                         120                                                                               2-CH.sub.3, 4-t-C.sub.4 H.sub.9                                             121                                                                               2-CH.sub.3, 6-t-C.sub.4 H.sub.9                                             122                                                                               2-CH.sub.3, 4-i-C.sub.3 H.sub.7                                             123                                                                               2-CH.sub.3, 5-i-C.sub.3 H.sub.7                                             124                                                                               3-CH.sub.3, 4-i-C.sub.3 H.sub.7                                             125                                                                               2-i-C.sub.3 H.sub.7, 5 CH.sub.3                                             126                                                                               2,4-(t-C.sub.4 H.sub.9), 6-i-C.sub.3 H.sub.7                                127                                                                               2-allyl                                                                     128                                                                               3-allyl                                                                     129                                                                               4-allyl                                                                     130                                                                               2-allyl, 6-CH.sub.3                                                         131                                                                               2-cyclo-C.sub.6 H.sub.11                                                    132                                                                               3-cyclo-C.sub.6 H.sub.11                                                    133                                                                               4-cyclo-C.sub.6 H.sub.11                                                    134                                                                               2,4-(cyclo-C.sub.6 H.sub.11).sub.2, 6-CH.sub.3                              135                                                                               2-CH.sub.3, 4-cyclo-C.sub.6 H.sub.11                                        136                                                                               2-CH.sub.2 C.sub.6 H.sub.5                                                  137                                                                               3-CH.sub.2 C.sub.6 H.sub.5                                                  138                                                                               4-CH.sub.2 C.sub.2 H.sub.5                                                  139                                                                               2-CH.sub.2 C.sub.6 H.sub.5, 4-CH.sub.3                                      140                                                                               2-CH.sub.3, 4-CH.sub.2 C.sub.6 H.sub.5                                      141                                                                               2-C.sub.6 H.sub.5                                                           142                                                                               3-C.sub.6 H.sub.5                                                           143                                                                               4-C.sub.6 H.sub.5                                                           144                                                                               4-(2-i-C.sub.3 H.sub.7 C.sub.6 H.sub.4)                                     145                                                                               4-C.sub.6 H.sub.5, 2,6-(CH.sub.3).sub.2                                     146                                                                               2-Cl, 4-C.sub.6 H.sub.5                                                     147                                                                               2-Br, 4-C.sub.6 H.sub.5                                                     148                                                                               2-C.sub.6 H.sub.5, 4-Cl                                                     149                                                                               2-C.sub.6 H.sub.5 , 4-Br                                                    150                                                                               2-CH.sub.2 C.sub.6 H.sub.5, 4-Cl                                            151                                                                               2-CH.sub.2 C.sub.6 H.sub.5, 4-Br                                            152                                                                               2-Cl, 4-CH.sub.2 C.sub.6 H.sub.5                                            153                                                                               2-Br, 4-CH.sub.2 C.sub.6 H.sub.5                                            154                                                                               2-cyclo-C.sub.6 H.sub.11, 4-Cl                                              155                                                                               2-cyclo-C.sub.6 H.sub.11, 4-Br                                              156                                                                               2-Cl, 4-cyclo-C.sub.6 H.sub.11                                              157                                                                               2-Br, 4-cyclo-C.sub.6 H.sub.11                                              158                                                                               2-OCH.sub.3                                                                 159a                                                                              3-OCH.sub.3 :  oil   3.80; 3, 95, 4.05(3s, 3H                                  non-polar isomer     in each case); 5.05(s, 2H)                             159b                                                                              3-OCH.sub.3 :  oil   3.80; 3.90, 4.05(3s, 3H                                   polar isomer         in each case); 5.05(s, 2H)                             160                                                                               4-OCH.sub.3                                                                 161                                                                               2-OC.sub.2 H.sub.5                                                          162                                                                               3-O-C.sub.2 H.sub.5                                                         163                                                                               4-O-C.sub.2 H.sub.5                                                         164                                                                               2-O-n-C.sub.3 H.sub.7                                                       165                                                                               3-O-n-C.sub.3 H.sub.7                                                       166                                                                               4-O-n-C.sub.3 H.sub.7                                                       167                                                                               2-O-i-C.sub.3 H.sub.7                                                       168                                                                               3-O-i-C.sub.3 H.sub.7                                                       169                                                                               4-O-i-C.sub.3 H.sub.7                                                       170                                                                               2-O-n-C.sub.6 H.sub.13                                                      171                                                                               3-O-n-C.sub.6 H.sub.13                                                      172                                                                               4-O-n-C.sub.6 H.sub.13                                                      173                                                                               2-O-n-C.sub.8 H.sub.17                                                      174                                                                               3-O-n-C.sub.8 H.sub.17                                                      175                                                                               4-O-n-C.sub.8 H.sub.17                                                      176                                                                               2-O-CH.sub.2 C.sub.6 H.sub.5                                                177                                                                               3-O-CH.sub.2 C.sub.6 H.sub.5                                                178                                                                               4-O-CH.sub.2 C.sub.6 H.sub. 5                                               179                                                                               2-O-(CH.sub.2).sub.3 C.sub.6 H.sub.5                                        180                                                                               3-O-(CH.sub.2).sub.3 C.sub.6 H.sub.5                                        181                                                                               4-O-(CH.sub.2).sub.3 C.sub.6 H.sub.5                                        182                                                                               2,4-(OCH.sub.3).sub.2                                                       183                                                                               2-CF.sub.3                                                                  184                                                                               3-CF.sub.3                                                                  185                                                                               4-CF.sub.3                                                                  186                                                                               2-OCF.sub.3                                                                 187                                                                               3-OCF.sub.3                                                                 188                                                                               4-OCF.sub.3                                                                 189                                                                               3-OCH.sub.2 CHF.sub.2                                                       190                                                                               2-NO.sub.2                                                                  191                                                                               3-NO.sub.2                                                                  192                                                                               4-NO.sub.2                                                                  193                                                                               2-CN                                                                        194                                                                               3-CN                                                                        195                                                                               4-CN                                                                        196                                                                               2-CH.sub.3, 3-Cl                                                            197                                                                               2-CH.sub.3, 4-Cl                                                            198                                                                               2-CH.sub.3, 5-Cl                                                            199                                                                               2-CH.sub.3, 6-Cl                                                            200                                                                               2-CH.sub.3, 3-F                                                             201                                                                               2-CH.sub.3, 4-F                                                             202                                                                               2-CH.sub.3, 5-F                                                             203                                                                               2-CH.sub.3, 6-F                                                             204                                                                               2-CH.sub.3, 3-Br                                                            205                                                                               2-CH.sub.3, 4-Br                                                            206                                                                               2-CH.sub.3, 5-Br                                                            207                                                                               2-CH.sub.3, 6-Br                                                            208                                                                               2-Cl, 3-CH.sub.3                                                            209                                                                               2-Cl, 4-CH.sub.3                                                            210                                                                               2-Cl, 5-CH.sub.3                                                            211                                                                               2-F, 3-CH.sub.3                                                             212                                                                               2-F, 4-CH.sub.3                                                             213                                                                               2-F, 5-CH.sub.3                                                             214                                                                               2-Br, 3-CH.sub.3                                                            215                                                                               2-Br, 4-CH.sub.3                                                            216                                                                               2-Br, 5-CH.sub.3                                                            217                                                                               3-CH.sub.3, 4-Cl                                                            218                                                                               3-CH.sub.3, 5-Cl                                                            219                                                                               3-CH.sub.3, 4-F                                                             220                                                                               3-CH.sub.3, 4-Br                                                            221                                                                               3-CH.sub.3, 4-Br                                                            222                                                                               3-CH.sub.3, 5-Br                                                            223                                                                               3-F, 4-CH.sub. 3                                                            224                                                                               3-Cl, 4-CH.sub.3                                                            225                                                                               3-Br, 4-CH.sub.3                                                            226                                                                               2-Cl, 4,5-(CH.sub.3).sub.2                                                  227                                                                               2-Br, 4,5-(CH.sub.3).sub.2                                                  228                                                                               2-Cl, 3,5-(CH.sub.3).sub.2                                                  229                                                                               2-Br, 3,5-(CH.sub.3).sub.2                                                  230                                                                               2,6-Cl.sub.2, 4-CH.sub.3                                                    231                                                                               2,6-F.sub.2, 4-CH.sub.3                                                     232                                                                               2,6-Br.sub.2, 4-CH.sub.3                                                    233                                                                               2,4-Cl.sub.2, 6-CH.sub.3                                                    234                                                                               2,4-F.sub.2, 6-CH.sub.3                                                     235                                                                               2,4-Br.sub.2, 6-CH.sub.3                                                    236                                                                               2,6-(CH.sub.3).sub.2, 4-F                                                   237                                                                               2,6-(CH.sub.3).sub.2, 4-Cl                                                  238                                                                               2,6-(CH.sub.3).sub.2, 4-Br                                                  239                                                                               3,5-(CH.sub.3).sub.2, 4-F                                                   240                                                                               3,5-(CH.sub.3).sub.2, 4-Cl                                                  241                                                                               3,5-(CH.sub.3).sub.2, 4-Br                                                  242                                                                               2,3,6-(CH.sub.3).sub.3, 4-F                                                 243                                                                               2,3,6-(CH.sub.3).sub.3, 4-Cl                                                244                                                                               2,3,6-(CH.sub.3).sub.3, 4-Br                                                245                                                                               2,4-(CH.sub.3).sub.2, 6-F                                                   246                                                                               2,4-(CH.sub.3).sub.2, 6-Cl                                                  247                                                                               2,4-(CH.sub.3).sub.62, 6-Br                                                 248                                                                               2-i-C.sub.3 H.sub.7, 4-Cl, 5-CH.sub.3                                       249                                                                               2-Cl, 4-NO.sub.2                                                            250                                                                               2-NO.sub.2, 4-Cl                                                            251                                                                               2-OCH.sub.3, 5-NO.sub.2                                                     252                                                                               2,4-Cl.sub.2, 5-NO.sub.2                                                    253                                                                               2,4-Cl.sub.2, 6-NO.sub.2                                                    254                                                                               2,6-Cl.sub.2, 4-NO.sub.2                                                    255                                                                               2,6-Br.sub.2, 4-NO.sub. 2                                                   256                                                                               2,6-I.sub.2, 4-NO.sub.2                                                     257                                                                               2-CH.sub.3, 5-i-C.sub.3 H.sub.7, 4-Cl                                       258                                                                               2-C.sub.6 H.sub.5 O                                                         259                                                                               3-C.sub.6 H.sub.5 O                                                         260                                                                               4-C.sub.6 H.sub.5 O                                                         261                                                                               2-CHNOCH.sub.3                                                              262                                                                               3-CHNOCH.sub.3                                                              263                                                                               4-CHNOCH.sub.3                                                              264                                                                               2-CHNOC.sub.2 H.sub.5                                                       265                                                                               3-CHNOC.sub.2 H.sub.5                                                       266                                                                               4-CHNOC.sub.2 H.sub.5                                                       267                                                                               2-CHNO(n-C.sub.3 H.sub.7)                                                   268                                                                               3-CHNO(n-C.sub.3 H.sub.7)                                                   269                                                                               4-CHNO(n-C.sub.3 H.sub.7)                                                   270                                                                               2-CHNO(i-C.sub.3 H.sub.7)                                                   271                                                                               3-CHNO(i-C.sub.3 H.sub.7)                                                   272                                                                               4-CHNO(i-C.sub.3 H.sub.7)                                                   273                                                                               2-CHNO(n-C.sub.6 H.sub.13)                                                  274                                                                               3-CHNO(n-C.sub.6 H.sub.13)                                                  275                                                                               4-CHNO(n-C.sub.6 H.sub.13)                                                  276                                                                               2-CHNO(n-C.sub.8 H.sub.17)                                                  277                                                                               3-CHNO(n-C.sub.8 H.sub.17)                                                  278                                                                               4-CHNO(n-C.sub.8 H.sub.17)                                                  279                                                                               2-CHNOCH.sub.2 (C.sub.6 H.sub.5)                                            280                                                                               3-CHNOCH.sub.2 (C.sub.6 H.sub.5)                                            281                                                                               4-CHNOCH.sub.2 (C.sub.6 H.sub.5)                                            282                                                                               2-CO.sub.2 CH.sub.3                                                         283                                                                               3-CO.sub.2 CH.sub.3                                                         284                                                                               4-CO.sub.2 CH.sub.3                                                         285                                                                               2-CO.sub.2 (C.sub.2 H.sub.5)                                                286                                                                               3-CO.sub.2 (C.sub.2 H.sub.5)                                                287                                                                               4-CO.sub.2 (C.sub.2 H.sub.5)                                                288                                                                               2-CO.sub.2 (n-C.sub.3 H.sub. 7)                                             289                                                                               3-CO.sub.2 (n-C.sub.3 H.sub.7)                                              290                                                                               4-CO.sub.2 (n-C.sub.3 H.sub.7)                                              291                                                                               2-CO.sub.2 (i-C.sub.3 H.sub.7)                                              292                                                                               3-CO.sub.2 (i-C.sub.3 H.sub.7)                                              293                                                                               4-CO.sub.2 (i-C.sub.3 H.sub.7)                                              294                                                                               2-CO.sub.2 (n-C.sub.6 H.sub.13)                                             295                                                                               3-CO.sub.2 (n-C.sub.6 H.sub.13)                                             296                                                                               4-CO.sub.2 (n-C.sub.6 H.sub.13)                                             297                                                                               2-CO.sub.2 (n-C.sub.8 H.sub.17)                                             298                                                                               3-CO.sub.2 (n-C.sub.8 H.sub.17)                                             299                                                                               4-CO.sub.2 (n-C.sub.8 H.sub.17)                                             300                                                                               2-CHNOCH.sub.2 CHCH.sub.2                                                   301                                                                               3-CHNOCH.sub.2 CHCH.sub.2                                                   302                                                                               4-CHNOCH.sub.2 CHCH.sub.2                                                   303                                                                               2-CHNO(CH.sub.2).sub.3 (C.sub.6 H.sub.5)                                    304                                                                               3-CHNO(CH.sub.2).sub.3 (C.sub.6 H.sub.5)                                    305                                                                               4-CHNO(CH.sub.2).sub.3 (C.sub.6 H.sub.5)                                    306                                                                               2-CH.sub.2 OCH.sub.3                                                        307                                                                               3-CH.sub.2 OCH.sub.3                                                        308                                                                               4-CH.sub.2 OCH.sub.3                                                        309                                                                               2-CH.sub.2 O(C.sub.2 H.sub.5)                                               310                                                                               3-CH.sub.2 O(C.sub.2 H.sub.5)                                               311                                                                               4-CH.sub.2 O(C.sub.2 H.sub.5)                                               312                                                                               2-CH.sub.2 O(n-C.sub.3 H.sub.7)                                             313                                                                               3-CH.sub.2 O(n-C.sub.3 H.sub.7)                                             314                                                                               4-CH.sub.2 O(n-C.sub.3 H.sub.7 )                                            315                                                                               2-CH.sub.2 O(i-C.sub.3 H.sub.7)                                             316                                                                               3-CH.sub.2 O(i-C.sub.3 H.sub.7)                                             317                                                                               4-(CH.sub.2 O(i-C.sub.3 H.sub.7)                                            318                                                                               2-CH.sub.2 O(n-C.sub.6 H.sub.13)                                            319                                                                               3-CH.sub.2 O(n-C.sub.6 H.sub.13)                                            320                                                                               4-CH.sub.2 O(n-C.sub.6 H.sub.13)                                            321                                                                               2-CH.sub.2 O(n-C.sub.8 H.sub.17)                                            322                                                                               3-CH.sub.2 O(n-C.sub.8 H.sub.17)                                            323                                                                               4-CH.sub.2 O(n-C.sub.8 H.sub.7)                                             324                                                                               2-CH.sub.2 OCH.sub.2 (C.sub.6 H.sub.5)                                      325                                                                               3-CH.sub.2 OCH.sub.2 (C.sub.6 H.sub.5)                                      326                                                                               4-CH.sub.2 OCH.sub.2 (C.sub.6 H.sub.5)                                      327                                                                               2-CH.sub.2 O(CH.sub.2).sub.3                                                328                                                                               3-CH.sub.2 O(CH.sub.2).sub.3 (C.sub.6 H.sub.5)                              329                                                                               4-CH.sub.2 O(CH.sub.2).sub.3 (C.sub.6 H.sub.5)                              330                                                                               2-CHO                                                                       331                                                                               3-CHO                                                                       332                                                                               4-CHO                                                                       __________________________________________________________________________

                  TABLE 9                                                          ______________________________________                                          ##STR36##                                                                     No.   X.sub.m            mp    NMR: δ (ppm)                              ______________________________________                                          1    2-F                                                                       2    3-F                                                                       3    4-F                                                                       4    2,4-F.sub.2                                                               5    2,4,6-F.sub.3                                                             6    2,3,4,5,6,-F.sub.5                                                        7    2,3-F.sub.2                                                               8    2-Cl                                                                      9    3-Cl                                                                      10   4-Cl                                                                      11   2,3-Cl.sub.2                                                              12   2,4-Cl.sub.2                                                              13   2,5-Cl.sub.2                                                              14   2,6-Cl.sub.2                                                              15   3,4-Cl.sub.2                                                              16   3,5-Cl.sub.2                                                              17   2,3,4-Cl.sub.3                                                            18   2,3,5-Cl.sub.3                                                            19   2,3,6-Cl.sub.3                                                            20   2,4,5-Cl.sub.3                                                            21   2,4,6-Cl.sub.3                                                            22   3,4,5-Cl.sub.3                                                            23   2,3,4,6-Cl.sub.4                                                          24   2,3,5,6-Cl.sub.4                                                          25   2,3,4,5,6,-Cl.sub.5                                                       26   2-Br                                                                      27   3-Br                                                                      28   4-Br                                                                      29   2,4-Br.sub.2                                                              30   2,5-Br.sub.5                                                              31   2,6-Br.sub.2                                                              32   2,4,6-Br.sub.3                                                            33   2,3,4,5,6-Br.sub.5                                                        34   2-I                                                                       35   3-I                                                                       36   4-I                                                                       37   2,4-I.sub.2                                                               38   2-Cl, 3-F                                                                 39   2-Cl, 4-F                                                                 40   2-Cl, 5-F                                                                 41   2-Cl, 6-F                                                                 42   2-Cl, 3-Br                                                                43   2-Cl, 4-Br                                                                44   2-Cl, 6-Br                                                                45   2-Cl, 6-Br                                                                46   2-Br, 3-Cl                                                                47   2-Br, 4-Cl                                                                48   2-Br, 5-Cl                                                                49   2-Br, 3-F                                                                 50   2-Br, 4-F                                                                 51   2-Br, 5-F                                                                 52   2-Br, 6-F                                                                 53   2-F, 3-Cl                                                                 54   2-F, 4-Cl                                                                 55   2-F, 5-Cl                                                                 56   3-Cl, 4-F                                                                 57   3-Cl, 5-F                                                                 58   3-Cl, 4-Br                                                                59   3-Cl, 5-Br                                                                60   3-F, 4-Cl                                                                 61   3-F, 4-Br                                                                 62   3-Br, 4-Cl                                                                63   3-Br, 4-F                                                                 64   2,6-Cl.sub.2, 4-Br                                                        65   2-CH.sub.3                                                                66   3-CH.sub.3                                                                67   4-CH.sub.3                                                                68   2,3-(CH.sub.3).sub.2                                                      69   2,4-(CH.sub.3).sub.2                                                      70   2,5-(CH.sub.3).sub.2                                                      71   2,6-(CH.sub.3).sub.2                                                      72   3,4-(CH.sub.3).sub.2                                                      73   3,5-(CH.sub.3).sub.2                                                      74   3,5-(CH.sub.3).sub.2                                                      75   2,3,4-(CH.sub.3).sub.3                                                    76   2,3,6-(CH.sub.3).sub.3                                                    77   2,4,5-(CH.sub.3).sub.3                                                    78   2,4,6-(CH.sub.3).sub.3                                                    79   3,4,5-(CH.sub.3).sub.3                                                    80   2,3,4,6-(CH.sub.3).sub.4                                                  81   2,3,5,6-(CH.sub.3).sub.4                                                  82   2,3,4,5,6-(CH.sub.3 ).sub.5                                               83   2-C.sub.2 H.sub.5                                                         84   3-C.sub.2 H.sub.5                                                         85   4-C.sub.2 H.sub.5                                                         86   2,4-(C.sub.2 H.sub.5).sub.2                                               87   2,6-(C.sub.2 H.sub.5).sub.2                                               88   3,5-(C.sub.2 H.sub.5).sub.2                                               89   2,4,6-(C.sub.2 H.sub.5).sub.3                                             90   2-n-C.sub.3 H.sub.7                                                       91   3-n-C.sub.3 H.sub.7                                                       92   4-n-C.sub.3 H.sub.7                                                       93   2-i-C.sub.3 H.sub.7                                                       94   3-i-C.sub.3 H.sub.7                                                       95   4-i-C.sub.3 H.sub.7                                                       96   2,4-(i-C.sub.3 H.sub.7).sub.2                                             97   2,6-(i-C.sub.3 H.sub.7).sub.2                                             98   3,5-(i-C.sub.3 H.sub.7).sub.2                                             99   2,4,6-(i-C.sub.3 H.sub.7).sub.3                                          100   2-S-C.sub.4 H.sub.9                                                      101   3-S-C.sub.4 H.sub.9                                                      102   4-S-C.sub.4 H.sub.9                                                      103   2-t-C.sub.4 H.sub.9                                                      104   3-t-C.sub.4 H.sub.9                                                      105   4-t-C.sub.4 H.sub.9                                                      106   2,3-(t-C.sub.4 H.sub.9).sub.2                                            107   2,4-(t-C.sub.4 H.sub.9).sub.2                                            108   2,5-(t-C.sub.4 H.sub.9).sub.2                                            109   2,6-(t-C.sub.4 H.sub.9).sub.2                                            110   3,4-(t-C.sub.4 H.sub.9).sub.2                                            111   2,4,6-(t-C.sub.4 H.sub.9).sub.3                                          112   4-n-C.sub.9 H.sub.19                                                     113   4-n-C.sub.12 H.sub.25                                                    114   3-n-C.sub.15 H.sub.31                                                    115   4-(1,1,3,3-tetramethylbutyl)                                             116   4-(2,4,4-trimethylpropyl                                                 117   2-t-C.sub.4 H.sub.9, 4-CH.sub.3                                          118   2-t-C.sub.4 H.sub.9, 5-CH.sub.3                                          119   2,6-(t-C.sub.4 H.sub.9), 4-CH.sub.3                                      120   2-CH.sub.3, 4-t-C.sub.4 H.sub.9                                          121   2-CH.sub.3, 6-t-C.sub.4 H.sub.9                                          122   2-CH.sub.3, 4-i-C.sub.3 H.sub.7                                          123   2-CH.sub.3, 5-i-C.sub.3 H.sub.7                                          124   3-CH.sub.3, 4-i-C.sub.3 H.sub.7                                          125   2-i-C.sub.3 H.sub.7, 5 CH.sub.3                                          126   2,4-(t-C.sub.4 H.sub.9), 6-i-C.sub.3 H.sub.7                             127   2-allyl                                                                  128   3-allyl                                                                  129   4-allyl                                                                  130   2-allyl, 6-CH.sub.3                                                      131   2-cyclo-C.sub.6 H.sub.11                                                 132   3-cyclo-C.sub.6 H.sub.11                                                 133   4-cyclo-C.sub.6 H.sub.11                                                 134   2,4-(cyclo-C.sub.6 H.sub.11).sub.2, 6-CH.sub.3                           135   2-CH.sub.3, 4-cyclo-C.sub.6 H.sub.11                                     136   2-CH.sub.2 -C.sub.6 H.sub.5                                              137   3-CH.sub.2 -C.sub.6 H.sub.5                                              138   4-CH.sub.2 -C.sub.2 H.sub.5                                              139   2-CH.sub.2 -C.sub.6 H.sub.5, 4-CH.sub.3                                  140   2-CH.sub.3, 4-CH.sub.2 -C.sub.6 H.sub.5                                  141   2-C.sub.6 H.sub.5                                                        142   3-C.sub.6 H.sub.5                                                        143   4-C.sub.6 H.sub.5                                                        144   4-(2-i-C.sub.3 H.sub.7 -C.sub.6 H.sub.4)                                 145   4-C.sub.6 H.sub.5, 2,6-(CH.sub.3).sub.2                                  146   2-Cl, 4-C.sub.6 H.sub.5                                                  147   2-Br, 4-C.sub.6 H.sub.5                                                  148   2-C.sub.6 H.sub.5, 4-Cl                                                  149   2-C.sub.6 H.sub.5, 4-Br                                                  150   2-CH.sub.2 C.sub.6 H.sub.5, 4-Cl                                         151   2-CH.sub.2 C.sub.6 H.sub.5, 5-Br                                         152   2-Cl, 4-CH.sub.2 C.sub.6 H.sub.5                                         153   2-Br, 4-CH.sub.2 C.sub.6 H.sub.5                                         154   2-cyclo-C.sub.6 H.sub.11, 4-Cl                                           155   2-cyclo-C.sub.6 H.sub.11, 4-Br                                           156   2-Cl, 4-cyclo-C.sub.6 H.sub.11                                           157   2-Br, 4-cyclo-C.sub.6 H.sub.11                                           158   2-OCH.sub.3                                                              159   3-OCH.sub.3                                                              160   4-OCH.sub.3                                                              161   2-OC.sub.2 H.sub.5                                                       162   3-O-C.sub.2 H.sub.5                                                      163   4-O-C.sub.2 H.sub.5                                                      164   2-O-n-C.sub.3 H.sub.7                                                    165   3-O-n-C.sub.3 H.sub.7                                                    166   4-O-n-C.sub.3 H.sub.7                                                    167   2-O-i-C.sub.3 H.sub.7                                                    168   3-O-i-C.sub.3 H.sub.7                                                    169   4-O-i-C.sub.3 H.sub.7                                                    170   2-O-n-C.sub.6 H.sub.13                                                   171   3-O-n-C.sub.6 H.sub.13                                                   172   4-O-n-C.sub.6 H.sub.13                                                   173   2-O-n-C.sub.8 H.sub.17                                                   174   3-O-n-C.sub.8 H.sub.17                                                   175   4-O-n-C.sub.8 H.sub.17                                                   176   2-O-CH.sub.2 C.sub.6 H.sub.5                                             177   3-O-CH.sub.2 C.sub.6 H.sub.5                                             178   4-O-CH.sub.2 C.sub.6 H.sub.5                                             179   2-O-(CH.sub.2).sub.3 C.sub.6 H.sub.5                                     180   3-O-(CH.sub.2).sub.3 C.sub.6 H.sub.5                                     181   4-O-(CH.sub.2).sub.3 C.sub.6 H.sub.5                                     182   2,4-(OCH.sub.3).sub.2                                                    183   2-CF.sub.3                                                               184   3-CF.sub.3                                                               185   4-CF.sub.3                                                               186   2-OCF.sub.3                                                              187   3-OCF.sub.3                                                              188   4-OCF.sub.3                                                              189   3-OCH.sub.2 CHF.sub.2                                                    190   2-NO.sub.2                                                               191   3-NO.sub.2                                                               192   4-NO.sub.2                                                               193   2-CN                                                                     194   3-CN                                                                     195   4-CN                                                                     196   2-CH.sub.3, 3-Cl                                                         197   2-CH.sub.3, 4-Cl                                                         198   2-CH.sub.3, 5-Cl                                                         199   2-CH.sub.3, 6-Cl                                                         200   2-CH.sub.3, 3-F                                                          201   2-CH.sub.3, 4-F                                                          202   2-CH.sub.3, 5-F                                                          203   2-CH.sub.3, 6-F                                                          204   2-CH.sub.3, 3-Br                                                         205   2-CH.sub.3, 4-Br                                                         206   2-CH.sub.3, 5-Br                                                         207   2-CH.sub.3, 6-Br                                                         208   2-Cl, 3-CH.sub.3                                                         209   2-Cl, 4-CH.sub.3                                                         210   2-Cl, 5-CH.sub.3                                                         211   2-F, 3-CH.sub.3                                                          212   2-F, 4-CH.sub.3                                                          213   2-F, 5-CH.sub.3                                                          214   2-Br, 3-CH.sub.3                                                         215   2-Br, 4-CH.sub.3                                                         216   2-Br, 5-CH.sub.3                                                         217   3-CH.sub.3, 4-Cl                                                         218   3-CH.sub.3, 5-Cl                                                         219   3-CH.sub.3, 4-F                                                          220   3-CH.sub.3, 4-Br                                                         221   3-CH.sub.3, 4-Br                                                         222   3-CH.sub.3, 5-Br                                                         223   3-F, 4-CH.sub.3                                                          224   3-Cl, 4-CH.sub.3                                                         225   3-Br, 4-CH.sub.3                                                         226   2-Cl, 4,5-(CH.sub.3).sub.2                                               227   2-Br, 4,5-(CH.sub.3).sub.2                                               228   2-Cl, 3,5-(CH.sub.3).sub.2                                               229   2-Br, 3,5-(CH.sub.3).sub.2                                               230   2,6-Cl.sub.2, 4-CH.sub.3                                                 231   2,6-F.sub.2, 4-CH.sub.3                                                  232   2,6-Br.sub.2, 4-CH.sub.3                                                 233   2,4-Cl.sub.2, 6-CH.sub.3                                                 234   2,4-F.sub.2, 6-CH.sub.3                                                  235   2,4-Br.sub.2, 6-CH.sub.3                                                 236   2,6-(CH.sub.3).sub.2, 4-F                                                237   2,6-(CH.sub.3).sub.2, 4-Cl                                               238   2,6-(CH.sub.3).sub.2, 4-Br                                               239   3,5-(CH.sub.3).sub.2, 4-F                                                240   3,5-(CH.sub.3).sub.2, 4-Cl                                               241   3,5-(CH.sub.3).sub.2, 4-Br                                               242   2,3,6-(CH.sub.3).sub.3, 4-F                                              243   2,3,6-(CH.sub.3).sub.3, 4-Cl                                             244   2,3,6-(CH.sub.3).sub.3, 4-Br                                             245   2,4-(CH.sub.3).sub.2, 6-F                                                246   2,4-(CH.sub.3).sub.2, 6-Cl                                               247   2,4-(CH.sub.3)62, 6-Br                                                   248   2-i-C.sub.3 H.sub.7, 4-Cl, 5-CH.sub.3                                    249   2-Cl, 4-NO.sub.2                                                         250   2-NO.sub.2, 4-Cl                                                         251   2-OCH.sub.3, 5-NO.sub.2                                                  252   2,4-Cl.sub.2, 5-NO.sub.2                                                 253   2,4-Cl.sub.2, 6-NO.sub.2                                                 254   2,6-Cl.sub.2, 4-NO.sub.2                                                 255   2,6-Br.sub.2 , 4-NO.sub.2                                                256   2,6-I.sub.2, 4-NO.sub.2                                                  257   2-CH.sub.3, 5-i-C.sub.3 H.sub.7, 4-Cl                                    258   2-C.sub.6 H.sub.5 O                                                      259   3-C.sub.6 H.sub.5 O                                                      260   4-C.sub.6 H.sub.5 O                                                      261   2-CHNOCH.sub.3                                                           262   3-CHNOCH.sub.3                                                           263   4-CHNOCH.sub.3                                                           264   2-CHNOC.sub.2 H.sub.5                                                    265   3-CHNOC.sub.2 H.sub.5                                                    266   4-CHNOC.sub.2 H.sub.5                                                    267   2-CHNO(n-C.sub.3 H.sub.7)                                                268   3-CHNO(n-C.sub.3 H.sub.7)                                                269   4-CHNO(n-C.sub.3 H.sub.7)                                                270   2-CHNO(i-C.sub.3 H.sub.7)                                                271   3-CHNO(i-C.sub.3 H.sub.7)                                                272   4-CHNO(i-C.sub.3 H.sub.7)                                                273   2-CHNO(n-C.sub.6 H.sub.13)                                               274   3-CHNO(n-C.sub.6 H.sub.13)                                               275   4-CHNO(n-C.sub.6 H.sub.13)                                               276   2-CHNO(n-C.sub.8 H.sub.17)                                               277   3-CHNO(n-C.sub.8 H.sub.17)                                               278   4-CHNO(n-C.sub.8 H.sub.17)                                               279   2-CHNOCH.sub.2 (C.sub.6 H.sub.5)                                         280   3-CHNOCH.sub.2 (C.sub.6 H.sub.5)                                         281   4-CHNOCH.sub.2 (C.sub.6 H.sub.5)                                         282   2-CO.sub.2 CH.sub.3                                                      283   3-CO.sub.2 CH.sub.3                                                      284   4-CO.sub.2 CH.sub.3                                                      285   2-CO.sub.2 (C.sub.2 H.sub.5)                                             286   3-CO.sub.2 (C.sub.2 H.sub.5)                                             287   4-CO.sub.2 (C.sub.2 H.sub.5)                                             288   2-CO.sub.2 (n-C.sub.3 H.sub.7)                                           289   3-CO.sub.2 (n-C.sub.3 H.sub.7)                                           290   4-CO.sub.2 (n-C.sub.3 H.sub.7)                                           291   2-CO.sub.2 (i-C.sub.3 H.sub.7)                                           292   3-CO.sub.2 (i-C.sub.3 H.sub.7)                                           293   4-CO.sub.2 (i-C.sub.3 H.sub.7)                                           294   2-CO.sub.2 (n-C.sub.6 H.sub.13)                                          295   3-CO.sub.2 (n-C.sub.6 H.sub.13)                                          296   4-CO.sub.2 (n-C.sub.6 H.sub.13)                                          297   2-CO.sub.2 (n-C.sub.8 H.sub.17)                                          298   3-CO.sub.2 (n-C.sub.8 H.sub.17)                                          299   4-CO.sub.2 (n-C.sub.8 H.sub.17)                                          300   2-CHNOCH.sub.2 CHCH.sub.2                                                301   3-CHNOCH.sub.2 CHCH.sub.2                                                302   4-CHNOCH.sub.2 CHCH.sub.2                                                303   2-CHNO(CH.sub.2).sub.3 (C.sub.6 H.sub.5)                                 304   3-CHNO(CH.sub.2).sub.3 (C.sub.6 H.sub.5)                                 305   4-CHNO(CH.sub.2).sub.3 (C.sub.6 H.sub.5)                                 306   2-CH.sub.2 OCH.sub.3                                                     307   3-CH.sub.2 OCH.sub.3                                                     308   4-CH.sub.2 OCH.sub.3                                                     309   2-CH.sub.2 O(C.sub.2 H.sub.5)                                            310   3-CH.sub.2 O(C.sub.2 H.sub.5)                                            311   4-CH.sub.2 O(C.sub.2 H.sub.5)                                            312   2-CH.sub.2 O(n-C.sub.3 H.sub.7)                                          313   3-CH.sub.2 O(n-C.sub.3 H.sub.7)                                          314   4-CH.sub.2 O(n-C.sub.3 H.sub.7)                                          315   2-CH.sub.2 O(i-C.sub.3 H.sub.7)                                          316   3-CH.sub.2 O(i-C.sub.3 H.sub.7)                                          317   4-(CH.sub.2 O(i-C.sub.3 H.sub.7)                                         318   2-CH.sub.2 O(n-C.sub.6 H.sub.13)                                         319   3-CH.sub.2 O(n-C.sub.6 H.sub.13)                                         320   4-CH.sub.2 O(n-C.sub.6 H.sub.13)                                         321   2-CH.sub.2 O(n-C.sub.8 H.sub.17)                                         322   3-CH.sub.2 O(n-C.sub.8 H.sub.17)                                         323   4-CH.sub.2 O(n-C.sub.8 H.sub.7)                                          324   2-CH.sub.2 OCH.sub.2 (C.sub.6 H.sub.5)                                   325   3-CH.sub.2 OCH.sub.2 (C.sub.6 H.sub.5)                                   326   4-CH.sub.2 OCH.sub.2 (C.sub.6 H.sub.5)                                   327   2-CH.sub.2 O(CH.sub.2).sub.3                                             328   3-CH.sub.2 O(CH.sub.2).sub.3 (C.sub.6 H.sub.5)                           329   4-CH.sub.2 O(CH.sub.2).sub.3 (C.sub.6 H.sub.5)                           330   2-CHO                                                                    331   3-CHO                                                                    332   4-CHO                                                                    ______________________________________                                    

                  TABLE 10                                                         ______________________________________                                          ##STR37##                                                                     No.   X.sub.m            mp     NMR: δ (ppm)                             ______________________________________                                         1     2-F                                                                      2     3-F                                                                      3     4-F                                                                      4     2,4-F.sub.2                                                              5     2,4,6-F.sub.3                                                            6     2,3,4,5,6-F.sub.5                                                        7     2,3-F.sub.2                                                              8     2-Cl                                                                     9     3-Cl                                                                     10    4-Cl                                                                     11    2,3-Cl.sub.2                                                             12    2,4-Cl.sub.2                                                             13    2,5-Cl.sub.2                                                             14    2,6-Cl.sub.2                                                             15    3,4-Cl.sub.2                                                             16    3,5-Cl.sub.2                                                             17    2,3,4-Cl.sub.3                                                           18    2,3,5-Cl.sub.3                                                           19    2,3,6-Cl.sub.3                                                           20    2,4,5-Cl.sub.3                                                           21    2,4,6-Cl.sub.3                                                           22    3,4,5-Cl.sub.3                                                           23    2,3,4,6-Cl.sub.4                                                         24    2,3,5,6-Cl.sub.4                                                         25    2,3,4,5,6-Cl.sub.5                                                       26    2-Br                                                                     27    3-Br                                                                     28    4-Br                                                                     29    2,4-Br.sub.2                                                             30    2,5-Br.sub.5                                                             31    2,6-Br.sub.2                                                             32    2,4,6-Br.sub.3                                                           33    2,3,4,5,6-Br.sub.5                                                       34    2-I                                                                      35    3-I                                                                      36    4-I                                                                      37    2,4-I.sub.2                                                              38    2-Cl, 3-F                                                                39    2-Cl, 4-F                                                                40    2-Cl, 5-F                                                                41    2-Cl, 6-F                                                                42    2-Cl, 3-Br                                                               43    2-Cl, 4-Br                                                               44    2-Cl, 6-Br                                                               45    2-Cl, 6-Br                                                               46    2-Br, 3-Cl                                                               47    2-Br, 4-Cl                                                               48    2-Br, 5-Cl                                                               49    2-Br, 3-F                                                                50    2-Br, 4-F                                                                51    2-Br, 5-F                                                                52    2-Br, 6-F                                                                53    2-F, 3-Cl                                                                54    2-F, 4-Cl                                                                55    2-F, 5-Cl                                                                56    3-Cl, 4-F                                                                57    3-Cl, 5-F                                                                58    3-Cl, 4-Br                                                               59    3-Cl, 5-Br                                                               60    3-F, 4-Cl                                                                61    3-F, 4-Br                                                                62    3-Br, 4-Cl                                                               63    3-Br, 4-F                                                                64    2,6-Cl.sub.2, 4-Br                                                       65    2-CH.sub.3                                                               66    3-CH.sub.3                                                               67    4-CH.sub.3                                                               68    2,3-(CH.sub.3).sub.2                                                     69    2,4-(CH.sub.3).sub.2                                                     70    2,5-(CH.sub.3).sub.2                                                     71    2,6-(CH.sub.3).sub.2                                                     72    3,4-(CH.sub.3).sub.2                                                     73    3,5-(CH.sub.3).sub.2                                                     74    3,5-(CH.sub.3).sub.2                                                     75    2,3,4-(CH.sub.3).sub.3                                                   76    2,3,6-(CH.sub.3).sub.3                                                   77    2,4,5-(CH.sub.3).sub.3                                                   78    2,4,6-(CH.sub.3).sub.3                                                   79    3,4,5-(CH.sub.3).sub.3                                                   80    2,3,4,6-(CH.sub.3).sub.4                                                 81    2,3,5,6-(CH.sub.3).sub.4                                                 82    2,3,4,5,6-(CH.sub.3).sub.5                                               83    2-C.sub.2 H.sub.5                                                        84    3-C.sub.2 H.sub.5                                                        85    4-C.sub.2 H.sub.5                                                        86    2,4-(C.sub.2 H.sub.5).sub.2                                              87    2,6-(C.sub.2 H.sub.5).sub.2                                              88    3,5-(C.sub.2 H.sub.5).sub.2                                              89    2,4,6-(C.sub.2 H.sub.5).sub.3                                            90    2-n-C.sub.3 H.sub.7                                                      91    3-n-C.sub.3 H.sub.7                                                      92    4-n-C.sub.3 H.sub.7                                                      93    2-i-C.sub.3 H.sub.7                                                      94    3-i-C.sub.3 H.sub.7                                                      95    4-i-C.sub.3 H.sub.7                                                      96    2,4-(i-C.sub.3 H.sub.7).sub.2                                            97    2,6-(i-C.sub.3 H.sub.7).sub. 2                                           98    3,5-(i-C.sub.3 H.sub.7).sub.2                                            99    2,4,6-(i-C.sub.3 H.sub.7).sub.3                                          100   2-SC.sub.4 H.sub.9                                                       101   3-SC.sub.4 H.sub.9                                                       102   4-SC.sub.4 H.sub.9                                                       103   2-t-C.sub.4 H.sub.9                                                      104   3-t-C.sub.4 H.sub.9                                                      105   4-t-C.sub.4 H.sub.9                                                      106   2,3-(t-C.sub.4 H.sub.9).sub.2                                            107   2,4-(t-C.sub.4 H.sub.9).sub.2                                            108   2,5-(t-C.sub.4 H.sub.9).sub.2                                            109   2,6-(t-C.sub.4 H.sub.9).sub.2                                            110   3,4-(t-C.sub.4 H.sub.9).sub.2                                            111   2,4,6-(t-C.sub.4 H.sub.9).sub.3                                          112   4-n-C.sub.9 H.sub.19                                                     113   4-n-C.sub.12 H.sub.25                                                    114   3-n-C.sub.15 H.sub.31                                                    115   4-(1,1,3,3-tetramethylbutyl)                                             116   4-(2,4,4-trimethylpropyl                                                 117   2-t-C.sub.4 H.sub.9, 4-CH.sub.3                                          118   2-t-C.sub.4 H.sub.9, 5-CH.sub.3                                          119   2,6-(t-C.sub.4 H.sub.9), 4-CH.sub.3                                      120   2-CH.sub.3, 4-t-C.sub.4 H.sub.9                                          121   2-CH.sub.3, 6-t-C.sub.4 H.sub.9                                          122   2-CH.sub.3, 4-i-C.sub.3 H.sub.7                                          123   2-CH.sub.3, 5-i-C.sub.3 H.sub.7                                          124   3-CH.sub.3, 4-i-C.sub.3 H.sub.7                                          125   2-i-C.sub.3 H.sub.7, 5 CH.sub.3                                          126   2,4-(t-C.sub.4 H.sub.9), 6-i-C.sub.3 H.sub.7                             127   2-allyl                                                                  128   3-allyl                                                                  129   4-allyl                                                                  130   2-allyl, 6-CH.sub.3                                                      131   2-cyclo-C.sub.6 H.sub.11                                                 132   3-cyclo-C.sub.6 H.sub.11                                                 133   4-cyclo-C.sub.6 H.sub.11                                                 134   2,4-(cyclo-C.sub.6 H.sub.11).sub.2, 6-CH.sub.3                           135   2-CH.sub.3, 4-cyclo-C.sub.6 H.sub.11                                     136   2-CH.sub.2C.sub.6 H.sub.5                                                137   3-CH.sub.2C.sub.6 H.sub.5                                                138   4-CH.sub.2C.sub.6 H.sub.5                                                139   2-CH.sub.2C.sub.6 H.sub.5, 4-CH.sub.3                                    140   2-CH.sub.3, 4-CH.sub.2C.sub.6 H.sub.5                                    141   2-C.sub.6 H.sub.5                                                        142   3-C.sub.6 H.sub.5                                                        143   4-C.sub.6 H.sub.5                                                        144   4-(2-i-C.sub.3 H.sub.7C.sub.6 H.sub.4)                                   145   4-C.sub.6 H.sub.5, 2,6-(CH.sub.3).sub.2                                  146   2-Cl, 4-C.sub.6 H.sub.5                                                  147   2-Br, 4-C.sub.6 H.sub.5                                                  148   2-C.sub.6 H.sub.5, 4-Cl                                                  149   2-C.sub.6 H.sub.5, 4-Br                                                  150   2-CH.sub.2 C.sub.6 H.sub.5, 4-Cl                                         151   2-CH.sub.2 C.sub.6 H.sub.5, 4-Br                                         152   2-Cl, 4-CH.sub.2 C.sub.6 H.sub.5                                         153   2-Br, 4-CH.sub.2 C.sub.6 H.sub.5                                         154   2-cyclo-C.sub.6 H.sub.11, 4-Cl                                           155   2-cyclo-C.sub.6 H.sub.11, 4-Br                                           156   2-Cl, 4-cyclo-C.sub.6 H.sub.11                                           157   2-Br, 4-cyclo-C.sub.6 H.sub.11                                           158   2-OCH.sub.3                                                              159   3-OCH.sub.3                                                              160   4-OCH.sub.3                                                              161   2-OC.sub.2 H.sub.5                                                       162   3-OC.sub.2 H.sub.5                                                       163   4-OC.sub.2 H.sub.5                                                       164   2-O-n-C.sub.3 H.sub.7                                                    165   3-O-n-C.sub.3 H.sub.7                                                    166   4-O-n-C.sub.3 H.sub.7                                                    167   2-O-i-C.sub.3 H.sub.7                                                    168   3-O-i-C.sub.3 H.sub.7                                                    169   4-O-i-C.sub.3 H.sub.7                                                    170   2-O-n-C.sub.6 H.sub.13                                                   171   3-O-n-C.sub.6 H.sub.13                                                   172   4-O-n-C.sub.6 H.sub.13                                                   173   2-O-n-C.sub.8 H.sub.17                                                   174   3-O-n-C.sub.8 H.sub.17                                                   175   4-O-n-C.sub.8 H.sub.17                                                   176   2-OCH.sub.2 C.sub.6 H.sub.5                                              177   3-OCH.sub.2 C.sub.6 H.sub.5                                              178   4-OCH.sub.2 C.sub.6 H.sub.5                                              179   2-O(CH.sub.2).sub.3 C.sub.6 H.sub.5                                      180   3-O(CH.sub.2).sub.3 C.sub.6 H.sub.5                                      181   4-O(CH.sub.2).sub.3 C.sub.6 H.sub.5                                      182   2,4-(OCH.sub.3).sub.2                                                    183   2-CF.sub.3                                                               184   3-CF.sub.3                                                               185   4-CF.sub.3                                                               186   2-OCF.sub.3                                                              187   3-OCF.sub.3                                                              188   4-OCF.sub.3                                                              189   3-OCH.sub.2 CHF.sub.2                                                    190   2-NO.sub.2                                                               191   3-NO.sub.2                                                               192   4-NO.sub.2                                                               193   2-CN                                                                     194   3-CN                                                                     195   4-CN                                                                     196   2-CH.sub.3, 3-Cl                                                         197   2-CH.sub.3, 4-Cl                                                         198   2-CH.sub.3, 5-Cl                                                         199   2-CH.sub.3, 6-Cl                                                         200   2-CH.sub.3, 3-F                                                          201   2-CH.sub.3, 4-F                                                          202   2-CH.sub.3, 5-F                                                          203   2-CH.sub.3, 6-F                                                          204   2-CH.sub.3, 3-Br                                                         205   2-CH.sub.3, 4-Br                                                         206   2-CH.sub.3, 5-Br                                                         207   2-CH.sub.3, 6-Br                                                         208   2-Cl, 3-CH.sub.3                                                         209   2-Cl, 4-CH.sub.3                                                         210   2-Cl, 5-CH.sub.3                                                         211   2-F, 3-CH.sub.3                                                          212   2-F, 4-CH.sub.3                                                          213   2-F, 5-CH.sub.3                                                          214   2-Br, 3-CH.sub.3                                                         215   2-Br, 4-CH.sub.3                                                         216   2-Br, 5-CH.sub.3                                                         217   3-CH.sub.3, 4-Cl                                                         218   3-CH.sub.3, 5-Cl                                                         219   3-CH.sub.3, 4-F                                                          220   3-CH.sub.3, 4-Br                                                         221   3-CH.sub.3, 4-Br                                                         222   3-CH.sub.3, 5-Br                                                         223   3-F, 4-CH.sub.3                                                          224   3-Cl, 4-CH.sub.3                                                         225   3-Br, 4-CH.sub.3                                                         226   2-Cl, 4,5-(CH.sub.3).sub.2                                               227   2-Br, 4,5-(CH.sub.3).sub.2                                               228   2-Cl, 3,5-(CH.sub.3).sub.2                                               229   2-Br, 3,5-(CH.sub.3).sub.2                                               230   2,6-Cl.sub.2, 4-CH.sub.3                                                 231   2,6-F.sub.2, 4-CH.sub.3                                                  232   2,6-Br.sub.2, 4-CH.sub.3                                                 233   2,4-Cl.sub.2, 6-CH.sub.3                                                 234   2,4-F.sub.2, 6-CH.sub.3                                                  235   2,4-Br.sub.2, 6-CH.sub.3                                                 236   2,6-(CH.sub.3).sub.2, 4-F                                                237   2,6-(CH.sub.3).sub.2, 4-Cl                                               238   2,6-(CH.sub.3).sub.2, 4-Br                                               239   3,5-(CH.sub.3).sub.2, 4-F                                                240   3,5-(CH.sub.3).sub.2, 4-Cl                                               241   3,5-(CH.sub.3).sub.2, 4-Br                                               242   2,3,6-(CH.sub.3).sub.3, 4-F                                              243   2,3,6-(CH.sub.3).sub.3, 4-Cl                                             244   2,3,6-(CH.sub.3).sub.3, 4-Br                                             245   2,4-(CH.sub.3).sub.2, 6-F                                                246   2,4-(CH.sub.3).sub.2, 6-Cl                                               247   2,4-(CH.sub.3).sub.62, 6-Br                                              248   2-i-C.sub.3 H.sub.7, 4-Cl, 5-CH.sub.3                                    249   2-Cl, 4-NO.sub.2                                                         250   2-NO.sub.2, 4-Cl                                                         251   2-OCH.sub.3, 5-NO.sub.2                                                  252   2,4-Cl.sub.2, 5-NO.sub.2                                                 253   2,4-Cl.sub.2, 6-NO.sub.2                                                 254   2,6-Cl.sub.2, 4-NO.sub.2                                                 255   2,6-Br.sub.2, 4-NO.sub.2                                                 256   2,6-I.sub.2, 4-NO.sub.2                                                  257   2-CH.sub.3, 5-i-C.sub.3 H.sub.7, 4-Cl                                    258   2-C.sub.6 H.sub.5 O                                                      259   3-C.sub.6 H.sub.5 O                                                      260   4-C.sub.6 H.sub.5 O                                                      261   2-CHNOCH.sub.3                                                           262   3-CHNOCH.sub.3                                                           263   4-CHNOCH.sub.3                                                           264   2-CHNOC.sub.2 H.sub.5                                                    265   3-CHNOC.sub.2 H.sub.5                                                    266   4-CHNOC.sub.2 H.sub.5                                                    267   2-CHNO(n-C.sub.3 H.sub.7)                                                268   3-CHNO(n-C.sub.3 H.sub.7)                                                269   4-CHNO(n-C.sub.3 H.sub.7)                                                270   2-CHNO(i-C.sub.3 H.sub.7)                                                271   3-CHNO(i-C.sub.3 H.sub.7)                                                272   4-CHNO(i-C.sub. 3 H.sub.7)                                               273   2-CHNO(i-C.sub.6 H.sub.13)                                               274   3-CHNO(i-C.sub.6 H.sub.13)                                               275   4-CHNO(i-C.sub.6 H.sub.13)                                               276   2-CHNO(n-C.sub.8 H.sub.17)                                               277   3-CHNO(n-C.sub.8 H.sub.17)                                               278   4-CHNO(n-C.sub.8 H.sub.17)                                               279   2-CHNOCH.sub.2 (C.sub.6 H.sub.5)                                         280   3-CHNOCH.sub.2 (C.sub.6 H.sub.5)                                         281   4-CHNOCH.sub.2 (C.sub.6 H.sub.5)                                         282   2-CO.sub.2 CH.sub.3                                                      283   3-CO.sub.2 CH.sub.3                                                      284   4-CO.sub.2 CH.sub.3                                                      285   2-CO.sub.2 (C.sub.2 H.sub.5)                                             286   3-CO.sub.2 (C.sub.2 H.sub.5)                                             287   4-CO.sub.2 (C.sub.2 H.sub.5)                                             288   2-CO.sub.2 (n-C.sub.3 H.sub.7)                                           289   3-CO.sub.2 (n-C.sub.3 H.sub.7)                                           290   4-CO.sub.2 (n-C.sub.3 H.sub.7)                                           291   2-CO.sub.2 (i-C.sub.3 H.sub.7)                                           292   3-CO.sub.2 (i-C.sub.3 H.sub.7)                                           293   4-CO.sub.2 (i-C.sub.3 H.sub.7)                                           294   2-CO.sub.2 (i-C.sub.6 H.sub.13)                                          295   3-CO.sub.2 (i-C.sub.6 H.sub.13)                                          296   4-CO.sub.2 (i-C.sub.6 H.sub.13)                                          297   2-CO.sub.2 (n-C.sub.8 H.sub.17)                                          298   3-CO.sub.2 (n-C.sub.8 H.sub.17)                                          299   4-CO.sub.2 (n-C.sub.8 H.sub.17)                                          300   2-CHNOCH.sub.2CHCH.sub.2                                                 301   3-CHNOCH.sub.2CHCH.sub.2                                                 302   4-CHNOCH.sub.2CHCH.sub.2                                                 303   2-CHNO(CH.sub.2).sub.3 (C.sub.6 H.sub.5)                                 304   3-CHNO(CH.sub.2).sub.3 (C.sub.6 H.sub.5)                                 305   4-CHNO(CH.sub.2).sub.3 (C.sub.6 H.sub.5)                                 306   2-CH.sub.2 OCH.sub.3                                                     307   3-CH.sub.2 OCH.sub.3                                                     308   4-CH.sub.2 OCH.sub.3                                                     309   2-CH.sub.2 O(C.sub.2 H.sub.5)                                            310   3-CH.sub.2 O(C.sub.2 H.sub.5)                                            311   4-CH.sub.2 O(C.sub.2 H.sub.5)                                            312   2-CH.sub.2 O(n-C.sub.3 H.sub.7)                                          313   3-CH.sub.2 O(n-C.sub.3 H.sub.7)                                          314   4-CH.sub.2 O(n-C.sub.3 H.sub.7)                                          315   2-CH.sub.2 O(i-C.sub.3 H.sub.7)                                          316   3-CH.sub.2 O(i-C.sub.3 H.sub.7)                                          317   4-(CH.sub.2 O(i-C.sub.3 H.sub.7)                                         318   2-CH.sub.2 O(n-C.sub.6 H.sub.13)                                         319   3-CH.sub.2 O(n-C.sub.6 H.sub.13)                                         320   4-CH.sub.2 O(n-C.sub.6 H.sub.13)                                         321   2-CH.sub.2 O(n-C.sub.8 H.sub.17)                                         322   3-CH.sub.2 O(n-C.sub.8 H.sub.17)                                         323   4-CH.sub.2 O(n-C.sub.8 H.sub.7)                                          324   2-CH.sub.2 OCH.sub.2 (C.sub.6 H.sub.5)                                   325   3-CH.sub.2 OCH.sub.2 (C.sub.6 H.sub.5)                                   326   4-CH.sub.2 OCH.sub.2 (C.sub.6 H.sub.5)                                   327   2-CH.sub.2 O(CH.sub.2).sub.3                                             328   3-CH.sub.2 O(CH.sub.2).sub.3 (C.sub.6 H.sub.5)                           329   4-CH.sub.2 O(CH.sub.2).sub.3 (C.sub.6 H.sub.5)                           330   2-CHO                                                                    331   3-CHO                                                                    332   4-CHO                                                                    ______________________________________                                    

                  TABLE 11                                                         ______________________________________                                          ##STR38##                                                                     No.   X.sub.m            mp     NMR: δ (ppm)                             ______________________________________                                         1     2-F                                                                      2     3-F                                                                      3     4-F                                                                      4     2,4-F.sub.2                                                              5     2,4,6-F.sub.3                                                            6     2,3,4,5,6-F.sub.5                                                        7     2,3-F.sub.2                                                              8     2-Cl                                                                     9     3-Cl                                                                     10    4-Cl                                                                     11    2,3-Cl.sub.2                                                             12    2,4-Cl.sub.2                                                             13    2,5-Cl.sub.2                                                             14    2,6-Cl.sub.2                                                             15    3,4-Cl.sub.2                                                             16    3,5-Cl.sub.2                                                             17    2,3,4-Cl.sub.3                                                           18    2,3,5-Cl.sub.3                                                           19    2,3,6-Cl.sub.3                                                           20    2,4,5-Cl.sub.3                                                           21    2,4,6-Cl.sub.3                                                           22    3,4,5-Cl.sub.3                                                           23    2,3,4,6-Cl.sub.4                                                         24    2,3,5,6-Cl.sub.4                                                         25    2,3,4,5,6-Cl.sub.5                                                       26    2-Br                                                                     27    3-Br                                                                     28    4-Br                                                                     29    2,4-Br.sub.2                                                             30    2,5-Br.sub.5                                                             31    2,6-Br.sub.2                                                             32    2,4,6-Br.sub.3                                                           33    2,3,4,5,6-Br.sub.5                                                       34    2-I                                                                      35    3-I                                                                      36    4-I                                                                      37    2,4-I.sub.2                                                              38    2-Cl, 3-F                                                                39    2-Cl, 4-F                                                                40    2-Cl, 5-F                                                                41    2-Cl, 6-F                                                                42    2-Cl, 3-Br                                                               43    2-Cl, 4-Br                                                               44    2-Cl, 6-Br                                                               45    2-Cl, 6-Br                                                               46    2-Br, 3-Cl                                                               47    2-Br, 4-Cl                                                               48    2-Br, 5-Cl                                                               49    2-Br, 3-F                                                                50    2-Br, 4-F                                                                51    2-Br, 5-F                                                                52    2-Br, 6-F                                                                53    2-F, 3-Cl                                                                54    2-F, 4-Cl                                                                55    2-F, 5-Cl                                                                56    3-Cl, 4-F                                                                57    3-Cl, 5-F                                                                58    3-Cl, 4-Br                                                               59    3-Cl, 5-Br                                                               60    3-F, 4-Cl                                                                61    3-F, 4-Br                                                                62    3-Br, 4-Cl                                                               63    3-Br, 4-F                                                                64    2,6-Cl.sub.2, 4-Br                                                       65    2-CH.sub.3                                                               66    3-CH.sub.3                                                               67    4-CH.sub.3                                                               68    2,3-(CH.sub.3).sub.2                                                     69    2,4-(CH.sub.3).sub.2                                                     70    2,5-(CH.sub.3).sub.2                                                     71    2,6-(CH.sub.3).sub.2                                                     72    3,4-(CH.sub.3).sub.2                                                     73    3,5-(CH.sub.3).sub.2                                                     74    3,5-(CH.sub.3).sub.2                                                     75    2,3,4-(CH.sub.3).sub.3                                                   76    2,3,6-(CH.sub.3).sub.3                                                   77    2,4,5-(CH.sub.3).sub.3                                                   78    2,4,6-(CH.sub.3).sub.3                                                   79    3,4,5-(CH.sub.3).sub.3                                                   80    2,3,4,6-(CH.sub.3).sub.4                                                 81    2,3,5,6-(CH.sub.3).sub.4                                                 82    2,3,4,5,6-(CH.sub.3).sub.5                                               83    2-C.sub.2 H.sub.5                                                        84    3-C.sub.2 H.sub.5                                                        85    4-C.sub.2 H.sub.5                                                        86    2,4-(C.sub.2 H.sub.5).sub.2                                              87    2,6-(C.sub.2 H.sub.5).sub.2                                              88    3,5-(C.sub.2 H.sub.5).sub.2                                              89    2,4,6-(C.sub.2 H.sub.5).sub.3                                            90    2-n-C.sub.3 H.sub.7                                                      91    3-n-C.sub.3 H.sub.7                                                      92    4-n-C.sub.3 H.sub.7                                                      93    2-i-C.sub.3 H.sub.7                                                      94    3-i-C.sub.3 H.sub.7                                                      95    4-i-C.sub.3 H.sub.7                                                      96    2,4-(i-C.sub.3 H.sub.7).sub.2                                            97    2,6-(i-C.sub.3 H.sub.7).sub.2                                            98    3,5-(i-C.sub.3 H.sub.7).sub.2                                            99    2,4,6-(i-C.sub.3 H.sub.7).sub.3                                          100   2-SC.sub.4 H.sub.9                                                       101   3-SC.sub.4 H.sub.9                                                       102   4-SC.sub.4 H.sub.9                                                       103   2-t-C.sub.4 H.sub.9                                                      104   3-t-C.sub.4 H.sub.9                                                      105   4-t-C.sub.4 H.sub.9                                                      106   2,3-(t-C.sub.4 H.sub.9).sub.2                                            107   2,4-(t-C.sub.4 H.sub.9).sub.2                                            108   2,5-(t-C.sub.4 H.sub.9).sub.2                                            109   2,6-(t-C.sub.4 H.sub.9).sub.2                                            110   3,4-(t-C.sub.4 H.sub.9).sub.2                                            111   2,4,6-(t-C.sub.4 H.sub.9).sub.3                                          112   4-n-C.sub.9 H.sub.19                                                     113   4-n-C.sub.12 H.sub.25                                                    114   3-n-C.sub.15 H.sub.31                                                    115   4-(1,1,3,3-tetramethylbutyl)                                             116   4-(2,4,4-trimethylpropyl                                                 117   2-t-C.sub.4 H.sub.9, 4-CH.sub.3                                          118   2-t-C.sub.4 H.sub.9, 5-CH.sub.3                                          119   2,6-(t-C.sub.4 H.sub.9), 4-CH.sub.3                                      120   2-CH.sub.3, 4-t-C.sub.4 H.sub.9                                          121   2-CH.sub.3, 6-t-C.sub.4 H.sub.9                                          122   2-CH.sub.3, 4-i-C.sub.3 H.sub.7                                          123   2-CH.sub.3, 5-i-C.sub.3 H.sub.7                                          124   3-CH.sub.3, 4-i-C.sub.3 H.sub.7                                          125   2-i-C.sub.3 H.sub.7, 5 CH.sub.3                                          126   2,4-(t-C.sub.4 H.sub.9), 6-i-C.sub.3 H.sub.7                             127   2-allyl                                                                  128   3-allyl                                                                  129   4-allyl                                                                  130   2-allyl, 6-CH.sub. 3                                                     131   2-cyclo-C.sub.6 H.sub.11                                                 132   3-cyclo-C.sub.6 H.sub.11                                                 133   4-cyclo-C.sub.6 H.sub.11                                                 134   2,4-(cyclo-C.sub.6 H.sub.11).sub.2, 6-CH.sub.3                           135   2-CH.sub.3, 4-cyclo-C.sub.6 H.sub.11                                     136   2-CH.sub.2C.sub.6 H.sub.5                                                137   3-CH.sub.2C.sub.6 H.sub.5                                                138   4-CH.sub.2C.sub.6 H.sub.5                                                139   2-CH.sub.2C.sub.6 H.sub.5, 4-CH.sub.3                                    140   2-CH.sub.3, 4-CH.sub.2C.sub.6 H.sub.5                                    141   2-C.sub.6 H.sub.5                                                        142   3-C.sub.6 H.sub.5                                                        143   4-C.sub.6 H.sub.5                                                        144   4-(2-i-C.sub.3 H.sub.7C.sub.6 H.sub.4)                                   145   4-C.sub.6 H.sub.5, 2,6-(CH.sub.3).sub.2                                  146   2-Cl, 4-C.sub.6 H.sub.5                                                  147   2-Br, 4-C.sub.6 H.sub.5                                                  148   2-C.sub.6 H.sub.5, 4-Cl                                                  149   2-C.sub.6 H.sub.5, 4-Br                                                  150   2-CH.sub.2 C.sub.6 H.sub.5, 4-Cl                                         151   2-CH.sub.2 C.sub.6 H.sub.5, 4-Br                                         152   2-Cl, 4-CH.sub.2 C.sub.6 H.sub.5                                         153   2-Br, 4-CH.sub.2 C.sub.6 H.sub.5                                         154   2-cyclo-C.sub.6 H.sub.11, 4-Cl                                           155   2-cyclo-C.sub.6 H.sub.11, 4-Br                                           156   2-Cl, 4-cyclo-C.sub.6 H.sub.11                                           157   2-Br, 4-cyclo-C.sub.6 H.sub.11                                           158   2-OCH.sub.3                                                              159   3-OCH.sub.3                                                              160   4-OCH.sub.3                                                              161   2-OC.sub.2 H.sub.5                                                       162   3-OC.sub.2 H.sub.5                                                       163   4-OC.sub.2 H.sub.5                                                       164   2-O-n-C.sub.3 H.sub.7                                                    165   3-O-n-C.sub.3 H.sub.7                                                    166   4-O-n-C.sub.3 H.sub.7                                                    167   2-O-i-C.sub.3 H.sub.7                                                    168   3-O-i-C.sub.3 H.sub.7                                                    169   4-O-i-C.sub.3 H.sub.7                                                    170   2-O-n-C.sub.6 H.sub.13                                                   171   3-O-n-C.sub.6 H.sub.13                                                   172   4-O-n-C.sub.6 H.sub.13                                                   173   2-O-n-C.sub.8 H.sub.17                                                   174   3-O-n-C.sub.8 H.sub.17                                                   175   4-O-n-C.sub.8 H.sub.17                                                   176   2-OCH.sub.2 C.sub.6 H.sub.5                                              177   3-OCH.sub.2 C.sub.6 H.sub.5                                              178   4-OCH.sub.2 C.sub.6 H.sub.5                                              179   2-O(CH.sub.2).sub.3 C.sub.6 H.sub.5                                      180   3-O(CH.sub.2).sub.3 C.sub.6 H.sub.5                                      181   4-O(CH.sub.2).sub.3 C.sub.6 H.sub.5                                      182   2,4-(OCH.sub.3).sub.2                                                    183   2-CF.sub.3                                                               184   3-CF.sub.3                                                               185   4-CF.sub.3                                                               186   2-OCF.sub.3                                                              187   3-OCF.sub.3                                                              188   4-OCF.sub.3                                                              189   3-OCH.sub.2 CHF.sub.2                                                    190   2-NO.sub.2                                                               191   3-NO.sub.2                                                               192   4-NO.sub.2                                                               193   2-CN                                                                     194   3-CN                                                                     195   4-CN                                                                     196   2-CH.sub.3, 3-Cl                                                         197   2-CH.sub.3, 4-Cl                                                         198   2-CH.sub.3, 5-Cl                                                         199   2-CH.sub.3, 6-Cl                                                         200   2-CH.sub.3, 3-F                                                          201   2-CH.sub.3, 4-F                                                          202   2-CH.sub.3, 5-F                                                          203   2-CH.sub.3, 6-F                                                          204   2-CH.sub.3, 3-Br                                                         205   2-CH.sub.3, 4-Br                                                         206   2-CH.sub.3, 5-Br                                                         207   2-CH.sub.3, 6-Br                                                         208   2-Cl, 3-CH.sub.3                                                         209   2-Cl, 4-CH.sub.3                                                         210   2-Cl, 5-CH.sub.3                                                         211   2-F, 3-CH.sub.3                                                          212   2-F, 4-CH.sub.3                                                          213   2-F, 5-CH.sub.3                                                          214   2-Br, 3-CH.sub.3                                                         215   2-Br, 4-CH.sub.3                                                         216   2-Br, 5-CH.sub.3                                                         217   3-CH.sub.3, 4-Cl                                                         218   3-CH.sub.3, 5-Cl                                                         219   3-CH.sub.3, 4-F                                                          220   3-CH.sub.3, 4-Br                                                         221   3-CH.sub.3, 4-Br                                                         222   3-CH.sub.3, 5-Br                                                         223   3-F, 4-CH.sub.3                                                          224   3-Cl, 4-CH.sub.3                                                         225   3-Br, 4-CH.sub.3                                                         226   2-Cl, 4,5-(CH.sub.3).sub.2                                               227   2-Br, 4,5-(CH.sub.3).sub.2                                               228   2-Cl, 3,5-(CH.sub.3).sub.2                                               229   2-Br, 3,5-(CH.sub.3).sub.2                                               230   2,6-Cl.sub.2, 4-CH.sub.3                                                 231   2,6-F.sub.2, 4-CH.sub.3                                                  232   2,6-Br.sub.2, 4-CH.sub.3                                                 233   2,4-Cl.sub.2, 6-CH.sub.3                                                 234   2,4-F.sub.2, 6-CH.sub.3                                                  235   2,4-Br.sub.2, 6-CH.sub.3                                                 236   2,6-(CH.sub.3).sub.2, 4-F                                                237   2,6-(CH.sub.3).sub.2, 4-Cl                                               238   2,6-(CH.sub.3).sub.2, 4-Br                                               239   3,5-(CH.sub. 3).sub.2, 4-F                                               240   3,5-(CH.sub.3).sub.2, 4-Cl                                               241   3,5-(CH.sub.3).sub.2, 4-Br                                               242   2,3,6-(CH.sub.3).sub.3, 4-F                                              243   2,3,6-(CH.sub.3).sub.3, 4-Cl                                             244   2,3,6-(CH.sub.3).sub.3, 4-Br                                             245   2,4-(CH.sub.3).sub.2, 6-F                                                246   2,4-(CH.sub.3).sub.2, 6-Cl                                               247   2,4-(CH.sub.3).sub.62, 6-Br                                              248   2-i-C.sub.3 H.sub.7, 4-Cl, 5-CH.sub.3                                    249   2-Cl, 4-NO.sub.2                                                         250   2-NO.sub.2, 4-Cl                                                         251   2-OCH.sub.3, 5-NO.sub.2                                                  252   2,4-Cl.sub.2, 5-NO.sub.2                                                 253   2,4-Cl.sub.2, 6-NO.sub.2                                                 254   2,6-Cl.sub.2, 4-NO.sub.2                                                 255   2,6-Br.sub.2, 4-NO.sub.2                                                 256   2,6-I.sub.2, 4-NO.sub.2                                                  257   2-CH.sub.3, 5-i-C.sub.3 H.sub.7, 4-Cl                                    258   2-C.sub.6 H.sub.5 O                                                      259   3-C.sub.6 H.sub.5 O                                                      260   4-C.sub.6 H.sub.5 O                                                      261   2-CHNOCH.sub.3                                                           262   3-CHNOCH.sub.3                                                           263   4-CHNOCH.sub.3                                                           264   2-CHNOC.sub.2 H.sub.5                                                    265   3-CHNOC.sub.2 H.sub.5                                                    266   4-CHNOC.sub.2 H.sub.5                                                    267   2-CHNO(n-C.sub.3 H.sub.7)                                                268   3-CHNO(n-C.sub.3 H.sub.7)                                                269   4-CHNO(n-C.sub.3 H.sub.7)                                                270   2-CHNO(i-C.sub.3 H.sub.7)                                                271   3-CHNO(i-C.sub.3 H.sub.7)                                                272   4-CHNO(i-C.sub.3 H.sub.7)                                                273   2-CHNO(i-C.sub.6 H.sub.13)                                               274   3-CHNO(i-C.sub.6 H.sub.13)                                               275   4-CHNO(i-C.sub.6 H.sub.13)                                               276   2-CHNO(n-C.sub.8 H.sub.17)                                               277   3-CHNO(n-C.sub.8 H.sub.17)                                               278   4-CHNO(n-C.sub.8 H.sub.17)                                               279   2-CHNOCH.sub.2 (C.sub.6 H.sub.5)                                         280   3-CHNOCH.sub.2 (C.sub.6 H.sub.5)                                         281   4-CHNOCH.sub.2 (C.sub.6 H.sub.5)                                         282   2-CO.sub.2 CH.sub.3                                                      283   3-CO.sub.2 CH.sub.3                                                      284   4-CO.sub.2 CH.sub.3                                                      285   2-CO.sub.2 (C.sub.2 H.sub.5)                                             286   3-CO.sub.2 (C.sub.2 H.sub.5)                                             287   4-CO.sub.2 (C.sub.2 H.sub.5)                                             288   2-CO.sub.2 (n-C.sub.3 H.sub.7)                                           289   3-CO.sub.2 (n-C.sub.3 H.sub.7)                                           290   4-CO.sub.2 (n-C.sub.3 H.sub.7)                                           291   2-CO.sub.2 (i-C.sub.3 H.sub.7)                                           292   3-CO.sub.2 (i-C.sub.3 H.sub.7)                                           293   4-CO.sub.2 (i-C.sub.3 H.sub.7)                                           294   2-CO.sub.2 (i-C.sub.6 H.sub.13)                                          295   3-CO.sub.2 (i-C.sub.6 H.sub.13)                                          296   4-CO.sub.2 (i-C.sub.6 H.sub.13)                                          297   2-CO.sub.2 (n-C.sub.8 H.sub.17)                                          298   3-CO.sub.2 (n-C.sub.8 H.sub.17)                                          299   4-CO.sub.2 (n-C.sub.8 H.sub.17)                                          300   2-CHNO CH.sub.2CHCH.sub.2                                                301   3-CHNOCH.sub.2CHCH.sub.2                                                 302   4-CHNOCH.sub.2CHCH.sub.2                                                 303   2-CHNO(CH.sub.2).sub.3 (C.sub.6 H.sub.5)                                 304   3-CHNO(CH.sub.2).sub.3 (C.sub.6 H.sub.5)                                 305   4-CHNO(CH.sub.2).sub.3 (C.sub.6 H.sub.5)                                 306   2-CH.sub.2 OCH.sub.3                                                     307   3-CH.sub.2 OCH.sub.3                                                     308   4-CH.sub.2 OCH.sub.3                                                     309   2-CH.sub.2 O(C.sub.2 H.sub.5)                                            310   3-CH.sub.2 O(C.sub.2 H.sub.5)                                            311   4-CH.sub.2 O(C.sub.2 H.sub.5)                                            312   2-CH.sub.2 O(n-C.sub.3 H.sub.7)                                          313   3-CH.sub.2 O(n-C.sub.3 H.sub.7)                                          314   4-CH.sub.2 O(n-C.sub.3 H.sub.7)                                          315   2-CH.sub.2 O(i-C.sub.3 H.sub.7)                                          316   3-CH.sub.2 O(i-C.sub.3 H.sub.7)                                          317   4-(CH.sub.2 O(i-C.sub.3 H.sub.7)                                         318   2-CH.sub.2 O(n-C.sub.6 H.sub.13)                                         319   3-CH.sub.2 O(n-C.sub.6 H.sub.13)                                         320   4-CH.sub.2 O(n-C.sub.6 H.sub.13)                                         321   2-CH.sub.2 O(n-C.sub.8 H.sub.17)                                         322   3-CH.sub.2 O(n-C.sub.8 H.sub.17)                                         323   4-CH.sub.2 O(n-C.sub.8 H.sub.7)                                          324   2-CH.sub.2 OCH.sub.2 (C.sub.6 H.sub.5)                                   325   3-CH.sub.2 OCH.sub.2 (C.sub. 6 H.sub.5)                                  326   4-CH.sub.2 OCH.sub.2 (C.sub.6 H.sub.5)                                   327   2-CH.sub.2 O(CH.sub.2).sub.3                                             328   3-CH.sub.2 O(CH.sub.2).sub.3 (C.sub.6 H.sub.5)                           329   4-CH.sub.2 O(CH.sub.2).sub.3 (C.sub.6 H.sub.5)                           330   2-CHO                                                                    331   3-CHO                                                                    332   4-CHO                                                                    ______________________________________                                    

                  TABLE 12                                                         ______________________________________                                          ##STR39##                                                                     No.   X.sub.m            mp     NMR: δ (ppm)                             ______________________________________                                         1     2-F                                                                      2     3-F                                                                      3     4-F                                                                      4     2,4-F.sub.2                                                              5     2,4,6-F.sub.3                                                            6     2,3,4,5,6-F.sub.5                                                        7     2,3-F.sub.2                                                              8     2-Cl                                                                     9     3-Cl                                                                     10    4-Cl                                                                     11    2,3-Cl.sub.2                                                             12    2,4-Cl.sub.2                                                             13    2,5-Cl.sub.2                                                             14    2,6-Cl.sub.2                                                             15    3,4-Cl.sub.2                                                             16    3,5-Cl.sub.2                                                             17    2,3,4-Cl.sub.3                                                           18    2,3,5-Cl.sub.3                                                           19    2,3,6-Cl.sub.3                                                           20    2,4,5-Cl.sub.3                                                           21    2,4,6-Cl.sub.3                                                           22    3,4,5-Cl.sub.3                                                           23    2,3,4,6-Cl.sub.4                                                         24    2,3,5,6-Cl.sub.4                                                         25    2,3,4,5,6-Cl.sub.5                                                       26    2-Br                                                                     27    3-Br                                                                     28    4-Br                                                                     29    2,4-Br.sub.2                                                             30    2,5-Br.sub.5                                                             31    2,6-Br.sub.2                                                             32    2,4,6-Br.sub.3                                                           33    2,3,4,5,6-Br.sub.5                                                       34    2-I                                                                      35    3-I                                                                      36    4-I                                                                      37    2,4-I.sub.2                                                              38    2-Cl, 3-F                                                                39    2-Cl, 4-F                                                                40    2-Cl, 5-F                                                                41    2-Cl, 6-F                                                                42    2-Cl, 3-Br                                                               43    2-Cl, 4-Br                                                               44    2-Cl, 6-Br                                                               45    2-Cl, 6-Br                                                               46    2-Br, 3-Cl                                                               47    2-Br, 4-Cl                                                               48    2-Br, 5-Cl                                                               49    2-Br, 3-F                                                                50    2-Br, 4-F                                                                51    2-Br, 5-F                                                                52    2-Br, 6-F                                                                53    2-F, 3-Cl                                                                54    2-F, 4-Cl                                                                55    2-F, 5-Cl                                                                56    3-Cl, 4-F                                                                57    3-Cl, 5-F                                                                58    3-Cl, 4-Br                                                               59    3-Cl, 5-Br                                                               60    3-F, 4-Cl                                                                61    3-F, 4-Br                                                                62    3-Br, 4-Cl                                                               63    3-Br, 4-F                                                                64    2,6-Cl.sub.2, 4-Br                                                       65    2-CH.sub.3                                                               66    3-CH.sub.3                                                               67    4-CH.sub.3                                                               68    2,3-(CH.sub.3).sub.2                                                     69    2,4-(CH.sub.3).sub.2                                                     70    2,5-(CH.sub.3).sub.2                                                     71    2,6-(CH.sub.3).sub.2                                                     72    3,4-(CH.sub.3).sub.2                                                     73    3,5-(CH.sub.3).sub.2                                                     74    3,5-(CH.sub.3).sub.2                                                     75    2,3,4-(CH.sub.3).sub.3                                                   76    2,3,6-(CH.sub.3).sub.3                                                   77    2,4,5-(CH.sub.3).sub.3                                                   78    2,4,6-(CH.sub.3).sub.3                                                   79    3,4,5-(CH.sub.3).sub.3                                                   80    2,3,4,6-(CH.sub.3).sub.4                                                 81    2,3,5,6-(CH.sub.3).sub.4                                                 82    2,3,4,5,6-(CH.sub.3).sub.5                                               83    2-C.sub.2 H.sub.5                                                        84    3-C.sub.2 H.sub.5                                                        85    4-C.sub.2 H.sub.5                                                        86    2,4-(C.sub.2 H.sub.5).sub.2                                              87    2,6-(C.sub.2 H.sub.5).sub.2                                              88    3,5-(C.sub.2 H.sub.5).sub.2                                              89    2,4,6-(C.sub.2 H.sub.5).sub.3                                            90    2-n-C.sub.3 H.sub.7                                                      91    3-n-C.sub.3 H.sub.7                                                      92    4-n-C.sub.3 H.sub.7                                                      93    2-i-C.sub.3 H.sub.7                                                      94    3-i-C.sub.3 H.sub.7                                                      95    4-i-C.sub.3 H.sub.7                                                      96    2,4-(i-C.sub.3 H.sub.7).sub.2                                            97    2,6-(i-C.sub.3 H.sub.7).sub.2                                            98    3,5-(i-C.sub.3 H.sub.7).sub.2                                            99    2,4,6-(i-C.sub.3 H.sub.7).sub.3                                          100   2-SC.sub.4 H.sub.9                                                       101   3-SC.sub.4 H.sub.9                                                       102   4-SC.sub.4 H.sub.9                                                       103   2-t-C.sub.4 H.sub.9                                                      104   3-t-C.sub.4 H.sub.9                                                      105   4-t-C.sub.4 H.sub.9                                                      106   2,3-(t-C.sub.4 H.sub.9).sub.2                                            107   2,4-(t-C.sub.4 H.sub.9).sub.2                                            108   2,5-(t-C.sub.4 H.sub.9).sub.2                                            109   2,6-(t-C.sub.4 H.sub.9).sub.2                                            110   3,4-(t-C.sub.4 H.sub.9).sub.2                                            111   2,4,6-(t-C.sub.4 H.sub.9).sub.3                                          112   4-n-C.sub.9 H.sub.19                                                     113   4-n-C.sub.12 H.sub.25                                                    114   3-n-C.sub.15 H.sub.31                                                    115   4-(1,1,3,3-tetramethylbutyl)                                             116   4-(2,4,4-trimethylpropyl                                                 117   2-t-C.sub.4 H.sub.9, 4-CH.sub.3                                          118   2-t-C.sub.4 H.sub.9, 5-CH.sub.3                                          119   2,6-(t-C.sub.4 H.sub.9), 4-CH.sub.3                                      120   2-CH.sub.3, 4-t-C.sub.4 H.sub.9                                          121   2-CH.sub.3, 6-t-C.sub.4 H.sub.9                                          122   2-CH.sub.3, 4-i-C.sub.3 H.sub.7                                          123   2-CH.sub.3, 5-i-C.sub.3 H.sub.7                                          124   3-CH.sub.3, 4-i-C.sub.3 H.sub.7                                          125   2-i-C.sub.3 H.sub.7, 5 CH.sub.3                                          126   2,4-(t-C.sub.4 H.sub.9), 6-i-C.sub.3 H.sub.7                             127   2-allyl                                                                  128   3-allyl                                                                  129   4-allyl                                                                  130   2-allyl, 6-CH.sub. 3                                                     131   2-cyclo-C.sub.6 H.sub.11                                                 132   3-cyclo-C.sub.6 H.sub.11                                                 133   4-cyclo-C.sub.6 H.sub.11                                                 134   2,4-(cyclo-C.sub.6 H.sub.11).sub.2, 6-CH.sub.3                           135   2-CH.sub.3, 4-cyclo-C.sub.6 H.sub.11                                     136   2-CH.sub.2C.sub.6 H.sub.5                                                137   3-CH.sub.2C.sub.6 H.sub.5                                                138   4-CH.sub.2C.sub.6 H.sub.5                                                139   2-CH.sub.2C.sub.6 H.sub.5, 4-CH.sub.3                                    140   2-CH.sub.3, 4-CH.sub.2C.sub.6 H.sub.5                                    141   2-C.sub.6 H.sub.5                                                        142   3-C.sub.6 H.sub.5                                                        143   4-C.sub.6 H.sub.5                                                        144   4-(2-i-C.sub.3 H.sub.7C.sub.6 H.sub.4)                                   145   4-C.sub.6 H.sub.5, 2,6-(CH.sub.3).sub.2                                  146   2-Cl, 4-C.sub.6 H.sub.5                                                  147   2-Br, 4-C.sub.6 H.sub.5                                                  148   2-C.sub.6 H.sub.5, 4-Cl                                                  149   2-C.sub.6 H.sub.5, 4-Br                                                  150   2-CH.sub.2 C.sub.6 H.sub.5, 4-Cl                                         151   2-CH.sub.2 C.sub.6 H.sub.5, 4-Br                                         152   2-Cl, 4-CH.sub.2 C.sub.6 H.sub.5                                         153   2-Br, 4-CH.sub.2 C.sub.6 H.sub.5                                         154   2-cyclo-C.sub.6 H.sub.11, 4-Cl                                           155   2-cyclo-C.sub.6 H.sub.11, 4-Br                                           156   2-Cl, 4-cyclo-C.sub.6 H.sub.11                                           157   2-Br, 4-cyclo-C.sub.6 H.sub.11                                           158   2-OCH.sub.3                                                              159   3-OCH.sub.3                                                              160   4-OCH.sub.3                                                              161   2-OC.sub.2 H.sub.5                                                       162   3-OC.sub.2 H.sub.5                                                       163   4-OC.sub.2 H.sub.5                                                       164   2-O-n-C.sub.3 H.sub.7                                                    165   3-O-n-C.sub.3 H.sub.7                                                    166   4-O-n-C.sub.3 H.sub.7                                                    167   2-O-i-C.sub.3 H.sub.7                                                    168   3-O-i-C.sub.3 H.sub.7                                                    169   4-O-i-C.sub.3 H.sub.7                                                    170   2-O-n-C.sub.6 H.sub.13                                                   171   3-O-n-C.sub.6 H.sub.13                                                   172   4-O-n-C.sub.6 H.sub.13                                                   173   2-O-n-C.sub.8 H.sub.17                                                   174   3-O-n-C.sub.8 H.sub.17                                                   175   4-O-n-C.sub.8 H.sub.17                                                   176   2-OCH.sub.2 C.sub.6 H.sub.5                                              177   3-OCH.sub.2 C.sub.6 H.sub.5                                              178   4-OCH.sub.2 C.sub.6 H.sub.5                                              179   2-O(CH.sub.2).sub.3 C.sub.6 H.sub.5                                      180   3-O(CH.sub.2).sub.3 C.sub.6 H.sub.5                                      181   4-O(CH.sub.2).sub.3 C.sub.6 H.sub.5                                      182   2,4-(OCH.sub.3).sub.2                                                    183   2-CF.sub.3                                                               184   3-CF.sub.3                                                               185   4-CF.sub.3                                                               186   2-OCF.sub.3                                                              187   3-OCF.sub.3                                                              188   4-OCF.sub.3                                                              189   3-OCH.sub.2 CHF.sub.2                                                    190   2-NO.sub.2                                                               191   3-NO.sub.2                                                               192   4-NO.sub.2                                                               193   2-CN                                                                     194   3-CN                                                                     195   4-CN                                                                     196   2-CH.sub.3, 3-Cl                                                         197   2-CH.sub.3, 4-Cl                                                         198   2-CH.sub.3, 5-Cl                                                         199   2-CH.sub.3, 6-Cl                                                         200   2-CH.sub.3, 3-F                                                          201   2-CH.sub.3, 4-F                                                          202   2-CH.sub.3, 5-F                                                          203   2-CH.sub.3, 6-F                                                          204   2-CH.sub.3, 3-Br                                                         205   2-CH.sub.3, 4-Br                                                         206   2-CH.sub.3, 5-Br                                                         207   2-CH.sub.3, 6-Br                                                         208   2-Cl, 3-CH.sub.3                                                         209   2-Cl, 4-CH.sub.3                                                         210   2-Cl, 5-CH.sub.3                                                         211   2-F, 3-CH.sub.3                                                          212   2-F, 4-CH.sub.3                                                          213   2-F, 5-CH.sub.3                                                          214   2-Br, 3-CH.sub.3                                                         215   2-Br, 4-CH.sub.3                                                         216   2-Br, 5-CH.sub.3                                                         217   3-CH.sub.3, 4-Cl                                                         218   3-CH.sub.3, 5-Cl                                                         219   3-CH.sub.3, 4-F                                                          220   3-CH.sub.3, 4-Br                                                         221   3-CH.sub.3, 4-Br                                                         222   3-CH.sub.3, 5-Br                                                         223   3-F, 4-CH.sub.3                                                          224   3-Cl, 4-CH.sub.3                                                         225   3-Br, 4-CH.sub.3                                                         226   2-Cl, 4,5-(CH.sub.3).sub.2                                               227   2-Br, 4,5-(CH.sub.3).sub.2                                               228   2-Cl, 3,5-(CH.sub.3).sub.2                                               229   2-Br, 3,5-(CH.sub.3).sub.2                                               230   2,6-Cl.sub.2, 4-CH.sub.3                                                 231   2,6-F.sub.2, 4-CH.sub.3                                                  232   2,6-Br.sub.2, 4-CH.sub.3                                                 233   2,4-Cl.sub.2, 6-CH.sub.3                                                 234   2,4-F.sub.2, 6-CH.sub.3                                                  235   2,4-Br.sub.2, 6-CH.sub.3                                                 236   2,6-(CH.sub.3).sub.2, 4-F                                                237   2,6-(CH.sub.3).sub.2, 4-Cl                                               238   2,6-(CH.sub.3).sub.2, 4-Br                                               239   3,5-(CH.sub. 3).sub.2, 4-F                                               240   3,5-(CH.sub.3).sub.2, 4-Cl                                               241   3,5-(CH.sub.3).sub.2, 4-Br                                               242   2,3,6-(CH.sub.3).sub.3, 4-F                                              243   2,3,6-(CH.sub.3).sub.3, 4-Cl                                             244   2,3,6-(CH.sub.3).sub.3, 4-Br                                             245   2,4-(CH.sub.3).sub.2, 6-F                                                246   2,4-(CH.sub.3).sub.2, 6-Cl                                               247   2,4-(CH.sub.3).sub.62, 6-Br                                              248   2-i-C.sub.3 H.sub.7, 4-Cl, 5-CH.sub.3                                    249   2-Cl, 4-NO.sub.2                                                         250   2-NO.sub.2, 4-Cl                                                         251   2-OCH.sub.3, 5-NO.sub.2                                                  252   2,4-Cl.sub.2, 5-NO.sub.2                                                 253   2,4-Cl.sub.2, 6-NO.sub.2                                                 254   2,6-Cl.sub.2, 4-NO.sub.2                                                 255   2,6-Br.sub.2, 4-NO.sub.2                                                 256   2,6-I.sub.2, 4-NO.sub.2                                                  257   2-CH.sub.3, 5-i-C.sub.3 H.sub.7, 4-Cl                                    258   2-C.sub.6 H.sub.5 O                                                      259   3-C.sub.6 H.sub.5 O                                                      260   4-C.sub.6 H.sub.5 O                                                      261   2-CHNOCH.sub.3                                                           262   3-CHNOCH.sub.3                                                           263   4-CHNOCH.sub.3                                                           264   2-CHNOC.sub.2 H.sub.5                                                    265   3-CHNOC.sub.2 H.sub.5                                                    266   4-CHNOC.sub.2 H.sub.5                                                    267   2-CHNO(n-C.sub.3 H.sub.7)                                                268   3-CHNO(n-C.sub.3 H.sub.7)                                                269   4-CHNO(n-C.sub.3 H.sub.7)                                                270   2-CHNO(i-C.sub.3 H.sub.7)                                                271   3-CHNO(i-C.sub.3 H.sub.7)                                                272   4-CHNO(i-C.sub.3 H.sub.7)                                                273   2-CHNO(i-C.sub.6 H.sub.13)                                               274   3-CHNO(i-C.sub.6 H.sub.13)                                               275   4-CHNO(i-C.sub.6 H.sub.13)                                               276   2-CHNO(n-C.sub.8 H.sub.17)                                               277   3-CHNO(n-C.sub.8 H.sub.17)                                               278   4-CHNO(n-C.sub.8 H.sub.17)                                               279   2-CHNOCH.sub.2 (C.sub.6 H.sub.5)                                         280   3-CHNOCH.sub.2 (C.sub.6 H.sub.5)                                         281   4-CHNOCH.sub.2 (C.sub.6 H.sub.5)                                         282   2-CO.sub.2 CH.sub.3                                                      283   3-CO.sub.2 CH.sub.3                                                      284   4-CO.sub.2 CH.sub.3                                                      285   2-CO.sub.2 (C.sub.2 H.sub.5)                                             286   3-CO.sub.2 (C.sub.2 H.sub.5)                                             287   4-CO.sub.2 (C.sub.2 H.sub.5)                                             288   2-CO.sub.2 (n-C.sub.3 H.sub.7)                                           289   3-CO.sub.2 (n-C.sub.3 H.sub.7)                                           290   4-CO.sub.2 (n-C.sub.3 H.sub.7)                                           291   2-CO.sub.2 (i-C.sub.3 H.sub.7)                                           292   3-CO.sub.2 (i-C.sub.3 H.sub.7)                                           293   4-CO.sub.2 (i-C.sub.3 H.sub.7)                                           294   2-CO.sub.2 (i-C.sub.6 H.sub.13)                                          295   3-CO.sub.2 (i-C.sub.6 H.sub.13)                                          296   4-CO.sub.2 (i-C.sub.6 H.sub.13)                                          297   2-CO.sub.2 (n-C.sub.8 H.sub.17)                                          298   3-CO.sub.2 (n-C.sub.8 H.sub.17)                                          299   4-CO.sub.2 (n-C.sub.8 H.sub.17)                                          300   2-CHNO CH.sub.2CHCH.sub.2                                                301   3-CHNOCH.sub.2CHCH.sub.2                                                 302   4-CHNOCH.sub.2CHCH.sub.2                                                 303   2-CHNO(CH.sub.2).sub.3 (C.sub.6 H.sub.5)                                 304   3-CHNO(CH.sub.2).sub.3 (C.sub.6 H.sub.5)                                 305   4-CHNO(CH.sub.2).sub.3 (C.sub.6 H.sub.5)                                 306   2-CH.sub.2 OCH.sub.3                                                     307   3-CH.sub.2 OCH.sub.3                                                     308   4-CH.sub.2 OCH.sub.3                                                     309   2-CH.sub.2 O(C.sub.2 H.sub.5)                                            310   3-CH.sub.2 O(C.sub.2 H.sub.5)                                            311   4-CH.sub.2 O(C.sub.2 H.sub.5)                                            312   2-CH.sub.2 O(n-C.sub.3 H.sub.7)                                          313   3-CH.sub.2 O(n-C.sub.3 H.sub.7)                                          314   4-CH.sub.2 O(n-C.sub.3 H.sub.7)                                          315   2-CH.sub.2 O(i-C.sub.3 H.sub.7)                                          316   3-CH.sub.2 O(i-C.sub.3 H.sub.7)                                          317   4-(CH.sub.2 O(i-C.sub.3 H.sub.7)                                         318   2-CH.sub.2 O(n-C.sub.6 H.sub.13)                                         319   3-CH.sub.2 O(n-C.sub.6 H.sub.13)                                         320   4-CH.sub.2 O(n-C.sub.6 H.sub.13)                                         321   2-CH.sub.2 O(n-C.sub.8 H.sub.17)                                         322   3-CH.sub.2 O(n-C.sub.8 H.sub.17)                                         323   4-CH.sub.2 O(n-C.sub.8 H.sub.7)                                          324   2-CH.sub.2 OCH.sub.2 (C.sub.6 H.sub.5)                                   325   3-CH.sub.2 OCH.sub.2 (C.sub. 6 H.sub.5)                                  326   4-CH.sub.2 OCH.sub.2 (C.sub.6 H.sub.5)                                   327   2-CH.sub.2 O(CH.sub.2).sub.3                                             328   3-CH.sub.2 O(CH.sub.2).sub.3 (C.sub.6 H.sub.5)                           329   4-CH.sub.2 O(CH.sub.2).sub.3 (C.sub.6 H.sub.5)                           330   2-CHO                                                                    331   3-CHO                                                                    332   4-CHO                                                                    ______________________________________                                    

                  TABLE 13                                                         ______________________________________                                          ##STR40##                                                                     No.  X.sub.m           mp        NMR: δ (ppm)                            ______________________________________                                         1    2-F                                                                       2    3-F                                                                       3    4-F                                                                       4    2,4-F.sub.2                                                               5    2,4,6-F.sub.3                                                             6    2,3,4,5,6-F.sub.5                                                         7    2,3-F.sub.2                                                               8    2-Cl              83-85                                                   9    3-Cl              oil       5.35(S, 2H);                                                                   7.6(S, 1H)                                    10   4-Cl              oil       5.35(S, 2H);                                                                   7.6(S, 1H)                                    11   2,3-Cl.sub.2                                                              12   2,4-Cl.sub.2                                                              13   2,5-Cl.sub.2                                                              14   2,6-Cl.sub.2                                                              15   3,4-Cl.sub.2                                                              16   3,5-Cl.sub.2                                                              17   2,3,4-Cl.sub.3                                                            18   2,3,5-Cl.sub.3                                                            19   2,3,6-Cl.sub.3                                                            20   2,4,5-Cl.sub.3                                                            21   2,4,6-Cl.sub.3                                                            22   3,4,5-Cl.sub.3                                                            23   2,3,4,6-Cl.sub.4                                                          24   2,3,5,6-Cl.sub.4                                                          25   2,3,4,5,6-Cl.sub.5                                                        26   2-Br                                                                      27   3-Br                                                                      28   4-Br                                                                      29   2,4-Br.sub.2                                                              30   2,5-Br.sub.5                                                              31   2,6-Br.sub.2                                                              32   2,4,6-Br.sub.3                                                            33   2,3,4,5,6-Br.sub.5                                                        34   2-I                                                                       35   3-I                                                                       36   4-I                                                                       37   2,4-I.sub.2                                                               38   2-Cl, 3-F                                                                 39   2-Cl, 4-F                                                                 40   2-Cl, 5-F                                                                 41   2-Cl, 6-F                                                                 42   2-Cl, 3-Br                                                                43   2-Cl, 4-Br                                                                44   2-Cl, 6-Br                                                                45   2-Cl, 6-Br                                                                46   2-Br, 3-Cl                                                                47   2-Br, 4-Cl                                                                48   2-Br, 5-Cl                                                                49   2-Br, 3-F                                                                 50   2-Br, 4-F                                                                 51   2-Br, 5-F                                                                 52   2-Br, 6-F                                                                 53   2-F, 3-Cl                                                                 54   2-F, 4-Cl                                                                 55   2-F, 5-Cl                                                                 56   3-Cl, 4-F                                                                 57   3-Cl, 5-F                                                                 58   3-Cl, 4-Br                                                                59   3-Cl, 5-Br                                                                60   3-F, 4-Cl                                                                 61   3-F, 4-Br                                                                 62   3-Br, 4-Cl                                                                63   3-Br, 4-F                                                                 64   2,6-Cl.sub.2, 4-Br                                                        65   2-CH.sub.3        68-69                                                   66   3-CH.sub.3        oil       5.35(S, 2H);                                                                   7.55(S, 1H)                                   67   4-CH.sub.3        oil       5.35(S, 2H);                                                                   7.55(S, 1H)                                   68   2,3-(CH.sub.3).sub.2                                                      69   2,4-(CH.sub.3).sub.2                                                      70   2,5-(CH.sub.3).sub.2                                                      71   2,6-(CH.sub.3).sub.2                                                      72   3,4-(CH.sub.3).sub.2                                                      73   3,5-(CH.sub.3).sub.2                                                      74   3,5-(CH.sub.3).sub.2                                                      75   2,3,4-(CH.sub.3).sub.3                                                    76   2,3,6-(CH.sub.3).sub.3                                                    77   2,4,5-(CH.sub.3).sub.3                                                    78   2,4,6-(CH.sub.3).sub.3                                                    79   3,4,5-(CH.sub.3).sub.3                                                    80   2,3,4,6-(CH.sub.3).sub.4                                                  81   2,3,5,6-(CH.sub.3).sub.4                                                  82   2,3,4,5,6-(CH.sub.3).sub.5                                                83   2-C.sub.2 H.sub.5                                                         84   3-C.sub.2 H.sub.5                                                         85   4-C.sub.2 H.sub.5                                                         86   2,4-(C.sub.2 H.sub.5).sub.2                                               87   2,6-(C.sub.2 H.sub.5).sub.2                                               88   3,5-(C.sub.2 H.sub.5).sub.2                                               89   2,4,6-(C.sub.2 H.sub.5).sub.3                                             90   2-n-C.sub.3 H.sub.7                                                       91   3-n-C.sub.3 H.sub.7                                                       92   4-n-C.sub.3 H.sub.7                                                       93   2-i-C.sub.3 H.sub.7                                                       94   3-i-C.sub.3 H.sub.7                                                       95   4-i-C.sub.3 H.sub.7                                                       96   2,4-(i-C.sub.3 H.sub.7).sub.2                                             97   2,6-(i-C.sub.3 H.sub.7).sub.2                                             98   3,5-(i-C.sub.3 H.sub.7).sub.2                                             99   2,4,6-(i-C.sub.3 H.sub.7).sub.3                                           100  2-SC.sub.4 H.sub.9                                                        101  3-SC.sub.4 H.sub.9                                                        102  4-SC.sub.4 H.sub.9                                                        103  2-t-C.sub.4 H.sub.9                                                       104  3-t-C.sub.4 H.sub.9                                                       105  4-t-C.sub.4 H.sub.9                                                       106  2,3-(t-C.sub.4 H.sub.9).sub.2                                             107  2,4-(t-C.sub.4 H.sub.9).sub.2                                             108  2,5-(t-C.sub.4 H.sub.9).sub.2                                             109  2,6-(t-C.sub.4 H.sub.9).sub.2                                             110  3,4-(t-C.sub.4 H.sub.9).sub.2                                             111  2,4,6-(t-C.sub.4 H.sub.9).sub.3                                           112  4-n-C.sub.9 H.sub.19                                                      113  4-n-C.sub.12 H.sub.25                                                     114  3-n-C.sub.15 H.sub.31                                                     115  4-(1,1,3,3-tetramethylbutyl)                                              116  4-(2,4,4-trimethylpropyl                                                  117  2-t-C.sub.4 H.sub.9, 4-CH.sub.3                                           118  2-t-C.sub.4 H.sub.9, 5-CH.sub.3                                           119  2,6-(t-C.sub.4 H.sub.9), 4-CH.sub.3                                       120  2-CH.sub.3, 4-t-C.sub.4 H.sub.9                                           121  2-CH.sub.3, 6-t-C.sub.4 H.sub.9                                           122  2-CH.sub. 3, 4-i-C.sub.3 H.sub.7                                          123  2-CH.sub.3, 5-i-C.sub.3 H.sub.7                                           124  3-CH.sub.3, 4-i-C.sub.3 H.sub.7                                           125  2-i-C.sub.3 H.sub.7, 5 CH.sub.3                                           126  2,4-(t-C.sub.4 H.sub.9), 6-i-C.sub.3 H.sub.7                              127  2-allyl                                                                   128  3-allyl                                                                   129  4-allyl                                                                   130  2-allyl, 6-CH.sub.3                                                       131  2-cyclo-C.sub.6 H.sub.11                                                  132  3-cyclo-C.sub.6 H.sub.11                                                  133  4-cyclo-C.sub.6 H.sub.11                                                  134  2,4-(cyclo-C.sub.6 H.sub.11).sub.2, 6-CH.sub.3                            135  2-CH.sub.3, 4-cyclo-C.sub.6 H.sub.11                                      136  2-CH.sub.2C.sub.6 H.sub.5                                                 137  3-CH.sub.2C.sub.6 H.sub.5                                                 138  4-CH.sub.2C.sub.6 H.sub.5                                                 139  2-CH.sub.2C.sub.6 H.sub.5, 4-CH.sub.3                                     140  2-CH.sub.3, 4-CH.sub.2C.sub.6 H.sub.5                                     141  2-C.sub.6 H.sub.5                                                         142  3-C.sub.6 H.sub.5                                                         143  4-C.sub.6 H.sub.5                                                         144  4-(2-i-C.sub.3 H.sub.7C.sub.6 H.sub.4)                                    145  4-C.sub.6 H.sub.5, 2,6-(CH.sub.3).sub.2                                   146  2-Cl, 4-C.sub.6 H.sub.5                                                   147  2-Br, 4-C.sub.6 H.sub.5                                                   148  2-C.sub.6 H.sub.5, 4-Cl                                                   149  2-C.sub.6 H.sub.5, 4-Br                                                   150  2-CH.sub.2 C.sub.6 H.sub.5, 4-Cl                                          151  2-CH.sub.2 C.sub.6 H.sub.5, 4-Br                                          152  2-Cl, 4-CH.sub.2 C.sub.6 H.sub.5                                          153  2-Br, 4-CH.sub.2 C.sub.6 H.sub.5                                          154  2-cyclo-C.sub.6 H.sub.11, 4-Cl                                            155  2-cyclo-C.sub.6 H.sub.11, 4-Br                                            156  2-Cl, 4-cyclo-C.sub.6 H.sub.11                                            157  2-Br, 4-cyclo-C.sub.6 H.sub.11                                            158  2-OCH.sub.3       89-91                                                   159  3-OCH.sub.3       72-73                                                   160  4-OCH.sub.3       oil       5.35(S, 2H);                                                                   7.55(S, 1H)                                   161  2-OC.sub.2 H.sub.5                                                        162  3-OC.sub.2 H.sub.5                                                        163  4-OC.sub.2 H.sub.5                                                        164  2-O-n-C.sub.3 H.sub.7                                                                            oil       5.35(S, 2H);                                                                   7.55(S, 1H)                                   165  3-O-n-C.sub.3 H.sub.7                                                                            oil       5.35(S, 2H);                                                                   7.55(S, 1H)                                   166  4-O-n-C.sub.3 H.sub.7                                                                            73-74                                                   167  2-O-i-C.sub.3 H.sub.7                                                     168  3-O-i-C.sub.3 H.sub.7                                                     169  4-O-i-C.sub.3 H.sub.7                                                     170  2-O-n-C.sub.6 H.sub.13                                                                           oil       5.35(S, 2H);                                                                   7.55(S, 1H)                                   171  3-O-n-C.sub.6 H.sub.13                                                                           43-45                                                   172  4-O-n-C.sub.6 H.sub.13                                                    173  2-O-n-C.sub.8 H.sub.17                                                    174  3-O-n-C.sub.8 H.sub.17                                                    175  4-O-n-C.sub.8 H.sub.17                                                    176  2-OCH.sub.2 C.sub.6 H.sub.5                                                                      oil       5.35(S, 2H);                                                                   7.55(S, 1H)                                   177  3-OCH.sub.2 C.sub.6 H.sub.5                                                                      oil       5.35(S, 2H);                                                                   7.55(S, 1H)                                   178  4-OCH.sub.2 C.sub.6 H.sub.5                                                                      103-106                                                 179  2-O(CH.sub.2).sub.3 C.sub.6 H.sub.5                                                              oil       5.35(S, 2H);                                                                   7.55(S, 1H)                                   180  3-O(CH.sub.2).sub.3 C.sub.6 H.sub.5                                                              oil       5.35(S, 2H);                                                                   7.55(S, 1H)                                   181  4-O(CH.sub.2).sub.3 C.sub.6 H.sub.5                                                              oil       5.35(S, 2H);                                                                   7.55(S, 1H)                                   182  2,4-(OCH.sub.3).sub.2                                                     183  2-CF.sub.3                                                                184  3-CF.sub.3                                                                185  4-CF.sub.3                                                                186  2-OCF.sub.3                                                               187  3-OCF.sub.3                                                               188  4-OCF.sub.3                                                               189  3-OCH.sub.2 CHF.sub.2                                                     190  2-NO.sub.2                                                                191  3-NO.sub.2                                                                192  4-NO.sub.2                                                                193  2-CN                                                                      194  3-CN                                                                      195  4-CN                                                                      196  2-CH.sub.3, 3-Cl                                                          197  2-CH.sub.3, 4-Cl                                                          198  2-CH.sub.3, 5-Cl                                                          199  2-CH.sub.3, 6-Cl                                                          200  2-CH.sub.3, 3-F                                                           201  2-CH.sub.3, 4-F                                                           202  2-CH.sub.3, 5-F                                                           203  2-CH.sub.3, 6-F                                                           204  2-CH.sub.3, 3-Br                                                          205  2-CH.sub.3, 4-Br                                                          206  2-CH.sub.3, 5-Br                                                          207  2-CH.sub.3, 6-Br                                                          208  2-Cl, 3-CH.sub.3                                                          209  2-Cl, 4-CH.sub.3                                                          210  2-Cl, 5-CH.sub.3                                                          211  2-F, 3-CH.sub.3                                                           212  2-F, 4-CH.sub.3                                                           213  2-F, 5-CH.sub.3                                                           214  2-Br, 3-CH.sub.3                                                          215  2-Br, 4-CH.sub.3                                                          216  2-Br, 5-CH.sub.3                                                          217  3-CH.sub.3, 4-Cl                                                          218  3-CH.sub.3, 5-Cl                                                          219  3-CH.sub.3, 4-F                                                           220  3-CH.sub.3, 4-Br                                                          221  3-CH.sub.3, 4-Br                                                          222  3-CH.sub.3, 5-Br                                                          223  3-F, 4-CH.sub.3                                                           224  3-Cl, 4-CH.sub.3                                                          225  3-Br, 4-CH.sub.3                                                          226  2-Cl, 4,5-(CH.sub.3).sub.2                                                227  2-Br, 4,5-(CH.sub.3).sub.2                                                228  2-Cl, 3,5-(CH.sub.3).sub.2                                                229  2-Br, 3,5-(CH.sub.3).sub.2                                                230  2,6-Cl.sub.2, 4-CH.sub.3                                                  231  2,6-F.sub.2, 4-CH.sub.3                                                   232  2,6-Br.sub.2, 4-CH.sub.3                                                  233  2,4-Cl.sub.2, 4-CH.sub.3                                                  234  2,4-F.sub.2, 4-CH.sub.3                                                   235  2,4-Br.sub.2, 4-CH.sub.3                                                  236  2,6-(CH.sub.3).sub.2, 4-F                                                 237  2,6-(CH.sub.3).sub.2, 4-Cl                                                238  2,6-(CH.sub.3).sub.2, 4-Br                                                239  3,5-(CH.sub.3).sub.2, 4-F                                                 240  3,5-(CH.sub.3).sub.2, 4-Cl                                                241  3,5-(CH.sub.3).sub.2, 4-Br                                                242  2,3,6-(CH.sub.3).sub.3, 4-F                                               243  2,3,6-(CH.sub.3).sub.3, 4-Cl                                              244  2,3,6-(CH.sub.3).sub.3, 4-Br                                              245  2,4-(CH.sub.3).sub.2, 6-F                                                 246  2,4-(CH.sub.3).sub.2, 6-Cl                                                247  2,4-(CH.sub.3).sub.62, 6-Br                                               248  2-i-C.sub.3 H.sub.7, 4-Cl, 5-CH.sub.3                                     249  2-Cl, 4-NO.sub.2                                                          250  2-NO.sub.2, 4-Cl                                                          251  2-OCH.sub.3, 5-NO.sub.2                                                   252  2,4-Cl.sub.2, 5-NO.sub.2                                                  253  2,4-Cl.sub.2, 6-NO.sub.2                                                  254  2,6-Cl.sub.2, 4-NO.sub.2                                                  255  2,6-Br.sub.2, 4-NO.sub.2                                                  256  2,6-I.sub.2, 4-NO.sub.2                                                   257  2-CH.sub.3, 5-i-C.sub.3 H.sub.7, 4-Cl                                     258  2-C.sub.6 H.sub.5 O                                                       259  3-C.sub.6 H.sub.5 O                                                       260  4-C.sub.6 H.sub.5 O                                                       261  2-CHNOCH.sub.3                                                            262  3-CHNOCH.sub.3                                                            263  4-CHNOCH.sub.3                                                            264  2-CHNOC.sub.2 H.sub.5                                                     265  3-CHNOC.sub.2 H.sub.5                                                     266  4-CHNOC.sub.2 H.sub.5                                                     267  2-CHNO(n-C.sub.3 H.sub.7)                                                 268  3-CHNO(n-C.sub.3 H.sub.7)                                                 269  4-CHNO(n-C.sub.3 H.sub.7)                                                 270  2-CHNO(i-C.sub.3 H.sub.7)                                                 271  3-CHNO(i-C.sub.3 H.sub.7)                                                 272  4-CHNO(i-C.sub.3 H.sub.7)                                                 273  2-CHNO(i-C.sub.6 H.sub.13)                                                274  3-CHNO(i-C.sub.6 H.sub.13)                                                275  4-CHNO(i-C.sub.6 H.sub.13)                                                276  2-CHNO(n-C.sub.8 H.sub.17)                                                277  3-CHNO(n-C.sub.8 H.sub.17)                                                278  4-CHNO(n-C.sub.8 H.sub.17)                                                279  2-CHNOCH.sub.2 (C.sub.6 H.sub.5)                                          280  3-CHNOCH.sub.2 (C.sub.6 H.sub.5)                                          281  4-CHNOCH.sub.2 (C.sub.6 H.sub.5)                                          282  2-CO.sub.2 CH.sub.3                                                       283  3-CO.sub.2 CH.sub.3                                                       284  4-CO.sub.2 CH.sub.3                                                       285  2-CO.sub.2 (C.sub.2 H.sub.5)                                              286  3-CO.sub.2 (C.sub.2 H.sub.5)                                              287  4-CO.sub.2 (C.sub.2 H.sub.5)                                              288  2-CO.sub.2 (n-C.sub.3 H.sub.7)                                            289  3-CO.sub.2 (n-C.sub.3 H.sub.7)                                            290  4-CO.sub.2 (n-C.sub.3 H.sub.7)                                            291  2-CO.sub.2 (i-C.sub.3 H.sub.7)                                            292  3-CO.sub.2 (i-C.sub.3 H.sub.7)                                            293  4-CO.sub.2 (i-C.sub.3 H.sub.7)                                            294  2-CO.sub.2 (i-C.sub.6 H.sub.13)                                           295  3-CO.sub.2 (i-C.sub.6 H.sub.13)                                           296  4-CO.sub.2 (i-C.sub.6 H.sub.13)                                           297  2-CO.sub.2 (n-C.sub.8 H.sub.17)                                           298  3-CO.sub.2 (n-C.sub.8 H.sub.17)                                           299  4-CO.sub.2 (n-C.sub.8 H.sub.17)                                           300  2-CHNOCH.sub.2CHCH.sub.2                                                  301  3-CHNOCH.sub.2CHCH.sub.2                                                  302  4-CHNOCH.sub.2CHCH.sub.2                                                  303  2-CHNO(CH.sub.2).sub.3 (C.sub.6 H.sub.5)                                  304  3-CHNO(CH.sub.2).sub.3 (C.sub.6 H.sub.5)                                  305  4-CHNO(CH.sub.2).sub.3 (C.sub.6 H.sub.5)                                  306  2-CH.sub.2 OCH.sub.3                                                      307  3-CH.sub.2 OCH.sub.3                                                      308  4-CH.sub.2 OCH.sub.3                                                      309  2-CH.sub.2 O(C.sub. 2 H.sub.5)                                            310  3-CH.sub.2 O(C.sub.2 H.sub.5)                                             311  4-CH.sub.2 O(C.sub.2 H.sub.5)                                             312  2-CH.sub.2 O(n-C.sub.3 H.sub.7)                                           313  3-CH.sub.2 O(n-C.sub.3 H.sub.7)                                           314  4-CH.sub.2 O(n-C.sub.3 H.sub.7)                                           315  2-CH.sub.2 O(i-C.sub.3 H.sub.7)                                           316  3-CH.sub.2 O(i-C.sub.3 H.sub.7)                                           317  4-(CH.sub.2 O(i-C.sub.3 H.sub.7)                                          318  2-CH.sub.2 O(n-C.sub.6 H.sub.13)                                          319  3-CH.sub.2 O(n-C.sub.6 H.sub.13)                                          320  4-CH.sub.2 O(n-C.sub.6 H.sub.13)                                          321  2-CH.sub.2 O(n-C.sub.8 H.sub.17)                                          322  3-CH.sub.2 O(n-C.sub.8 H.sub.17)                                          323  4-CH.sub.2 O(n-C.sub.8 H.sub.7)                                           324  2-CH.sub.2 OCH.sub.2 (C.sub.6 H.sub.5)                                    325  3-CH.sub.2 OCH.sub.2 (C.sub.6 H.sub.5)                                    326  4-CH.sub.2 OCH.sub.2 (C.sub.6 H.sub.5)                                    327  2-CH.sub.2 O(CH.sub.2).sub.3                                              328  3-CH.sub.2 O(CH.sub.2).sub.3 (C.sub.6 H.sub.5)                            329  4-CH.sub.2 O(CH.sub.2).sub.3 (C.sub.6 H.sub.5)                            330  2-CHO                                                                     331  3-CHO                                                                     332  4-CHO                                                                     ______________________________________                                    

                  TABLE 14                                                         ______________________________________                                          ##STR41##                                                                     No.  X.sub.m          mp      NMR: δ (ppm)                               ______________________________________                                         1    2-F                                                                       2    3-F                                                                       3    4-F                                                                       4    2,4-F.sub.2                                                               5    2,4,6-F.sub.3                                                             6    2,3,4,5,6-F.sub.5                                                         7    2,3-F.sub.2                                                               8    2-Cl                                                                      9    3-Cl                                                                      10   4-Cl                                                                      11   2,3-Cl.sub.2                                                              12   2,4-Cl.sub.2                                                              13   2,5-Cl.sub.2                                                              14   2,6-Cl.sub.2                                                              15   3,4-Cl.sub.2                                                              16   3,5-Cl.sub.2                                                              17   2,3,4-Cl.sub.3                                                            18   2,3,5-Cl.sub.3                                                            19   2,3,6-Cl.sub.3                                                            20   2,4,5-Cl.sub.3                                                            21   2,4,6-Cl.sub.3                                                            22   3,4,5-Cl.sub.3                                                            23   2,3,4,6-Cl.sub.4                                                          24   2,3,5,6-Cl.sub.4                                                          25   2,3,4,5,6-Cl.sub.5                                                        26   2-Br                                                                      27   3-Br                                                                      28   4-Br                                                                      29   2,4-Br.sub.2                                                              30   2,5-Br.sub.5                                                              31   2,6-Br.sub.2                                                              32   2,4,6-Br.sub.3                                                            33   2,3,4,5,6-Br.sub.5                                                        34   2-I                                                                       35   3-I                                                                       36   4-I                                                                       37   2,4-I.sub.2                                                               38   2-Cl, 3-F                                                                 39   2-Cl, 4-F                                                                 40   2-Cl, 5-F                                                                 41   2-Cl, 6-F                                                                 42   2-Cl, 3-Br                                                                43   2-Cl, 4-Br                                                                44   2-Cl, 6-Br                                                                45   2-Cl, 6-Br                                                                46   2-Br, 3-Cl                                                                47   2-Br, 4-Cl                                                                48   2-Br, 5-Cl                                                                49   2-Br, 3-F                                                                 50   2-Br, 4-F                                                                 51   2-Br, 5-F                                                                 52   2-Br, 6-F                                                                 53   2-F, 3-Cl                                                                 54   2-F, 4-Cl                                                                 55   2-F, 5-Cl                                                                 56   3-Cl, 4-F                                                                 57   3-Cl, 5-F                                                                 58   3-Cl, 4-Br                                                                59   3-Cl, 5-Br                                                                60   3-F, 4-Cl                                                                 61   3-F, 4-Br                                                                 62   3-Br, 4-Cl                                                                63   3-Br, 4-F                                                                 64   2,6-Cl.sub.2, 4-Br                                                        65   2-CH.sub.3                                                                66a) 3-CH.sub.3 : non-polar isomer                                                                   oil     3.9(S, 3H); 4.0(S, 3H);                                                        5.15(S, 2H)                                      66b) 3-CH.sub.3 : polar isomer                                                                       66-70                                                    67   4-CH.sub.3                                                                68   2,3-(CH.sub.3).sub.2                                                      69   2,4-(CH.sub.3).sub.2                                                      70   2,5-(CH.sub.3).sub.2                                                      71   2,6-(CH.sub.3).sub.2                                                      72   3,4-(CH.sub.3).sub.2                                                      73   3,5-(CH.sub.3).sub.2                                                      74   3,5-(CH.sub.3).sub.2                                                      75   2,3,4-(CH.sub.3).sub.3                                                    76   2,3,6-(CH.sub.3).sub.3                                                    77   2,4,5-(CH.sub.3).sub.3                                                    78   2,4,6-(CH.sub.3).sub.3                                                    79   3,4,5-(CH.sub.3).sub.3                                                    80   2,3,4,6-(CH.sub.3).sub.4                                                  81   2,3,5,6-(CH.sub.3).sub.4                                                  82   2,3,4,5,6-(CH.sub.3).sub.5                                                83   2-C.sub.2 H.sub.5                                                         84   3-C.sub.2 H.sub.5                                                         85   4-C.sub.2 H.sub.5                                                         86   2,4-(C.sub.2 H.sub.5).sub.2                                               87   2,6-(C.sub.2 H.sub.5).sub.2                                               88   3,5-(C.sub.2 H.sub.5).sub.2                                               89   2,4,6-(C.sub.2 H.sub.5).sub.3                                             90   2-n-C.sub.3 H.sub.7                                                       91   3-n-C.sub.3 H.sub.7                                                       92   4-n-C.sub.3 H.sub.7                                                       93   2-i-C.sub.3 H.sub.7                                                       94   3-i-C.sub.3 H.sub.7                                                       95   4-i-C.sub.3 H.sub.7                                                       96   2,4-(i-C.sub.3 H.sub.7).sub.2                                             97   2,6-(i-C.sub.3 H.sub.7).sub.2                                             98   3,5-(i-C.sub.3 H.sub.7).sub.2                                             99   2,4,6-(i-C.sub.3 H.sub.7).sub.3                                           100  2-SC.sub.4 H.sub.9                                                        101  3-SC.sub.4 H.sub.9                                                        102  4-SC.sub.4 H.sub.9                                                        103  2-t-C.sub.4 H.sub.9                                                       104  3-t-C.sub.4 H.sub.9                                                       105  4-t-C.sub.4 H.sub.9                                                       106  2,3-(t-C.sub.4 H.sub.9).sub.2                                             107  2,4-(t-C.sub.4 H.sub.9).sub.2                                             108  2,5-(t-C.sub.4 H.sub.9).sub.2                                             109  2,6-(t-C.sub.4 H.sub.9).sub.2                                             110  3,4-(t-C.sub.4 H.sub.9).sub.2                                             111  2,4,6-(t-C.sub.4 H.sub.9).sub.3                                           112  4-n-C.sub.9 H.sub.19                                                      113  4-n-C.sub.12 H.sub.25                                                     114  3-n-C.sub.15 H.sub.31                                                     115  4-(1,1,3,3-tetramethylbutyl)                                              116  4-(2,4,4-trimethylpropyl                                                  117  2-t-C.sub.4 H.sub.9, 4-CH.sub.3                                           118  2-t-C.sub.4 H.sub.9, 5-CH.sub.3                                           119  2,6-(t-C.sub.4 H.sub.9), 4-CH.sub.3                                       120  2-CH.sub.3, 4-t-C.sub.4 H.sub.9                                           121  2-CH.sub.3, 6-t-C.sub.4 H.sub.9                                           122  2-CH.sub.3, 4-i-C.sub.3 H.sub.7                                           123  2-CH.sub.3, 5-i-C.sub.3 H.sub.7                                           124  3-CH.sub. 3, 4-i-C.sub.3 H.sub.7                                          125  2-i-C.sub.3 H.sub.7, 5 CH.sub.3                                           126  2,4-(t-C.sub.4 H.sub.9), 6-i-C.sub.3 H.sub.7                              127  2-allyl                                                                   128  3-allyl                                                                   129  4-allyl                                                                   130  2-allyl, 6-CH.sub.3                                                       131  2-cyclo-C.sub.6 H.sub.11                                                  132  3-cyclo-C.sub.6 H.sub.11                                                  133  4-cyclo-C.sub.6 H.sub.11                                                  134  2,4-(cyclo-C.sub.6 H.sub.11).sub.2, 6-CH.sub.3                            135  2-CH.sub.3, 4-cyclo-C.sub.6 H.sub.11                                      136  2-CH.sub.2C.sub.6 H.sub.5                                                 137  3-CH.sub.2C.sub.6 H.sub.5                                                 138  4-CH.sub.2C.sub.2 H.sub.5                                                 139  2-CH.sub.2C.sub.6 H.sub.5, 4-CH.sub.3                                     140  2-CH.sub.3, 4-CH.sub.2C.sub.6 H.sub.5                                     141  2-C.sub.6 H.sub.5                                                         142  3-C.sub.6 H.sub.5                                                         143  4-C.sub.6 H.sub.5                                                         144  4-(2-i-C.sub.3 H.sub.7C.sub.6 H.sub.4)                                    145  4-C.sub.6 H.sub.5, 2,6-(CH.sub.3).sub.2                                   146  2-Cl, 4-C.sub.6 H.sub.5                                                   147  2-Br, 4-C.sub.6 H.sub.5                                                   148  2-C.sub.6 H.sub.5, 4-Cl                                                   149  2-C.sub.6 H.sub.5, 4-Br                                                   150  2-CH.sub.2 C.sub.6 H.sub.5, 4-Cl                                          151  2-CH.sub.2 C.sub.6 H.sub.5, 4-Br                                          152  2-Cl, 4-CH.sub.2 C.sub.6 H.sub.5                                          153  2-Br, 4-CH.sub.2 C.sub.6 H.sub.5                                          154  2-cyclo-C.sub.6 H.sub.11, 4-Cl                                            155  2-cyclo-C.sub.6 H.sub.11, 4-Br                                            156  2-Cl, 4-cyclo-C.sub.6 H.sub.11                                            157  2-Br, 4-cyclo-C.sub.6 H.sub.11                                            158  2-OCH.sub.3                                                               159  3-OCH.sub.3                                                               160  4-OCH.sub.3                                                               161  2-OC.sub.2 H.sub.5                                                        162  3-OC.sub.2 H.sub.5                                                        163  4-OC.sub.2 H.sub.5                                                        164  2-O-n-C.sub.3 H.sub.7                                                     165  3-O-n-C.sub.3 H.sub.7                                                     166  4-O-n-C.sub.3 H.sub.7                                                     167  2-O-i-C.sub.3 H.sub.7                                                     168  3-O-i-C.sub.3 H.sub.7                                                     169  4-O-i-C.sub.3 H.sub.7                                                     170  2-O-n-C.sub.6 H.sub.13                                                    171  3-O-n-C.sub.6 H.sub.13                                                    172  4-O-n-C.sub.6 H.sub.13                                                    173  2-O-n-C.sub.8 H.sub.17                                                    174  3-O-n-C.sub.8 H.sub.17                                                    175  4-O-n-C.sub.8 H.sub.17                                                    176  2-OCH.sub.2 C.sub.6 H.sub.5                                               177  3-OCH.sub.2 C.sub.6 H.sub.5                                               178  4-OCH.sub.2 C.sub.6 H.sub.5                                               179  2-O(CH.sub.2).sub.3 C.sub.6 H.sub.5                                       180  3-O(CH.sub.2).sub.3 C.sub.6 H.sub.5                                       181  4-O(CH.sub.2).sub.3 C.sub.6 H.sub.5                                       182  2,4-(OCH.sub.3).sub.2                                                     183  2-CF.sub.3                                                                184  3-CF.sub.3                                                                185  4-CF.sub.3                                                                186  2-OCF.sub.3                                                               187  3-OCF.sub.3                                                               188  4-OCF.sub.3                                                               189  3-OCH.sub.2 CHF.sub.2                                                     190  2-NO.sub. 2                                                               191  3-NO.sub.2                                                                192  4-NO.sub.2                                                                193  2-CN                                                                      194  3-CN                                                                      195  4-CN                                                                      196  2-CH.sub.3, 3-Cl                                                          197  2-CH.sub.3, 4-Cl                                                          198  2-CH.sub.3, 5-Cl                                                          199  2-CH.sub.3, 6-Cl                                                          200  2-CH.sub.3, 3-F                                                           201  2-CH.sub.3, 4-F                                                           202  2-CH.sub.3, 5-F                                                           203  2-CH.sub.3, 6-F                                                           204  2-CH.sub.3, 3-Br                                                          205  2-CH.sub.3, 4-Br                                                          206  2-CH.sub.3, 5-Br                                                          207  2-CH.sub.3, 6-Br                                                          208  2-Cl, 3-CH.sub.3                                                          209  2-Cl, 4-CH.sub.3                                                          210  2-Cl, 5-CH.sub.3                                                          211  2-F, 3-CH.sub.3                                                           212  2-F, 4-CH.sub.3                                                           213  2-F, 5-CH.sub.3                                                           214  2-Br, 3-CH.sub.3                                                          215  2-Br, 4-CH.sub.3                                                          216  2-Br, 5-CH.sub.3                                                          217  3-CH.sub.3, 4-Cl                                                          218  3-CH.sub.3, 5-Cl                                                          219  3-CH.sub.3, 4-F                                                           220  3-CH.sub.3, 4-Br                                                          221  3-CH.sub.3, 4-Br                                                          222  3-CH.sub.3, 5-Br                                                          223  3-F, 4-CH.sub.3                                                           224  3-Cl, 4-CH.sub.3                                                          225  3-Br, 4-CH.sub.3                                                          226  2-Cl, 4,5-(CH.sub.3).sub.2                                                227  2-Br, 4,5-(CH.sub.3).sub.2                                                228  2-Cl, 3,5-(CH.sub.3).sub.2                                                229  2-Br, 3,5-(CH.sub.3).sub.2                                                230  2,6-Cl.sub.2, 4-CH.sub.3                                                  231  2,6-F.sub.2, 4-CH.sub.3                                                   232  2,6-Br.sub.2, 4-CH.sub.3                                                  233  2,4-Cl.sub.2, 6-CH.sub.3                                                  234  2,4-F.sub.2, 6-CH.sub.3                                                   235  2,4-Br.sub.2, 6-CH.sub.3                                                  236  2,6-(CH.sub.3).sub.2, 4-F                                                 237  2,6-(CH.sub.3).sub.2, 4-Cl                                                238  2,6-(CH.sub.3).sub.2, 4-Br                                                239  3,5-(CH.sub.3).sub.2, 4-F                                                 240  3,5-(CH.sub.3).sub.2, 4-Cl                                                241  3,5-(CH.sub.3).sub.2, 4-Br                                                242  2,3,6-(CH.sub.3).sub.3, 4-F                                               243  2,3,6-(CH.sub.3).sub.3, 4-Cl                                              244  2,3,6-(CH.sub.3).sub.3, 4-Br                                              245  2,4-(CH.sub.3).sub.2, 6-F                                                 246  2,4-(CH.sub.3).sub.2, 6-Cl                                                247  2,4-(CH.sub.3).sub.62, 6-Br                                               248  2-i-C.sub.3 H.sub.7, 4-Cl, 5-CH.sub.3                                     249  2-Cl, 4-NO.sub.2                                                          250  2-NO.sub.2, 4-Cl                                                          251  2-OCH.sub.3, 5-NO.sub.2                                                   252  2,4-Cl.sub.2, 5-NO.sub.2                                                  253  2,4-Cl.sub.2, 6-NO.sub.2                                                  254  2,6-Cl.sub.2, 4-NO.sub.2                                                  255  2,6-Br.sub.2, 4-NO.sub.2                                                  256  2,6-I.sub.2, 4-NO.sub.2                                                   257  2-CH.sub.3, 5-i-C.sub.3 H.sub.7, 4-Cl                                     258  2-C.sub.6 H.sub.5 O                                                       259  3-C.sub.6 H.sub.5 O                                                       260  4-C.sub.6 H.sub.5 O                                                       261  2-CHNOCH.sub.3                                                            262  3-CHNOCH.sub.3                                                            263  4-CHNOCH.sub.3                                                            264  2-CHNOC.sub.2 H.sub.5                                                     265  3-CHNOC.sub.2 H.sub.5                                                     266  4-CHNOC.sub.2 H.sub. 5                                                    267  2-CHNO(n-C.sub.3 H.sub.7)                                                 268  3-CHNO(n-C.sub.3 H.sub.7)                                                 269  4-CHNO(n-C.sub.3 H.sub.7)                                                 270  2-CHNO(i-C.sub.3 H.sub.7)                                                 271  3-CHNO(i-C.sub.3 H.sub.7)                                                 272  4-CHNO(i-C.sub.3 H.sub.7)                                                 273  2-CHNO(n-C.sub.6 H.sub.13)                                                274  3-CHNO(n-C.sub.6 H.sub.13)                                                275  4-CHNO(n-C.sub.6 H.sub.13)                                                276  2-CHNO(n-C.sub.8 H.sub.17)                                                277  3-CHNO(n-C.sub.8 H.sub.17)                                                278  4-CHNO(n-C.sub.8 H.sub.17)                                                279  2-CHNOCH.sub.2 (C.sub.6 H.sub.5)                                          280  3-CHNOCH.sub.2 (C.sub.6 H.sub.5)                                          281  4-CHNOCH.sub.2 (C.sub.6 H.sub.5)                                          282  2-CO.sub.2 CH.sub.3                                                       283  3-CO.sub.2 CH.sub.3                                                       284  4-CO.sub.2 CH.sub.3                                                       285  2-CO.sub.2 (C.sub.2 H.sub.5)                                              286  3-CO.sub.2 (C.sub.2 H.sub.5)                                              287  4-CO.sub.2 (C.sub.2 H.sub.5)                                              288  2-CO.sub.2 (n-C.sub.3 H.sub.7)                                            289  3-CO.sub.2 (n-C.sub.3 H.sub.7)                                            290  4-CO.sub.2 (n-C.sub.3 H.sub.7)                                            291  2-CO.sub.2 (i-C.sub.3 H.sub.7)                                            292  3-CO.sub.2 (i-C.sub.3 H.sub.7)                                            293  4-CO.sub.2 (i-C.sub.3 H.sub.7)                                            294  2-CO.sub.2 (n-C.sub.6 H.sub.13)                                           295  3-CO.sub.2 (n-C.sub.6 H.sub.13)                                           296  4-CO.sub.2 (n-C.sub.6 H.sub.13)                                           297  2-CO.sub.2 (n-C.sub.8 H.sub.17)                                           298  3-CO.sub.2 (n-C.sub.8 H.sub.17)                                           299  4-CO.sub.2 (n-C.sub.8 H.sub.17)                                           300  2-CHNOCH.sub.2CHCH.sub.2                                                  301  3-CHNOCH.sub.2CHCH.sub.2                                                  302  4-CHNOCH.sub.2CHCH.sub.2                                                  303  2-CHNO(CH.sub.2).sub.3 (C.sub.6 H.sub.5)                                  304  3-CHNO(CH.sub.2).sub.3 (C.sub.6 H.sub.5)                                  305  4-CHNO(CH.sub.2).sub.3 (C.sub.6 H.sub.5)                                  306  2-CH.sub.2 OCH.sub.3                                                      307  3-CH.sub.2 OCH.sub.3                                                      308  4-CH.sub.2 OCH.sub.3                                                      309  2-CH.sub.2 O(C.sub.2 H.sub.5)                                             310  3-CH.sub.2 O(C.sub.2 H.sub.5)                                             311  4-CH.sub.2 O(C.sub.2 H.sub.5)                                             312  2-CH.sub.2 O(n-C.sub.3 H.sub.7)                                           313  3-CH.sub.2 O(n-C.sub.3 H.sub.7)                                           314  4-CH.sub.2 O(n-C.sub.3 H.sub.7)                                           315  2-CH.sub.2 O(i-C.sub.3 H.sub.7)                                           316  3-CH.sub.2 O(i-C.sub.3 H.sub.7)                                           317  4-(CH.sub.2 O(i-C.sub.3 H.sub.7)                                          318  2-CH.sub.2 O(n-C.sub.6 H.sub.13)                                          319  3-CH.sub.2 O(n-C.sub.6 H.sub.13)                                          320  4-CH.sub.2 O(n-C.sub.6 H.sub.13)                                          321  2-CH.sub.2 O(n-C.sub.8 H.sub. 17)                                         322  3-CH.sub.2 O(n-C.sub.8 H.sub.17)                                          323  4-CH.sub.2 O(n-C.sub.8 H.sub.7)                                           324  2-CH.sub.2 OCH.sub.2 (C.sub.6 H.sub.5)                                    325  3-CH.sub.2 OCH.sub.2 (C.sub.6 H.sub.5)                                    326  4-CH.sub.2 OCH.sub.2 (C.sub.6 H.sub.5)                                    327  2-CH.sub.2 O(CH.sub.2).sub.3                                              328  3-CH.sub.2 O(CH.sub.2).sub.3 (C.sub.6 H.sub.5)                            329  4-CH.sub.2 O(CH.sub.2).sub.3 (C.sub.6 H.sub.5)                            330  2-CHO                                                                     331  3-CHO                                                                     332  4-CHO                                                                     ______________________________________                                    

                  TABLE 15                                                         ______________________________________                                          ##STR42##                                                                     No.   X.sub.m            mp     NMR: δ (ppm)                             ______________________________________                                          1    2-F                                                                       2    3-F                                                                       3    4-F                                                                       4    2,4-F.sub.2                                                               5    2,4,6-F.sub.3                                                             6    2,3,4,5,6-F.sub.5                                                         7    2,3-F.sub.2                                                               8    2-Cl                                                                      9    3-Cl                                                                      10   4-Cl                                                                      11   2,3-Cl.sub.2                                                              12   2,4-Cl.sub.2                                                              13   2,5-Cl.sub.2                                                              14   2,6-Cl.sub.2                                                              15   3,4-Cl.sub.2                                                              16   3,5-Cl.sub.2                                                              17   2,3,4-Cl.sub.3                                                            18   2,3,5-Cl.sub.3                                                            19   2,3,6-Cl.sub.3                                                            20   2,4,5-Cl.sub.3                                                            21   2,4,6-Cl.sub.3                                                            22   3,4,5-Cl.sub.3                                                            23   2,3,4,6-Cl.sub.4                                                          24   2,3,5,6-Cl.sub.4                                                          25   2,3,4,5,6-Cl.sub.5                                                        26   2-Br                                                                      27   3-Br                                                                      28   4-Br                                                                      29   2,4-Br.sub.2                                                              30   2,5-Br.sub.5                                                              31   2,6-Br.sub.2                                                              32   2,4,6-Br.sub.3                                                            33   2,3,4,5,6-Br.sub.5                                                        34   2-I                                                                       35   3-I                                                                       36   4-I                                                                       37   2,4-I.sub.2                                                               38   2-Cl, 3-F                                                                 39   2-Cl, 4-F                                                                 40   2-Cl, 5-F                                                                 41   2-Cl, 6-F                                                                 42   2-Cl, 3-Br                                                                43   2-Cl, 4-Br                                                                44   2-Cl, 6-Br                                                                45   2-Cl, 6-Br                                                                46   2-Br, 3-Cl                                                                47   2-Br, 4-Cl                                                                48   2-Br, 5-Cl                                                                49   2-Br, 3-F                                                                 50   2-Br, 4-F                                                                 51   2-Br, 5-F                                                                 52   2-Br, 6-F                                                                 53   2-F, 3-Cl                                                                 54   2-F, 4-Cl                                                                 55   2-F, 5-Cl                                                                 56   3-Cl, 4-F                                                                 57   3-Cl, 5-F                                                                 58   3-Cl, 4-Br                                                                59   3-Cl, 5-Br                                                                60   3-F, 4-Cl                                                                 61   3-F, 4-Br                                                                 62   3-Br, 4-Cl                                                                63   3-Br, 4-F                                                                 64   2,6-Cl.sub.2, 4-Br                                                        65   2-CH.sub.3                                                                66   3-CH.sub.3                                                                67   4-CH.sub.3                                                                68   2,3-(CH.sub.3).sub.2                                                      69   2,4-(CH.sub.3).sub.2                                                      70   2,5-(CH.sub.3).sub.2                                                      71   2,6-(CH.sub.3).sub.2                                                      72   3,4-(CH.sub.3).sub.2                                                      73   3,5-(CH.sub.3).sub.2                                                      74   3,5-(CH.sub.3).sub.2                                                      75   2,3,4-(CH.sub.3).sub.3                                                    76   2,3,6-(CH.sub.3).sub.3                                                    77   2,4,5-(CH.sub.3).sub.3                                                    78   2,4,6-(CH.sub.3).sub.3                                                    79   3,4,5-(CH.sub.3).sub.3                                                    80   2,3,4,6-(CH.sub.3).sub.4                                                  81   2,3,5,6-(CH.sub.3).sub.4                                                  82   2,3,4,5,6-(CH.sub.3).sub.5                                                83   2-C.sub.2 H.sub.5                                                         84   3-C.sub.2 H.sub.5                                                         85   4-C.sub.2 H.sub.5                                                         86   2,4-(C.sub.2 H.sub.5).sub.2                                               87   2,6-(C.sub.2 H.sub.5).sub.2                                               88   3,5-(C.sub.2 H.sub.5).sub.2                                               89   2,4,6-(C.sub.2 H.sub.5).sub.3                                             90   2-n-C.sub.3 H.sub.7                                                       91   3-n-C.sub.3 H.sub.7                                                       92   4-n-C.sub.3 H.sub.7                                                       93   2-i-C.sub.3 H.sub.7                                                       94   3-i-C.sub.3 H.sub.7                                                       95   4-i-C.sub.3 H.sub.7                                                       96   2,4-(i-C.sub.3 H.sub.7).sub.2                                             97   2,6-(i-C.sub.3 H.sub.7).sub.2                                             98   3,5-(i-C.sub.3 H.sub.7).sub.2                                             99   2,4,6-(i-C.sub.3 H.sub.7).sub.3                                          100   2-S-C.sub.4 H.sub.9                                                      101   3-S-C.sub.4 H.sub.9                                                      102   4-S-C.sub.4 H.sub.9                                                      103   2-t-C.sub.4 H.sub.9                                                      104   3-t-C.sub.4 H.sub.9                                                      105   4-t-C.sub.4 H.sub.9                                                      106   2,3-(t-C.sub.4 H.sub.9).sub.2                                            107   2,4-(t-C.sub.4 H.sub.9).sub.2                                            108   2,5-(t-C.sub.4 H.sub.9).sub.2                                            109   2,6-(t-C.sub.4 H.sub.9).sub.2                                            110   3,4-(t-C.sub.4 H.sub.9).sub.2                                            111   2,4,6-(t-C.sub.4 H.sub.9).sub.3                                          112   4-n-C.sub.9 H.sub.19                                                     113   4-n-C.sub.12 H.sub.25                                                    114   3-n-C.sub.15 H.sub.31                                                    115   4-(1,1,3,3-tetramethylbutyl)                                             116   4-(2,4,4-trimethylpropyl                                                 117   2-t-C.sub.4 H.sub.9, 4-CH.sub.3                                          118   2-t-C.sub.4 H.sub.9, 5-CH.sub.3                                          119   2,6-(t-C.sub.4 H.sub.9), 4-CH.sub.3                                      120   2-CH.sub.3, 4-t-C.sub.4 H.sub.9                                          121   2-CH.sub.3, 6-t-C.sub.4 H.sub.9                                          122   2-CH.sub.3, 4-i-C.sub.3 H.sub.7                                          123   2-CH.sub.3, 5-i-C.sub.3 H.sub.7                                          124   3-CH.sub.3, 4-i-C.sub.3 H.sub.7                                          125   2-i-C.sub.3 H.sub.7, 5 CH.sub.3                                          126   2,4-(t-C.sub.4 H.sub.9), 6-i-C.sub.3 H.sub.7                             127   2-allyl                                                                  128   3-allyl                                                                  129   4-allyl                                                                  130   2-allyl, 6-CH.sub.3                                                      131   2-cyclo-C.sub.6 H.sub.11                                                 132   3-cyclo-C.sub.6 H.sub.11                                                 133   4-cyclo-C.sub.6 H.sub.11                                                 134   2,4-(cyclo-C.sub.6 H.sub.11).sub.2, 6-CH.sub.3                           135   2-CH.sub.3, 4-cyclo-C.sub.6 H.sub.11                                     136   2-CH.sub.2 C.sub.6 H.sub.5                                               137   3-CH.sub.2 C.sub.6 H.sub.5                                               138   4-CH.sub.2 C.sub.2 H.sub.5                                               139   2-CH.sub.2 C.sub.6 H.sub.5, 4-CH.sub.3                                   140   2-CH.sub.3, 4-CH.sub.2 C.sub.6 H.sub.5                                   141   2-C.sub.6 H.sub.5                                                        142   3-C.sub.6 H.sub.5                                                        143   4-C.sub.6 H.sub.5                                                        144   4-(2-i-C.sub.3 H.sub.7 C.sub.6 H.sub.4)                                  145   4-C.sub.6 H.sub.5, 2,6-(CH.sub.3).sub.2                                  146   2-Cl, 4-C.sub.6 H.sub.5                                                  147   2-Br, 4-C.sub.6 H.sub.5                                                  148   2-C.sub.6 H.sub.5, 4-Cl                                                  149   2-C.sub.6 H.sub.5, 4-Br                                                  150   2-CH.sub.2 C.sub.6 H.sub.5, 4-Cl                                         151   2-CH.sub.2 C.sub.6 H.sub.5, 4-Br                                         152   2-Cl, 4-CH.sub.2 C.sub.6 H.sub.5                                         153   2-Br, 4-CH.sub.2 C.sub.6 H.sub.5                                         154   2-cyclo-C.sub.6 H.sub.11, 4-Cl                                           155   2-cyclo-C.sub.6 H.sub.11, 4-Br                                           156   2-Cl, 4-cyclo-C.sub.6 H.sub.11                                           157   2-Br, 4-cyclo-C.sub.6 H.sub.11                                           158   2-OCH.sub.3                                                              159   3-OCH.sub.3                                                              160   4-OCH.sub.3                                                              161   2-OC.sub.2 H.sub.5                                                       162   3-O-C.sub.2 H.sub.5                                                      163   4-O-C.sub.2 H.sub.5                                                      164   2-O-n-C.sub.3 H.sub.7                                                    165   3-O-n-C.sub.3 H.sub.7                                                    166   4-O-n-C.sub.3 H.sub.7                                                    167   2-O-i-C.sub.3 H.sub.7                                                    168   3-O-i-C.sub.3 H.sub.7                                                    169   4-O-i-C.sub.3 H.sub.7                                                    170   2-O-n-C.sub.6 H.sub.13                                                   171   3-O-n-C.sub.6 H.sub.13                                                   172   4-O-n-C.sub.6 H.sub.13                                                   173   2-O-n-C.sub.8 H.sub.17                                                   174   3-O-n-C.sub.8 H.sub.17                                                   175   4-O-n-C.sub.8 H.sub.17                                                   176   2-O-CH.sub.2 C.sub.6 H.sub.5                                             177   3-O-CH.sub. 2 C.sub.6 H.sub.5                                            178   4-O-CH.sub.2 C.sub.6 H.sub.5                                             179   2-O-(CH.sub.2).sub.3 C.sub.6 H.sub.5                                     180   3-O-(CH.sub.2).sub.3 C.sub.6 H.sub.5                                     181   4-O-(CH.sub.2).sub.3 C.sub.6 H.sub.5                                     182   2,4-(OCH.sub.3).sub.2                                                    183   2-CF.sub.3                                                               184   3-CF.sub.3                                                               185   4-CF.sub.3                                                               186   2-OCF.sub.3                                                              187   3-OCF.sub.3                                                              188   4-OCF.sub.3                                                              189   3-OCH.sub.2 CHF.sub.2                                                    190   2-NO.sub.2                                                               191   3-NO.sub.2                                                               192   4-NO.sub.2                                                               193   2-CN                                                                     194   3-CN                                                                     195   4-CN                                                                     196   2-CH.sub.3, 3-Cl                                                         197   2-CH.sub.3, 4-Cl                                                         198   2-CH.sub.3, 5-Cl                                                         199   2-CH.sub.3, 6-Cl                                                         200   2-CH.sub.3, 3-F                                                          201   2-CH.sub.3, 4-F                                                          202   2-CH.sub.3, 5-F                                                          203   2-CH.sub.3, 6-F                                                          204   2-CH.sub.3, 3-Br                                                         205   2-CH.sub.3, 4-Br                                                         206   2-CH.sub.3, 5-Br                                                         207   2-CH.sub.3, 6-Br                                                         208   2-Cl, 3-CH.sub.3                                                         209   2-Cl, 4-CH.sub.3                                                         210   2-Cl, 5-CH.sub.3                                                         211   2-F, 3-CH.sub.3                                                          212   2-F, 4-CH.sub.3                                                          213   2-F, 5-CH.sub.3                                                          214   2-Br, 3-CH.sub.3                                                         215   2-Br, 4-CH.sub.3                                                         216   2-Br, 5-CH.sub.3                                                         217   3-CH.sub.3, 4-Cl                                                         218   3-CH.sub.3, 5-Cl                                                         219   3-CH.sub.3, 4-F                                                          220   3-CH.sub.3, 4-Br                                                         221   3-CH.sub. 3, 4-Br                                                        222   3-CH.sub.3, 5-Br                                                         223   3-F, 4-CH.sub.3                                                          224   3-Cl, 4-CH.sub.3                                                         225   3-Br, 4-CH.sub.3                                                         226   2-Cl, 4,5-(CH.sub.3).sub.2                                               227   2-Br, 4,5-(CH.sub.3).sub.2                                               228   2-Cl, 3,5-(CH.sub.3).sub.2                                               229   2-Br, 3,5-(CH.sub.3).sub.2                                               230   2,6-Cl.sub.2, 4-CH.sub.3                                                 231   2,6-F.sub.2, 4-CH.sub.3                                                  232   2,6-Br.sub.2, 4-CH.sub.3                                                 233   2,4-Cl.sub.2, 6-CH.sub.3                                                 234   2,4-F.sub.2, 6-CH.sub.3                                                  235   2,4-Br.sub.2, 6-CH.sub.3                                                 236   2,6-(CH.sub.3).sub.2, 4-F                                                237   2,6-(CH.sub.3).sub.2, 4-Cl                                               238   2,6-(CH.sub.3).sub.2, 4-Br                                               239   3,5-(CH.sub.3).sub.2, 4-F                                                240   3,5-(CH.sub.3).sub.2, 4-Cl                                               241   3,5-(CH.sub.3).sub.2, 4-Br                                               242   2,3,6-(CH.sub.3).sub.3, 4-F                                              243   2,3,6-(CH.sub.3).sub.3, 4-Cl                                             244   2,3,6-(CH.sub.3).sub.3, 4-Br                                             245   2,4-(CH.sub.3).sub.2, 6-F                                                246   2,4-(CH.sub.3).sub.2, 6-Cl                                               247   2,4-(CH.sub.3).sub.62, 6-Br                                              248   2-i-C.sub.3 H.sub.7, 4-Cl, 5-CH.sub.3                                    249   2-Cl, 4-NO.sub.2                                                         250   2-NO.sub.2, 4-Cl                                                         251   2-OCH.sub.3, 5-NO.sub.2                                                  252   2,4-Cl.sub.2, 5-NO.sub.2                                                 253   2,4-Cl.sub.2, 6-NO.sub.2                                                 254   2,6-Cl.sub.2, 4-NO.sub.2                                                 255   2,6-Br.sub.2, 4-NO.sub.2                                                 256   2,6-I.sub.2, 4-NO.sub.2                                                  257   2-CH.sub.3, 5-i-C.sub.3 H.sub.7, 4-Cl                                    258   2-C.sub.6 H.sub.5 O                                                      259   3-C.sub.6 H.sub.5 O                                                      260   4-C.sub.6 H.sub.5 O                                                      261   2-CHNOCH.sub.3                                                           262   3-CHNOCH.sub.3                                                           263   4-CHNOCH.sub.3                                                           264   2-CHNOC.sub.2 H.sub.5                                                    265   3-CHNOC.sub.2 H.sub.5                                                    266   4-CHNOC.sub.2 H.sub.5                                                    267   2-CHNO(n-C.sub.3 H.sub.7)                                                268   3-CHNO(n-C.sub.3 H.sub.7)                                                269   4-CHNO(n-C.sub.3 H.sub.7)                                                270   2-CHNO(i-C.sub.3 H.sub.7)                                                271   3-CHNO(i-C.sub.3 H.sub.7)                                                272   4-CHNO(i-C.sub.3 H.sub.7)                                                273   2-CHNO(n-C.sub.6 H.sub.13)                                               274   3-CHNO(n-C.sub.6 H.sub.13)                                               275   4-CHNO(n-C.sub.6 H.sub.13)                                               276   2-CHNO(n-C.sub.8 H.sub.17)                                               277   3-CHNO(n-C.sub.8 H.sub.17)                                               278   4-CHNO(n-C.sub.8 H.sub.17)                                               279   2-CHNOCH.sub.2 (C.sub.6 H.sub.5)                                         280   3-CHNOCH.sub.2 (C.sub.6 H.sub.5)                                         281   4-CHNOCH.sub.2 (C.sub.6 H.sub.5)                                         282   2-CO.sub.2 CH.sub.3                                                      283   3-CO.sub.2 CH.sub.3                                                      284   4-CO.sub.2 CH.sub.3                                                      285   2-CO.sub.2 (C.sub.2 H.sub.5)                                             286   3-CO.sub.2 (C.sub.2 H.sub.5)                                             287   4-CO.sub.2 (C.sub.2 H.sub.5)                                             288   2-CO.sub.2 (n-C.sub.3 H.sub.7)                                           289   3-CO.sub.2 (n-C.sub.3 H.sub.7)                                           290   4-CO.sub.2 (n-C.sub.3 H.sub.7)                                           291   2-CO.sub.2 (i-C.sub.3 H.sub.7)                                           292   3-CO.sub.2 (i-C.sub.3 H.sub.7)                                           293   4-CO.sub.2 (i-C.sub.3 H.sub.7)                                           294   2-CO.sub.2 (n-C.sub.6 H.sub.13)                                          295   3-CO.sub.2 (n-C.sub.6 H.sub.13)                                          296   4-CO.sub.2 (n-C.sub.6 H.sub.13)                                          297   2-CO.sub.2 (n-C.sub.8 H.sub.17)                                          298   3-CO.sub.2 (n-C.sub.8 H.sub.17)                                          299   4-CO.sub.2 (n-C.sub.8 H.sub.17)                                          300   2-CHNOCH.sub.2 CHCH.sub.2                                                301   3-CHNOCH.sub.2 CHCH.sub.2                                                302   4-CHNOCH.sub.2 CHCH.sub.2                                                303   2-CHNO(CH.sub.2).sub.3 (C.sub.6 H.sub.5)                                 304   3-CHNO(CH.sub.2).sub.3 (C.sub.6 H.sub.5)                                 305   4-CHNO(CH.sub.2).sub.3 (C.sub.6 H.sub.5)                                 306   2-CH.sub.2 OCH.sub.3                                                     307   3-CH.sub.2 OCH.sub.3                                                     308   4-CH.sub.2 OCH.sub.3                                                     309   2-CH.sub.2 O(C.sub.2 H.sub.5)                                            310   3-CH.sub.2 O(C.sub.2 H.sub.5)                                            311   4-CH.sub.2 O(C.sub.2 H.sub.5)                                            312   2-CH.sub.2 O(n-C.sub.3 H.sub. 7)                                         313   3-CH.sub.2 O(n-C.sub.3 H.sub.7)                                          314   4-CH.sub.2 O(n-C.sub.3 H.sub.7)                                          315   2-CH.sub.2 O(i-C.sub.3 H.sub.7)                                          316   3-CH.sub.2 O(i-C.sub.3 H.sub.7)                                          317   4-(CH.sub.2 O(i-C.sub.3 H.sub.7)                                         318   2-CH.sub.2 O(n-C.sub.6 H.sub.13)                                         319   3-CH.sub.2 O(n-C.sub.6 H.sub.13)                                         320   4-CH.sub.2 O(n-C.sub.6 H.sub.13)                                         321   2-CH.sub.2 O(n-C.sub.8 H.sub.17)                                         322   3-CH.sub.2 O(n-C.sub.8 H.sub.17)                                         323   4-CH.sub.2 O(n-C.sub.8 H.sub.7)                                          324   2-CH.sub.2 OCH.sub.2 (C.sub.6 H.sub.5)                                   325   3-CH.sub.2 OCH.sub.2 (C.sub.6 H.sub.5)                                   326   4-CH.sub.2 OCH.sub.2 (C.sub.6 H.sub.5)                                   327   2-CH.sub.2 O(CH.sub.2).sub.3                                             328   3-CH.sub.2 O(CH.sub.2).sub.3 (C.sub.6 H.sub.5)                           329   4-CH.sub.2 O(CH.sub.2).sub.3 (C.sub.6 H.sub.5)                           330   2-CHO                                                                    331   3-CHO                                                                    332   4-CHO                                                                    ______________________________________                                    

                  TABLE 16                                                         ______________________________________                                          ##STR43##                                                                     No.   Aryl               mp     NMR: δ (ppm)                             ______________________________________                                          1    1-naphthyl                                                                2    2-naphthyl                                                                3    3-phenanthrenyl                                                           4    2-chlorophenyl                                                            5    2-bromophenyl                                                             6    3-bromophenyl                                                             7    4-bromophenyl                                                             8    2-fluorophenyl                                                            9    3-fluorophenyl                                                           10    4-fluorophenyl                                                           11    2-ethyl-phenyl                                                           12    3-ethyl-phenyl                                                           13    4-ethyl-phenyl                                                           14    2-iso-propyl-phenyl                                                      15    3-iso-propyl-phenyl                                                      16    4-iso-propyl-phenyl                                                      17    2-tert-butyl-phenyl                                                      18    3-tert-butyl-phenyl                                                      19    4-tert-butyl-phenyl                                                      20    4-butyl-phenyl                                                           21    4-hexyl-phenyl                                                           22    4-nonyl-phenyl                                                           23    4-decyl-phenyl                                                           24    2-methoxy-phenyl                                                         25    3-methoxy-phenyl                                                         26    4-methoxy-phenyl                                                         27    2-trifluoromethyl-phenyl                                                 28    3-trifluoromethyl-phenyl                                                 29    4-trifluoromethyl-phenyl                                                 30    4-formyl-phenyl                                                          31    2-nitro-phenyl                                                           32    3-nitro-phenyl                                                           33    4-nitro-phenyl                                                           34    2,5-dichlorophenyl                                                       35    2,6-dichlorophenyl                                                       36    3,4-dichlorophenyl                                                       37    2,3-dichlorophenyl                                                       38    3,5-dichlorophenyl                                                       39    2,3,4-trichlorophenyl                                                    40    2,4,5-trichlorophenyl                                                    41    2,4,6-trichlorophenyl                                                    42    2,3,4,6-tetrachlorophenyl                                                43    2,3,4,5,6-pentachlorophenyl                                              44    2,3,4,5-tetrafluorophenyl                                                45    2,3,5,6-tetrafluorophenyl                                                46    2,3,4,5,6-pentafluorophenyl                                              47    2-chloro, 4-fluorophenyl                                                 48    3-chloro, 4-fluorophenyl                                                 49    2-chloro, 6-methyl-phenyl                                                50    4-chloro, 2-methyl-phenyl                                                51    2,4-dichloro, 5-methyl-phenyl                                            52    4-chloro, 2,5-dimethyl-phenyl                                            53    3-bromo, 3-methyl-phenyl                                                 54    3,5-bistrifluoromethyl-phenyl                                            55    2,5-dimethyl-phenyl                                                      56    2,4-dimethyl-phenyl                                                      57    2,5-dimethyl-phenyl                                                      58    2,6-dimethyl-phenyl                                                      59    3,4-dimethyl-phenyl                                                      60    3,5-dimethyl-phenyl                                                      61    2,4,5-trimethyl-phenyl                                                   62    2,6-diethyl-phenyl                                                       63    2,4-di-tert.-butyl-phenyl                                                64    2,5-dimethoxy-phenyl                                                     65    3,4-dimethoxy-phenyl                                                     66    2-methyl, 4-tert.-butyl-phenyl                                           67    2-methoxycarbonyl-phenyl                                                 68    2-ethoxycarbonyl-phenyl                                                  69    2-propoxycarbonyl-phenyl                                                 70    2-butoxycarbonyl-phenyl                                                  71    2-cyano-phenyl                                                           72    3-cyano-phenyl                                                           73    4-cyano-phenyl                                                           ______________________________________                                    

                  TABLE 17                                                         ______________________________________                                          ##STR44##                                                                     No.   Aryl               mp     NMR: δ (ppm)                             ______________________________________                                          1    1-naphthyl                                                                2    2-naphthyl                                                                3    3-phenanthrenyl                                                           4    2-chlorophenyl                                                            5    2-bromophenyl                                                             6    3-bromophenyl                                                             7    4-bromophenyl                                                             8    2-fluorophenyl                                                            9    3-fluorophenyl                                                           10    4-fluorophenyl                                                           11    2-ethyl-phenyl                                                           12    3-ethyl-phenyl                                                           13    4-ethyl-phenyl                                                           14    2-iso-propyl-phenyl                                                      15    3-iso-propyl-phenyl                                                      16    4-iso-propyl-phenyl                                                      17    2-tert-butyl-phenyl                                                      18    3-tert-butyl-phenyl                                                      19    4-tert-butyl-phenyl                                                      20    4-butyl-phenyl                                                           21    4-hexyl-phenyl                                                           22    4-nonyl-phenyl                                                           23    4-decyl-phenyl                                                           24    2-methoxy-phenyl                                                         25    3-methoxy-phenyl                                                         26    4-methoxy-phenyl                                                         27    2-trifluoromethyl-phenyl                                                 28    3-trifluoromethyl-phenyl                                                 29    4-trifluoromethyl-phenyl                                                 30    4-formyl-phenyl                                                          31    2-nitro-phenyl                                                           32    3-nitro-phenyl                                                           33    4-nitro-phenyl                                                           34    2,5-dichlorophenyl                                                       35    2,6-dichlorophenyl                                                       36    3,4-dichlorophenyl                                                       37    2,3-dichlorophenyl                                                       38    3,5-dichlorophenyl                                                       39    2,3,4-trichlorophenyl                                                    40    2,4,5-trichlorophenyl                                                    41    2,4,6-trichlorophenyl                                                    42    2,3,4,6-tetrachlorophenyl                                                43    2,3,4,5,6-pentachlorophenyl                                              44    2,3,4,5-tetrafluorophenyl                                                45    2,3,5,6-tetrafluorophenyl                                                46    2,3,4,5,6-pentafluorophenyl                                              47    2-chloro, 4-fluorophenyl                                                 48    3-chloro, 4-fluorophenyl                                                 49    2-chloro, 6-methyl-phenyl                                                50    4-chloro, 2-methyl-phenyl                                                51    2,4-dichloro, 5-methyl-phenyl                                            52    4-chloro, 2,5-dimethyl-phenyl                                            53    3-bromo, 3-methyl-phenyl                                                 54    3,5-bistrifluoromethyl-phenyl                                            55    2,5-dimethyl-phenyl                                                      56    2,4-dimethyl-phenyl                                                      57    2,5-dimethyl-phenyl                                                      58    2,6-dimethyl-phenyl                                                      59    3,4-dimethyl-phenyl                                                      60    3,5-dimethyl-phenyl                                                      61    2,4,5-trimethyl-phenyl                                                   62    2,6-diethyl-phenyl                                                       63    2,4-di-tert.-butyl-phenyl                                                64    2,5-dimethoxy-phenyl                                                     65    3,4-dimethoxy-phenyl                                                     66    2-methyl, 4-tert.-butyl-phenyl                                           67    2-methoxycarbonyl-phenyl                                                 68    2-ethoxycarbonyl-phenyl                                                  69    2-propoxycarbonyl-phenyl                                                 70    2-butoxycarbonyl-phenyl                                                  71    2-cyano-phenyl                                                           72    3-cyano-phenyl                                                           73    4-cyano-phenyl                                                           ______________________________________                                    

                  TABLE 18                                                         ______________________________________                                          ##STR45##                                                                     No.   Aryl               mp     NMR: δ (ppm)                             ______________________________________                                          1    1-naphthyl                                                                2    2-naphthyl                                                                3    3-phenanthrenyl                                                           4    2-chlorophenyl                                                            5    2-bromophenyl                                                             6    3-bromophenyl                                                             7    4-bromophenyl                                                             8    2-fluorophenyl                                                            9    3-fluorophenyl                                                           10    4-fluorophenyl                                                           11    2-ethyl-phenyl                                                           12    3-ethyl-phenyl                                                           13    4-ethyl-phenyl                                                           14    2-iso-propyl-phenyl                                                      15    3-iso-propyl-phenyl                                                      16    4-iso-propyl-phenyl                                                      17    2-tert-butyl-phenyl                                                      18    3-tert-butyl-phenyl                                                      19    4-tert-butyl-phenyl                                                      20    4-butyl-phenyl                                                           21    4-hexyl-phenyl                                                           22    4-nonyl-phenyl                                                           23    4-decyl-phenyl                                                           24    2-methoxy-phenyl                                                         25    3-methoxy-phenyl                                                         26    4-methoxy-phenyl                                                         27    2-trifluoromethyl-phenyl                                                 28    3-trifluoromethyl-phenyl                                                 29    4-trifluoromethyl-phenyl                                                 30    4-formyl-phenyl                                                          31    2-nitro-phenyl                                                           32    3-nitro-phenyl                                                           33    4-nitro-phenyl                                                           34    2,5-dichlorophenyl                                                       35    2,6-dichlorophenyl                                                       36    3,4-dichlorophenyl                                                       37    2,3-dichlorophenyl                                                       38    3,5-dichlorophenyl                                                       39    2,3,4-trichlorophenyl                                                    40    2,4,5-trichlorophenyl                                                    41    2,4,6-trichlorophenyl                                                    42    2,3,4,6-tetrachlorophenyl                                                43    2,3,4,5,6-pentachlorophenyl                                              44    2,3,4,5-tetrafluorophenyl                                                45    2,3,5,6-tetrafluorophenyl                                                46    2,3,4,5,6-pentafluorophenyl                                              47    2-chloro, 4-fluorophenyl                                                 48    3-chloro, 4-fluorophenyl                                                 49    2-chloro, 6-methyl-phenyl                                                50    4-chloro, 2-methyl-phenyl                                                51    2,4-dichloro, 5-methyl-phenyl                                            52    4-chloro, 2,5-dimethyl-phenyl                                            53    3-bromo, 3-methyl-phenyl                                                 54    3,5-bistrifluoromethyl-phenyl                                            55    2,5-dimethyl-phenyl                                                      56    2,4-dimethyl-phenyl                                                      57    2,5-dimethyl-phenyl                                                      58    2,6-dimethyl-phenyl                                                      59    3,4-dimethyl-phenyl                                                      60    3,5-dimethyl-phenyl                                                      61    2,4,5-trimethyl-phenyl                                                   62    2,6-diethyl-phenyl                                                       63    2,4-di-tert.-butyl-phenyl                                                64    2,5-dimethoxy-phenyl                                                     65    3,4-dimethoxy-phenyl                                                     66    2-methyl, 4-tert.-butyl-phenyl                                           67    2-methoxycarbonyl-phenyl                                                 68    2-ethoxycarbonyl-phenyl                                                  69    2-propoxycarbonyl-phenyl                                                 70    2-butoxycarbonyl-phenyl                                                  71    2-cyano-phenyl                                                           72    3-cyano-phenyl                                                           73    4-cyano-phenyl                                                           ______________________________________                                    

                                      TABLE 19                                     __________________________________________________________________________      ##STR46##                                                                     No.                                                                               A    Hetaryl                   mp   NMR: δ (ppm)                      __________________________________________________________________________      1 CH.sub.2 S                                                                          4-pyridyl                 76-77                                         2 CH.sub.2 O                                                                          6-methyl-2-pyridyl        76-77                                         3 CH.sub.2 S                                                                          6-methyl-2-pyridyl                                                      4 CH.sub.2 O                                                                          6-ethyl-2-pyridyl                                                       5 CH.sub.2 S                                                                          6-ethyl-2-pyridyl                                                       6 CH.sub.2 O                                                                          6-n-propyl-2-pyridyl                                                    7 CH.sub.2 S                                                                          6-n-propyl-2-pyridyl                                                    8 CH.sub.2 O                                                                          6-iso-propyl-2-pyridyl                                                  9 CH.sub.2 S                                                                          6-iso-propyl-2-pyridyl                                                  10                                                                               CH.sub.2 O                                                                          6-n-butyl-2-pyridyl                                                     11                                                                               CH.sub.2 S                                                                          6-n-butyl-2-pyridyl                                                     12                                                                               CH.sub.2 O                                                                          6-tert.-butyl-2-pyridyl                                                 13                                                                               CH.sub.2 S                                                                          6-tert.-butyl-2-pyridyl                                                 14                                                                               CH.sub.2 O                                                                          6-n-pentyl-2-pyridyl                                                    15                                                                               CH.sub.2 S                                                                          6-n-pentyl-2-pyridyl                                                    16                                                                               CH.sub.2 O                                                                          6-n-hexyl-2-pyridyl                                                     17                                                                               CH.sub.2 S                                                                          6-n-hexyl-2-pyridyl                                                     18                                                                               CH.sub.2 O                                                                          6-phenyl-2-pyridyl                                                      19                                                                               CH.sub.2 S                                                                          6-phenyl-2-pyridyl                                                      20                                                                               CH.sub.2 O                                                                          6-benzyl-2-pyridyl                                                      21                                                                               CH.sub.2 S                                                                          6-benzyl-2-pyridyl                                                       22                                                                              CH.sub.2 S                                                                          6-benzyl-2-pyridyl                                                      23                                                                               CH.sub.2 S                                                                          6-trifluoromethyl-2-pyridyl                                             24                                                                               CH.sub.2 O                                                                          6-methoxy-2-pyridyl                                                     25                                                                               CH.sub.2 S                                                                          6-methoxy-2-pyridyl                                                     26                                                                               CH.sub.2 O                                                                          6-chloro-2-pyridyl        72-73                                         27                                                                               CH.sub.2 S                                                                          6-chloro-2-pyridyl                                                      28                                                                               CH.sub.2 O                                                                          3,6-dimethyl-2-pyridyl                                                  29                                                                               CH.sub.2 S                                                                          3,6-dimethyl-2-pyridyl                                                  30                                                                               CH.sub.2 O                                                                          3,6-diethyl-2-pyridyl                                                   31                                                                               CH.sub.2 S                                                                          3,6-diethyl-2-pyridyl                                                   32                                                                               CH.sub.2 O                                                                          4,6-dimethyl-2-pyridyl                                                  33                                                                               CH.sub.2 S                                                                          4,6-dimethyl-2-pyridyl                                                  34                                                                               CH.sub.2 O                                                                          5,6-dimethyl-2-pyridyl                                                  35                                                                               CH.sub.2 S                                                                          5,6-dimethyl-2-pyridyl                                                  36                                                                               CH.sub.2 O                                                                          4-phenyl-6-methyl-2-pyridyl                                             37                                                                               CH.sub.2 S                                                                          4-phenyl-6-methyl-2-pyridyl                                             38                                                                               CH.sub.2 O                                                                          4,6-diphenyl-2-pyridyl                                                  39                                                                               CH.sub.2 S                                                                          4,6-diphenyl-2-pyridyl                                                  40                                                                               CH.sub.2 O                                                                          3,4-dichloro-6-methyl-2-pyridyl                                         41                                                                               CH.sub.2 S                                                                          3,4-dichloro-6-methyl-2-pyridyl                                         42                                                                               CH.sub.2 O                                                                          3,4,5-trichloro-6-phenyl-2-pyridyl                                      43                                                                               CH.sub.2 S                                                                          3,4,5-trichloro-6-phenyl-2-pyridyl                                      44                                                                               CH.sub.2 O                                                                          4-trifluoromethyl-6-methyl-2-pyridyl                                    45                                                                               CH.sub.2 S                                                                          4-trifluoromethyl-6-methyl-2-pyridyl                                    46                                                                               CH.sub.2 O                                                                          3-acetyl-4,6-dimethyl-2-pyridyl                                         47                                                                               CH.sub.2 S                                                                          3-acetyl-4,6-dimethyl-2-pyridyl                                         48                                                                               CH.sub.2 O                                                                          3-cyano-6-methyl-2-pyridyl                                              49                                                                               CH.sub.2 S                                                                          3-cyano-6-methyl-2-pyridyl                                              50                                                                               CH.sub. 2 O                                                                         3-cyano-6-ethyl-2-pyridyl                                               51                                                                               CH.sub.2 S                                                                          3-cyano-6-ethyl-2-pyridyl                                               52                                                                               CH.sub.2 O                                                                          3-cyano-6-n-propyl-2-pyridyl                                            53                                                                               CH.sub.2 S                                                                          3-cyano-6-n-propyl-2-pyridyl                                            54                                                                               CH.sub.2 O                                                                          3-cyano-6-iso-propyl-2-pyridyl                                          55                                                                               CH.sub.2 S                                                                          3-cyano-6-iso-propyl-2-pyridyl                                          56                                                                               CH.sub.2 O                                                                          3-cyano-6-cyclo-propyl-2-pyridyl                                        57                                                                               CH.sub.2 S                                                                          3-cyano-6-cyclo-propyl-2-pyridyl                                        58                                                                               CH.sub.2 O                                                                          3-cyano-6-n-butyl-2-pyridyl                                             59                                                                               CH.sub.2 S                                                                          3-cyano-6-n-butyl-2-pyridyl                                             60                                                                               CH.sub.2 O                                                                          3-cyano-6-tert.-butyl-2-pyridyl                                         61                                                                               CH.sub.2 S                                                                          3-cyano-6-tert.-butyl-2-pyridyl                                         62                                                                               CH.sub.2 O                                                                          3-cyano-6-cyclo-hexyl-2-pyridyl                                         63                                                                               CH.sub.2 S                                                                          3-cyano-6-cyclo-hexyl-2-pyridyl                                         64                                                                               CH.sub.2 O                                                                          3-cyano-6-phenyl-2-pyridyl                                              65                                                                               CH.sub.2 S                                                                          3-cyano-6-phenyl-2-pyridyl                                              66                                                                               CH.sub.2 O                                                                          3-methyloxycarbonyl-6-iso-propyl-2-pyridyl                              67                                                                               CH.sub.2 S                                                                          3-methyloxycarbonyl-6-iso-propyl-2-pyridyl                              68                                                                               CH.sub.2 O                                                                          3-ethyloxycarbonyl-6-iso-propyl-2-pyridyl                               69                                                                               CH.sub.2 S                                                                          3-ethyloxycarbonyl-6-iso-propyl-2-pyridyl                               70                                                                               CH.sub.2 O                                                                          3-cyano-4,6-dimethyl-2-pyridyl                                          71                                                                               CH.sub.2 S                                                                          3-cyano-4,6-dimethyl-2-pyridyl                                          72                                                                               CH.sub.2 O                                                                          3,5,6-trichloro-2-pyridyl                                               73                                                                               CH.sub.2 S                                                                          3,5,6-trichloro-2-pyridyl                                               74                                                                               CH.sub.2 O                                                                          5-trifluoromethyl-2-pyridyl                                             75                                                                               CH.sub.2 S                                                                          5-trifluoromethyl-2-pyridyl                                             76                                                                               CH.sub.2 O                                                                          3-chloro-5-trifluoromethyl-2-pyridyl                                    77                                                                               CH.sub.2 S                                                                          3-chloro-5-trifluoromethyl-2-pyridyl                                    78                                                                               CH.sub.2 O                                                                          2-quinolyl                                                              79                                                                               CH.sub.2 S                                                                          2-quinolyl                                                              80                                                                               CH.sub.2 O                                                                          3-methyl-2-quinolyl                                                     81                                                                               CH.sub.2 S                                                                          3-methyl-2-quinolyl                                                     82                                                                               CH.sub.2 O                                                                          4-methyl-2-quinolyl                                                     83                                                                               CH.sub.2 S                                                                          4-methyl-2-quinolyl                                                     84                                                                               CH.sub.2 O                                                                          4-ethyl-2-quinolyl                                                      85                                                                               CH.sub.2 S                                                                          4-ethyl-2-quinolyl                                                      86                                                                               CH.sub.2 O                                                                          4-phenyl-2-quinolyl                                                     87                                                                               CH.sub.2 S                                                                          4-phenyl-2-quinolyl                                                     88                                                                               CH.sub.2 O                                                                          6-methyl-2-quinolyl                                                     89                                                                               CH.sub.2 S                                                                          6-methyl-2-quinolyl                                                     90                                                                               CH.sub.2 O                                                                          6-chloro-2-quinolyl                                                     91                                                                               Ch.sub.2 S                                                                          6-chloro-2-quinolyl                                                     92                                                                               CH.sub.2 O                                                                          8-methyl-2-quinolyl                                                     93                                                                               CH.sub.2 S                                                                          8-methyl-2-quinolyl                                                     94                                                                               CH.sub.2 O                                                                          8-chloro-2-quinolyl                                                     95                                                                               CH.sub.2 S                                                                          8-chloro-2-quinolyl                                                     96                                                                               CH.sub.2 O                                                                          4-Ethoxycarbonyl-2-quinolyl                                             97                                                                               CH.sub.2 S                                                                          4-Ethoxycarbonyl-2-quinolyl                                             98                                                                               CH.sub.2 O                                                                          3,4-dimethyl-2-quinolyl                                                 99                                                                               CH.sub.2 S                                                                          3,4-dimethyl-2-quinolyl                                                100                                                                               CH.sub.2 O                                                                          4-methyl-8-methoxy-2-quinolyl                                          101                                                                               CH.sub.2 S                                                                          4-methyl-8-methoxy-2-quinolyl                                          102                                                                               CH.sub.2 O                                                                          4-phenyl-8-ethoxy-2-quinolyl                                           103                                                                               CH.sub.2 S                                                                          4-phenyl-8-ethoxy-2-quinolyl                                           104                                                                               CH.sub.2 O                                                                          4-methyl-8-chloro-2-quinolyl                                           105                                                                               CH.sub.2 S                                                                          4-methyl-8-chloro-2-quinolyl                                           106                                                                               CH.sub.2 O                                                                          4-methyl-8-fluoro-2-quinolyl                                           107                                                                               CH.sub.2 S                                                                          4-methyl-8-fluoro-2-quinolyl                                           108                                                                               CH.sub.2 O                                                                          4-quinolyl                                                             109                                                                               CH.sub.2 S                                                                          4-quinolyl                                                             110                                                                               CH.sub.2 O                                                                          2-methyl-4-quinolyl                                                    111                                                                               CH.sub.2 S                                                                          2-methyl-4-quinolyl                                                    112                                                                               CH.sub.2 O                                                                          2-trichloromethyl-4-quinolyl                                           113                                                                               CH.sub.2 S                                                                          2-trichloromethyl-4-quinolyl                                           114                                                                               CH.sub.2 O                                                                          2-trifluoromethyl-2-quinolyl                                           115                                                                               CH.sub.2 S                                                                          2-trifluoromethyl-2-quinolyl                                           116                                                                               CH.sub.2 O                                                                          2-iso-propyl-4-quinolyl                                                117                                                                               CH.sub.2 S                                                                          2-iso-propyl-4-quinolyl                                                118                                                                               CH.sub.2 O                                                                          2-n-pentyl-4-quinolyl                                                  119                                                                               CH.sub.2 S                                                                          2-n-pentyl-4-quinolyl                                                  120                                                                               CH.sub.2 O                                                                          2-phenyl-4-quinolyl                                                    121                                                                               CH.sub.2 S                                                                          2-phenyl-4-quinolyl                                                    122                                                                               CH.sub.2 O                                                                          2-methoxycarbonyl-4-quinolyl                                           123                                                                               CH.sub.2 S                                                                          2-methoxycarbonyl-4-quinolyl                                           124                                                                               CH.sub.2 O                                                                          2,6-dimethyl-4-quinolyl                                                125                                                                               CH.sub.2 S                                                                          2,6-dimethyl-4-quinolyl                                                126                                                                               CH.sub.2 O                                                                          2-methyl-6-chloro-4-quinolyl                                           127                                                                               CH.sub.2 S                                                                          2-methyl-6-chloro-4-quinolyl                                           128                                                                               CH.sub.2 O                                                                          2-methyl-6-fluoro-4-quinolyl                                           129                                                                               CH.sub.2 S                                                                          2-methyl-6-fluoro-4-quinolyl                                           130                                                                               CH.sub.2 O                                                                          8-quinolyl                                                             131                                                                               CH.sub.2 S                                                                          8-quinolyl                                                             132                                                                               CH.sub.2 O                                                                          2-methyl-8-quinolyl                                                    133                                                                               CH.sub.2 S                                                                          2-methyl-8-quinolyl                                                    134                                                                               CH.sub.2 O                                                                          5,7-dichloro-8-quinolyl                                                135                                                                               CH.sub.2 S                                                                          5,7-dichloro-8-quinolyl                                                136                                                                               CH.sub.2 O                                                                          4,6-dimethyl-2-pyrimidinyl                                             137                                                                               CH.sub.2 S                                                                          4,6-dimethyl-2-pyrimidinyl                                             138                                                                               CH.sub.2 O                                                                          4-trifluoromethyl-2-pyrimidinyl                                        139                                                                               CH.sub.2 S                                                                          4-trifluoromethyl-2-pyrimidinyl                                        140                                                                               CH.sub.2 O                                                                          4,5,6-trimethyl-2-pyrimidinyl                                          141                                                                               CH.sub.2 S                                                                          4,5,6-trimethyl-2-pyrimidinyl                                          142                                                                               CH.sub.2 O                                                                          4-benzyl-6-methyl-2-pyrimidinyl                                        143                                                                               CH.sub.2 S                                                                          4-benzyl-6-methyl-2-pyrimidinyl                                        144                                                                               CH.sub.2 O                                                                          4-methyl-6-phenyl-2-pyrimidinyl                                        145                                                                               CH.sub.2 S                                                                          4-methyl-6-phenyl-2-pyrimidinyl                                        146                                                                               CH.sub.2 O                                                                          4,6-dimethyl-5-chloro-2-pyrimidinyl                                    147                                                                               CH.sub.2 S                                                                          4,6-dimethyl-5-chloro-2-pyrimidinyl                                    148                                                                               CH.sub.2 O                                                                          2,6-dimethyl-4-pyrimidinyl                                             149                                                                               CH.sub.2 S                                                                          2,6-dimethyl-4-pyrimidinyl                                             150                                                                               CH.sub.2 O                                                                          2,6-bis-(trifluoromethyl)-4-pyrimidinyl                                151                                                                               CH.sub.2 S                                                                          2,6-bis-(trifluoromethyl)-4-pyrimidinyl                                152                                                                               CH.sub.2 O                                                                          2-chloromethyl-6-methyl-4-pyrimidinyl                                  153                                                                               CH.sub.2 S                                                                          2-chloromethyl-6-methyl-4-pyrimidinyl                                  154                                                                               CH.sub.2 O                                                                          2-methyl-6-chloromethyl-4-pyrimidinyl                                  155                                                                               CH.sub.2 S                                                                          2-methyl-6-chloromethyl-4-pyrimidinyl                                  156                                                                               CH.sub.2 O                                                                          2-iso-propyl-6-methyl-4-pyrimidinyl                                    157                                                                               CH.sub.2 S                                                                          2-iso-propyl-6-methyl-4-pyrimidinyl                                    158                                                                               CH.sub.2 O                                                                          2-iso-propyl-6-chloromethyl-4-pyrimidinyl                              159                                                                               CH.sub.2 S                                                                          2-iso-propyl-6-chloromethyl-4-pyrimidinyl                              160                                                                               CH.sub.2 O                                                                          2-cyclo-propyl-6-chloromethyl-4-pyrimidinyl                            161                                                                               CH.sub.2 S                                                                          2-cyclo-propyl-6-chloromethyl-4-pyrimidinyl                            162                                                                               CH.sub.2 O                                                                          2-cyclo-propyl-6-methyl-4-pyrimidinyl                                  163                                                                               CH.sub.2 S                                                                          2-cyclo-propyl-6-methyl-4-pyrimidinyl                                  164                                                                               CH.sub.2 O                                                                          2-methyl-6-methoxymethyl-4-pyrimidinyl                                 165                                                                               CH.sub.2 S                                                                          2-methyl-6-methoxymethyl-4-pyrimidinyl                                 166                                                                               CH.sub.2 O                                                                          2-iso-propyl-6-methoxymethyl-4-pyrimidinyl                             167                                                                               CH.sub.2 S                                                                          2-iso-propyl-6-methoxymethyl-4-pyrimidinyl                             168                                                                               CH.sub.2 O                                                                          2-phenyl-4-pyrimidinyl                                                 169                                                                               CH.sub.2 S                                                                          2-phenyl-4-pyrimidinyl                                                 170                                                                               CH.sub.2 O                                                                          3,5-dimethyl-4-pyrimidinyl                                             171                                                                               CH.sub.2 S                                                                          3,5-dimethyl-4-pyrimidinyl                                             172                                                                               CH.sub.2 O                                                                          2-methylthio-6-trifluoromethyl-4-pyrimidinyl                           173                                                                               CH.sub.2 S                                                                          2-methylthio-6-trifluoromethyl-4-pyrimidinyl                           174                                                                               CH.sub.2  O                                                                         2-methylthio-5-chloro-6-trifluoromethyl-4-pyrimidinyl                  175                                                                               CH.sub.2 S                                                                          2-methylthio-5-chloro-6-trifluoromethyl-4-pyrimidinyl                  176                                                                               CH.sub.2 O                                                                          2-methylthio-5-n-octyl-6-methyl-4-pyrimidinyl                          177                                                                               CH.sub.2 S                                                                          2-methylthio-5-n-octyl-6-methyl-4-pyrimidinyl                          178                                                                               CH.sub.2 O                                                                          2-methyl-6-trifluoromethyl-4-pyrimidinyl                               179                                                                               CH.sub.2 S                                                                          2-methyl-6-trifluoromethyl-4-pyrimidinyl                               180                                                                               CH.sub.2 O                                                                          2-n-propyl-6-trifluoromethyl-4-pyrimidinyl                             181                                                                               CH.sub.2 S                                                                          2-n-propyl-6-trifluoromethyl-4-pyrimidinyl                             182                                                                               CH.sub.2 O                                                                          2-iso-propyl-6-trifluoromethyl-4-pyrimidinyl                           183                                                                               CH.sub.2 S                                                                          2-iso-propyl-6-trifluoromethyl-4-pyrimidinyl                           184                                                                               CH.sub.2 O                                                                          2-tert.-butyl-6-trifluoromethyl-4-pyrimidinyl                          185                                                                               CH.sub.2 S                                                                          2-tert.-butyl-6-trifluoromethyl-4-pyrimidinyl                          186                                                                               CH.sub.2 O                                                                          2-methyl-5-chloro-6-trifluoromethyl-4-pyrimidinyl                      187                                                                               CH.sub.2 S                                                                          2-methyl-5-chloro-6-trifluoromethyl-4-pyrimidinyl                      188                                                                               CH.sub.2 O                                                                          2-n-propyl-5-chloro-6-trifluoromethyl-4-pyrimidinyl                    189                                                                               CH.sub.2 S                                                                          2-n-propyl-5-chloro-6-trifluoromethyl-4-pyrimidinyl                    190                                                                               CH.sub.2 O                                                                          2-iso-propyl-5-chloro-6-trifluoromethyl-4-pyrimidinyl                  191                                                                               CH.sub.2 S                                                                          2-iso-propyl-5-chloro-6-trifluoromethyl-4-pyrimidinyl                  192                                                                               CH.sub.2 O                                                                          2-tert.-butyl-5-chloro-6-trifluoromethyl-4-pyrimidininyl               193                                                                               CH.sub.2 S                                                                          2-tert.-butyl-5-chloro-6-trifluoromethyl-4-pyrimidininyl               194                                                                               CH.sub.2 S                                                                          2-pyrimidinyl             62-64                                        195                                                                               CH.sub.2 O                                                                          6-cyclopropyl-2-pyridyl                                                196                                                                               CH.sub.2 S                                                                          6-cyclopropyl-2-pyridyl                                                197                                                                               CH.sub.2 O                                                                          2-pyrazinyl                                                            198                                                                               CH.sub.2 S                                                                          2-pyrazinyl                                                            199                                                                               CH.sub.2 O                                                                          6-chloro-2-pyrazinyl                                                   200                                                                               CH.sub.2 S                                                                          6-chloro-2-pyrazinyl                                                   201                                                                               CH.sub.2 O                                                                          5-methyl-2-pyrazinyl                                                   202                                                                               CH.sub.2 S                                                                          5-methyl-2-pyrazinyl                                                   203                                                                               CH.sub.2 O                                                                          3-pyridazinyl                                                          204                                                                               CH.sub.2 S                                                                          3-pyridazinyl                                                          205                                                                               CH.sub.2 O                                                                          5-chloro-3-pyridazinyl                                                 206                                                                               CH.sub.2 S                                                                          5-chloro-3-pyridazinyl                                                 207                                                                               CH.sub.2 O                                                                          2-thienyl                                                              208                                                                               CH.sub.2 S                                                                          2-thienyl                                                              209                                                                               CH.sub.2 O                                                                          3-thienyl                                                              210                                                                               CH.sub.2 S                                                                          3-thienyl                                                              211                                                                               CH.sub.2 O                                                                          4-chloro-3-thienyl                                                     212                                                                               CH.sub.2 S                                                                          4-chloro-3-thienyl                                                     213                                                                               CH.sub.2 O                                                                          2-chloro-3-thienyl                                                     214                                                                               CH.sub.2 S                                                                          2-chloro-3-thienyl                                                     215                                                                               CH.sub.2 O                                                                          5-chloro-3-thienyl                                                     216                                                                               CH.sub.2 S                                                                          5-chloro-3-thienyl                                                     217                                                                               CH.sub.2 O                                                                          2-quinoxalinyl                                                         218                                                                               CH.sub.2 S                                                                          2-quinoxalinyl                                                         219                                                                               CH.sub.2 O                                                                          3-methyl-2-quinoxalinyl                                                220                                                                               CH.sub.2 S                                                                          3-methyl-2-quinoxalinyl                                                221                                                                               CH.sub.2 O                                                                          7,8-dimethyl-2-quinoxalinyl                                            222                                                                               CH.sub.2 S                                                                          7,8-dimethyl-2-quinoxalinyl                                            223                                                                               CH.sub.2 O                                                                          7,8-dichloro-2-quinoxalinyl                                            224                                                                               CH.sub.2 S                                                                          7,8-dichloro-2-quinoxalinyl                                            225                                                                               CH.sub.2 O                                                                          7-methyl-2-quinoxalinyl                                                226                                                                               CH.sub.2 S                                                                          7-methyl-2-quinoxalinyl                                                227                                                                               CH.sub.2 O                                                                          8-methyl-2-quinoxalinyl                                                228                                                                               CH.sub.2 S                                                                          8-methyl-2-quinoxalinyl                                                229                                                                               CH.sub.2 O                                                                          7-methoxy-2-qunioxalinyl                                               230                                                                               CH.sub.2 S                                                                          7-methoxy-2-quinoxalinyl                                               231                                                                               CH.sub.2 O                                                                          3-phenyl-5-isoxazolyl                                                  232                                                                               CH.sub.2 S                                                                          3-phenyl-5-isoxazolyl                                                  233                                                                               CH.sub.2 O                                                                          2-benzoxazolyl                                                         234                                                                               CH.sub.2 S                                                                          2-benzoxazolyl                                                         235                                                                               CH.sub.2 O                                                                          2-benzthiazolyl                                                        236                                                                               CH.sub.2 S                                                                          2-benzthiazolyl                                                        237                                                                               CH.sub.2 S                                                                          6-methyl-2-benzthiazolyl  86-88                                        238                                                                               CH.sub.2 S                                                                          4-chloro-2-benzthiazolyl  oil  4.6(S, 2H); 7, 55(S, 1H)                239                                                                               CH.sub.2 S                                                                          5-chloro-2-benzthiazolyl  131-133                                      240                                                                               CH.sub.2 S                                                                          6-chloro-2-benzthiazolyl  86-89                                        241                                                                               CH.sub.2 S                                                                          6-ethoxy-2-benzthiazolyl                                               242                                                                               CH.sub.2 S                                                                          5-trifluoromethyl-2-benzthiazolyl                                                                        oil  4.6(S, 2H); 7.55(S, 1H)                 243                                                                               CH.sub.2 S                                                                          4,8-dimethyl-2-quinolyl                                                244                                                                               CH.sub.2 O                                                                          4,8-dimethyl-2-quinolyl                                                245                                                                               CH.sub.2 O                                                                          6-iso-butyl-2-pyridyl                                                  246                                                                               CH.sub.2 O                                                                          3-cyano-6-iso-butyl-2-pyridyl                                          __________________________________________________________________________

                                      TABLE 20                                     __________________________________________________________________________      ##STR47##                                                                     No.                                                                               A    Hetaryl                   mp NMR: δ (ppm)                        __________________________________________________________________________     1  CH.sub.2S                                                                           4-pyridyl                                                              2  CH.sub.2O                                                                           6-methyl-2-pyridyl        oil                                                                               3.95(S, 3H); 4.05                                                              (S, 3H); 5.35(S, 2H)                      3  CH.sub.2S                                                                           6-methyl-2-pyridyl                                                     4  CH.sub.2O                                                                           6-ethyl-2-pyridyl                                                      5  CH.sub.2S                                                                           6-ethyl-2-pyridyl                                                      6  CH.sub.2O                                                                           6-n-propyl-2-pyridyl                                                   7  CH.sub.2S                                                                           6-n-propyl-2-pyridyl                                                   8  CH.sub.2O                                                                           6-iso-propyl-2-pyridyl                                                 9  CH.sub.2S                                                                           6-iso-propyl-2-pyridyl                                                 10 CH.sub.2O                                                                           6-n-butyl-2-pyridyl                                                    11 CH.sub.2S                                                                           6-n-butyl-2-pyridyl                                                    12 CH.sub.2O                                                                           6-tert.-butyl-2-pyridyl                                                13 CH.sub.2S                                                                           6-tert.-butyl-2-pyridyl                                                14 CH.sub.2O                                                                           6-n-pentyl-2-pyridyl                                                   15 CH.sub.2S                                                                           6-n-pentyl-2-pyridyl                                                   16 CH.sub.2O                                                                           6-n-hexyl-2-pyridyl                                                    17 CH.sub.2S                                                                           6-n-hexyl-2-pyridyl                                                    18 CH.sub.2O                                                                           6-phenyl-2-pyridyl                                                     19 CH.sub.2S                                                                           6-phenyl-2-pyridyl                                                     20 CH.sub.2O                                                                           6-benzyl-2-pyridyl                                                     21 CH.sub.2S                                                                           6-benzyl-2-pyridyl                                                     22 CH.sub.2S                                                                           6-benzyl-2-pyridyl                                                     23 CH.sub.2S                                                                           6-trifluoromethyl-2-pyridyl                                            24 CH.sub.2O                                                                           6-methoxy-2-pyridyl                                                    25 CH.sub.2S                                                                           6-methoxy-2-pyridyl                                                    26 CH.sub.2O                                                                           6-chloro-2-pyridyl                                                     27 CH.sub.2S                                                                           6-chloro-2-pyridyl                                                     28 CH.sub.2O                                                                           3,6-dimethyl-2-pyridyl                                                 29 CH.sub.2S                                                                           3,6-dimethyl-2-pyridyl                                                 30 CH.sub.2O                                                                           3,6-diethyl-2-pyridyl                                                  31 CH.sub.2S                                                                           3,6-diethyl-2-pyridyl                                                  32 CH.sub.2O                                                                           4,6-dimethyl-2-pyridyl                                                 33 CH.sub.2S                                                                           4,6-dimethyl-2-pyridyl                                                 34 CH.sub.2O                                                                           5,6-dimethyl-2-pyridyl                                                 35 CH.sub.2S                                                                           5,6-dimethyl-2-pyridyl                                                 36 CH.sub.2O                                                                           4-phenyl-6-methyl-2-pyridyl                                            37 CH.sub.2S                                                                           4-phenyl-6-methyl-2-pyridyl                                            38 CH.sub.2O                                                                           4,6-diphenyl-2-pyridyl                                                 39 CH.sub.2S                                                                           4,6-diphenyl-2-pyridyl                                                 40 CH.sub.2O                                                                           3,4-dichloro-6-methyl-2-pyridyl                                        41 CH.sub.2S                                                                           3,4-dichloro-6-methyl-2-pyridyl                                        42 CH.sub.2O                                                                           3,4,5-trichloro-6-phenyl-2-pyridyl                                     43 CH.sub.2S                                                                           3,4,5-trichloro-6-phenyl-2-pyridyl                                     44 CH.sub.2O                                                                           4-trifluoromethyl-6-methyl-2-pyridyl                                   45 CH.sub.2S                                                                           4-trifluoromethyl-6-methyl-2-pyridyl                                   46 CH.sub.2O                                                                           3-acetyl-4,6-dimethyl-2-pyridyl                                        47 CH.sub.2S                                                                           3-acetyl-4,6-dimethyl-2-pyridyl                                        48 CH.sub.2O                                                                           3-cyano-6-methyl-2-pyridyl                                             49 CH.sub.2S                                                                           3-cyano-6-methyl-2-pyridyl                                             50 CH.sub.2O                                                                           3-cyano-6-ethyl-2-pyridyl                                              51 CH.sub.2S                                                                           3-cyano-6-ethyl-2-pyridyl                                              52 CH.sub.2O                                                                           3-cyano-6-n-propyl-2-pyridyl                                           53 CH.sub.2S                                                                           3-cyano-6-n-propyl-2-pyridyl                                           54 CH.sub.2O                                                                           3-cyano-6-iso-propyl-2-pyridyl                                         55 CH.sub.2S                                                                           3-cyano-6-iso-propyl-2-pyridyl                                         56 CH.sub.2O                                                                           3-cyano-6-cyclo-propyl-2-pyridyl                                       57 CH.sub.2S                                                                           3-cyano-6-cyclo-propyl-2-pyridyl                                       58 CH.sub.2O                                                                           3-cyano-6-n-butyl-2-pyridyl                                            59 CH.sub.2S                                                                           3-cyano-6-n-butyl-2-pyridyl                                            60 CH.sub.2O                                                                           3-cyano-6-tert.-butyl-2-pyridyl                                        61 CH.sub.2S                                                                           3-cyano-6-tert.-butyl-2-pyridyl                                        62 CH.sub.2O                                                                           3-cyano-6-cyclo-hexyl-2-pyridyl                                        63 CH.sub.2S                                                                           3-cyano-6-cyclo-hexyl-2-pyridyl                                        64 CH.sub.2O                                                                           3-cyano-6-phenyl-2-pyridyl                                             65 CH.sub.2S                                                                           3-cyano-6-phenyl-2-pyridyl                                             66 CH.sub.2O                                                                           3-methyloxycarbonyl-6-iso-propyl-2-pyridyl                             67 CH.sub.2S                                                                           3-methyloxycarbonyl-6-iso-propyl-2-pyridyl                             68 CH.sub.2O                                                                           3-ethyloxycarbonyl-6-iso-propyl-2-pyridyl                              69 CH.sub.2S                                                                           3-ethyloxycarbonyl-6-iso-propyl-2-pyridyl                              70 CH.sub.2O                                                                           3-cyano-4,6-dimethyl-2-pyridyl                                         71 CH.sub.2S                                                                           3-cyano-4,6-dimethyl-2-pyridyl                                         72 CH.sub.2O                                                                           3,5,6-trichloro-2-pyridyl                                              73 CH.sub.2S                                                                           3,5,6-trichloro-2-pyridyl                                              74 CH.sub.2O                                                                           5-trifluoromethyl-2-pyridyl                                            75 CH.sub.2S                                                                           5-trifluoromethyl-2-pyridyl                                            76 CH.sub.2O                                                                           3-chloro-5-trifluoromethyl-2-pyridyl                                   77 CH.sub.2S                                                                           3-chloro-5-trifluoromethyl-2-pyridyl                                   78 CH.sub.2O                                                                           2-quinolyl                                                             79 CH.sub.2S                                                                           2-quinolyl                                                             80 CH.sub.2O                                                                           3-methyl-2-quinolyl                                                    81 CH.sub.2S                                                                           3-methyl-2-quinolyl                                                    82 CH.sub.2O                                                                           4-methyl-2-quinolyl                                                    83 CH.sub.2S                                                                           4-methyl-2-quinolyl                                                    84 CH.sub.2O                                                                           4-ethyl-2-quinolyl                                                     85 CH.sub.2S                                                                           4-ethyl-2-quinolyl                                                     86 CH.sub.2O                                                                           4-phenyl-2-quinolyl                                                    87 CH.sub.2S                                                                           4-phenyl-2-quinolyl                                                    88 CH.sub.2O                                                                           6-methyl-2-quinolyl                                                    89 CH.sub.2S                                                                           6-methyl-2-quinolyl                                                    90 CH.sub.2O                                                                           6-chloro-2-quinolyl                                                    91 CH.sub.2S                                                                           6-chloro-2-quinolyl                                                    92 CH.sub.2O                                                                           8-methyl-2-quinolyl                                                    93 CH.sub.2S                                                                           8-methyl-2-quinolyl                                                    94 CH.sub.2O                                                                           8-chloro-2-quinolyl                                                    95 CH.sub.2S                                                                           8-chloro-2-quinolyl                                                    96 CH.sub.2O                                                                           4-ethoxycarbonyl-2-quinolyl                                            97 CH.sub.2S                                                                           4-ethoxycarbonyl-2-quinolyl                                            98 CH.sub.2O                                                                           3,4-dimethyl-2-quinolyl                                                99 CH.sub.2S                                                                           3,4-dimethyl-2-quinolyl                                                100                                                                               CH.sub.2O                                                                           4-methyl-8-methoxy-2-quinolyl                                          101                                                                               CH.sub.2S                                                                           4-methyl-8-methoxy-2-quinolyl                                          102                                                                               CH.sub.2O                                                                           4-phenyl-8-ethoxy-2-quinolyl                                           103                                                                               CH.sub.2S                                                                           4-phenyl-8-ethoxy-2-quinolyl                                           104                                                                               CH.sub.2O                                                                           4-methyl-8-chloro-2-quinolyl                                           105                                                                               CH.sub.2S                                                                           4-methyl-8-chloro-2-quinolyl                                           106                                                                               CH.sub.2O                                                                           4-methyl-8-fluoro-2-quinolyl                                           107                                                                               CH.sub.2S                                                                           4-methyl-8-fluoro-2-quinolyl                                           108                                                                               CH.sub.2O                                                                           4-quinolyl                                                             109                                                                               CH.sub.2S                                                                           4-quinolyl                                                             110                                                                               CH.sub.2O                                                                           2-methyl-4-quinolyl                                                    111                                                                               CH.sub.2S                                                                           2-methyl-4-quinolyl                                                    112                                                                               CH.sub.2O                                                                           2-trichloromethyl-4-quinolyl                                           113                                                                               CH.sub.2S                                                                           2-trichloromethyl-4-quinolyl                                           114                                                                               CH.sub.2O                                                                           2-trichloromethyl-2-quinolyl                                           115                                                                               CH.sub.2S                                                                           2-trichloromethyl-2-quinolyl                                           116                                                                               CH.sub.2O                                                                           2-iso-propyl-4-quinolyl                                                117                                                                               CH.sub.2S                                                                           2-iso-propyl-4-quinolyl                                                118                                                                               CH.sub.2O                                                                           2-n-pentyl-4-quinolyl                                                  119                                                                               CH.sub.2S                                                                           2-n-pentyl-4-quinolyl                                                  120                                                                               CH.sub.2O                                                                           2-phenyl-4-quinolyl                                                    121                                                                               CH.sub.2S                                                                           2-phenyl-4-quinolyl                                                    122                                                                               CH.sub.2O                                                                           2-methoxycarbonyl-4-quinolyl                                           123                                                                               CH.sub.2S                                                                           2-methoxycarbonyl-4-quinolyl                                           124                                                                               CH.sub.2O                                                                           2,6-dimethyl-4-quinolyl                                                125                                                                               CH.sub.2S                                                                           2,6-dimethyl-4-quinolyl                                                126                                                                               CH.sub.2O                                                                           2-methyl-6-chloro-4-quinolyl                                           127                                                                               CH.sub.2S                                                                           2-methyl-6-chloro-4-quinolyl                                           128                                                                               CH.sub.2O                                                                           2-methyl-6-fluoro-4-quinolyl                                           129                                                                               CH.sub.2S                                                                           2-methyl-6-fluoro-4-quinolyl                                           130                                                                               CH.sub.2O                                                                           8-quinolyl                                                             131                                                                               CH.sub.2S                                                                           8-quinolyl                                                             132                                                                               CH.sub.2O                                                                           2-methyl-8-quinolyl                                                    133                                                                               CH.sub.2S                                                                           2-methyl-8-quinolyl                                                    134                                                                               CH.sub.2O                                                                           5,7-dichloro-8-quinolyl                                                135                                                                               CH.sub.2S                                                                           5,7-dichloro-8-quinolyl                                                136                                                                               CH.sub.2O                                                                           4,6-dimethyl-2-pyrimidinyl                                             137                                                                               CH.sub.2S                                                                           4,6-dimethyl-2-pyrimidinyl                                             138                                                                               CH.sub.2O                                                                           4-trifluoromethyl-2-pyrimidinyl                                        139                                                                               CH.sub.2S                                                                           4-trifluoromethyl-2-pyrimidinyl                                        140                                                                               CH.sub.2O                                                                           4,5,6-trimethyl-2-pyrimidinyl                                          141                                                                               CH.sub.2S                                                                           4,5,6-trimethyl-2-pyrimidinyl                                          142                                                                               CH.sub.2O                                                                           4-benzyl-6-methyl-2-pyrimidinyl                                        143                                                                               CH.sub.2S                                                                           4-benzyl-6-methyl-2-pyrimidinyl                                        144                                                                               CH.sub.2O                                                                           4-methyl-6-phenyl-2-pyrimidinyl                                        145                                                                               CH.sub.2S                                                                           4-methyl-6-phenyl-2-pyrimidinyl                                        146                                                                               CH.sub.2O                                                                           4,5-dimethyl-5-chloro-2-pyrimidinyl                                    147                                                                               CH.sub.2S                                                                           4,5-dimethyl-5-chloro-2-pyrimidinyl                                    148                                                                               CH.sub.2O                                                                           2,6-dimethyl-4-pyrimidinyl                                             149                                                                               CH.sub.2S                                                                           2,6-dimethyl-4-pyrimidinyl                                             150                                                                               CH.sub.2O                                                                           2,6-bis-(trifluoromethyl)-4-pyrimidinyl                                151                                                                               CH.sub.2S                                                                           2,6-bis-(trifluoromethyl)-4-pyrimidinyl                                152                                                                               CH.sub.2O                                                                           2-chloromethyl-6-methyl-4-pyrimidinyl                                  153                                                                               CH.sub.2S                                                                           2-chloromethyl-6-methyl-4-pyrimidinyl                                  154                                                                               CH.sub.2O                                                                           2-methyl-6-chloromethyl-4-pyrimidinyl                                  155                                                                               CH.sub.2S                                                                           2-methyl-6-chloromethyl-4-pyrimidinyl                                  156                                                                               CH.sub.2O                                                                           2-iso-propyl-6-methyl-4-pyrimidinyl                                    157                                                                               CH.sub.2S                                                                           2-iso-propyl-6-methyl-4-pyrimidinyl                                    158                                                                               CH.sub.2O                                                                           2-iso-propyl-6-chloromethyl-4-pyrimidinyl                              159                                                                               CH.sub.2S                                                                           2-iso-propyl-6-chloromethyl-4-pyrimidinyl                              160                                                                               CH.sub.2O                                                                           2-cyclo-propyl-6-chloromethyl-4-pyrimidinyl                            161                                                                               CH.sub.2S                                                                           2-cyclo-propyl-6-chloromethyl-4-pyrimidinyl                            162                                                                               CH.sub.2O                                                                           2-cyclo-propyl-6-methyl-4-pyrimidinyl                                  163                                                                               CH.sub.2S                                                                           2-cyclo-propyl-6-methyl-4-pyrimidinyl                                  164                                                                               CH.sub.2O                                                                           2-methyl-6-methoxymethyl-4-pyrimidinyl                                 165                                                                               CH.sub.2S                                                                           2-methyl-6-methoxymethyl-4-pyrimidinyl                                 166                                                                               CH.sub.2O                                                                           2-iso-propyl-6-methoxymethyl-4-pyrimidinyl                             167                                                                               CH.sub.2S                                                                           2-iso-propyl-6-methoxymethyl-4-pyrimidinyl                             168                                                                               CH.sub.2O                                                                           2-phenyl-4-pyrimidinyl                                                 169                                                                               CH.sub.2S                                                                           2-phenyl-4-pyrimidinyl                                                 170                                                                               CH.sub.2O                                                                           3,5-dimethyl-4-pyrimidinyl                                             171                                                                               CH.sub.2S                                                                           3,5-dimethyl-4-pyrimidinyl                                             172                                                                               CH.sub.2O                                                                           2-methylthio-6-trifluoromethyl-4-pyrimidinyl                           173                                                                               CH.sub.2S                                                                           2-methylthio-6-trifluoromethyl-4-pyrimidinyl                           174                                                                               CH.sub.2O                                                                           2-methylthio-5-chloro-6-trifluoromethyl-4-pyrimidinyl                  175                                                                               CH.sub.2S                                                                           2-methylthio-5-chloro-6-trifluoromethyl-4-pyrimidinyl                  176                                                                               CH.sub.2O                                                                           2-methylthio-5-n-octyl-6-trifluoromethyl-4-pyrimidinyl                 177                                                                               CH.sub.2S                                                                           2-methylthio-5-n-octyl-6-trifluoromethyl-4-pyrimidinyl                 178                                                                               CH.sub.2O                                                                           2-methyl-6-trifluoromethyl-4-pyrimidinyl                               179                                                                               CH.sub.2S                                                                           2-methyl-6-trifluoromethyl-4-pyrimidinyl                               180                                                                               CH.sub.2O                                                                           2-n-propyl-6-trifluoromethyl-4-pyrimidinyl                             181                                                                               CH.sub.2S                                                                           2-n-propyl-6-trifluoromethyl-4-pyrimidinyl                             182                                                                               CH.sub.2O                                                                           2-iso-propyl-6-trifluoromethyl-4-pyrimidinyl                           183                                                                               CH.sub.2S                                                                           2-iso-propyl-6-trifluoromethyl-4-pyrimidinyl                           184                                                                               CH.sub.2O                                                                           2-tert.-butyl-6-trifluoromethyl-4-pyrimidinyl                          185                                                                               CH.sub.2S                                                                           2-tert.-butyl-6-trifluoromethyl-4-pyrimidinyl                          186                                                                               CH.sub.2O                                                                           2-methyl-5-chloro-6-trifluoromethyl-4-pyrimidinyl                      187                                                                               CH.sub.2S                                                                           2-methyl-5-chloro-6-trifluoromethyl-4-pyrimidinyl                      188                                                                               CH.sub.2O                                                                           2-n-propyl-5-chloro-6-trifluoromethyl-4-pyrimidinyl                    189                                                                               CH.sub.2S                                                                           2-n-propyl-5-chloro-6-trifluoromethyl-4-pyrimidinyl                    190                                                                               CH.sub.2O                                                                           2-iso-propyl-5-chloro-6-trifluoromethyl-4-pyrimidinyl                  191                                                                               CH.sub.2S                                                                           2-iso-propyl-5-chloro-6-trifluoromethyl-4-pyrimidinyl                  192                                                                               CH.sub.2O                                                                           2-tert.-butyl-5-chloro-6-trifluoromethyl-4-pyrimidinyl                 193                                                                               CH.sub.2S                                                                           2-tert.-butyl-5-chloro-6-trifluoromethyl-4-pyrimidinyl                 194                                                                               CH.sub.2S                                                                           2-pyrimidinyl                                                          195                                                                               CH.sub.2O                                                                           6-cyclopropyl-2-pyridyl                                                196                                                                               CH.sub.2S                                                                           6-cyclopropyl-2-pyridyl                                                197                                                                               CH.sub.2O                                                                           2-pyrazinyl                                                            198                                                                               CH.sub.2S                                                                           2-pyrazinyl                                                            199                                                                               CH.sub.2O                                                                           6-chloro-2-pyrazinyl                                                   200                                                                               CH.sub.2S                                                                           6-chloro-2-pyrazinyl                                                   201                                                                               CH.sub.2O                                                                           5-methyl-2-pyrazinyl                                                   202                                                                               CH.sub.2S                                                                           5-methyl-2-pyrazinyl                                                   203                                                                               CH.sub.2O                                                                           3-pyridazinyl                                                          204                                                                               CH.sub.2S                                                                           3-pyridazinyl                                                          205                                                                               CH.sub.2O                                                                           5-chloro-3-pyridazinyl                                                 206                                                                               CH.sub.2S                                                                           5-chloro-3-pyridazinyl                                                 207                                                                               CH.sub.2O                                                                           2-thienyl                                                              208                                                                               CH.sub.2S                                                                           2-thienyl                                                              209                                                                               CH.sub.2O                                                                           3-thienyl                                                              210                                                                               CH.sub.2S                                                                           3-thienyl                                                              211                                                                               CH.sub.2O                                                                           4-chloro-3-thienyl                                                     212                                                                               CH.sub.2S                                                                           4-chloro-3-thienyl                                                     213                                                                               CH.sub.2O                                                                           2-chloro-3-thienyl                                                     214                                                                               CH.sub.2S                                                                           2-chloro-3-thienyl                                                     215                                                                               CH.sub.2O                                                                           5-chloro-3-thienyl                                                     216                                                                               CH.sub.2S                                                                           5-chloro-3-thienyl                                                     217                                                                               CH.sub.2O                                                                           2-quinoxalinyl                                                         218                                                                               CH.sub.2S                                                                           2-quinoxalinyl                                                         219                                                                               CH.sub.2O                                                                           3-methyl-2-quinoxalinyl                                                220                                                                               CH.sub.2S                                                                           3-methyl-2-quinoxalinyl                                                221                                                                               CH.sub.2O                                                                           7,8-dimethyl-2-quinoxalinyl                                            222                                                                               CH.sub.2S                                                                           7,8-dimethyl-2-quinoxalinyl                                            223                                                                               CH.sub.2O                                                                           7,8-dichloro-2-quinoxalinyl                                            224                                                                               CH.sub.2S                                                                           7,8-dichloro-2-quinoxalinyl                                            225                                                                               CH.sub.2O                                                                           7-methyl-2-quinoxalinyl                                                226                                                                               CH.sub.2S                                                                           7-methyl-2-quinoxalinyl                                                227                                                                               CH.sub.2O                                                                           8-methyl-2-quinoxalinyl                                                228                                                                               CH.sub.2S                                                                           8-methyl-2-quinoxalinyl                                                229                                                                               CH.sub.2O                                                                           7-methoxy-2-quinoxalinyl                                               230                                                                               CH.sub.2S                                                                           7-methoxy-2-quinoxalinyl                                               231                                                                               CH.sub.2O                                                                           3-phenyl-5-isoxazolyl                                                  232                                                                               CH.sub.2S                                                                           3-phenyl-5-isoxazolyl                                                  233                                                                               CH.sub.2O                                                                           2-benzoxazolyl                                                         234                                                                               CH.sub.2S                                                                           2-benzoxazolyl                                                         235                                                                               CH.sub.2O                                                                           2-benzthiazolyl                                                        236                                                                               CH.sub.2S                                                                           2-benzthiazolyl                                                        237                                                                               CH.sub.2S                                                                           6-methyl-2-benzthiazolyl (non-polar isomer)                                                              oil                                                                               3.9(S, 3H); 4.0(S, 3H);                                                        4.55(S, 2H)                               238                                                                               CH.sub.2S                                                                           4-chloro-2-benzthiazolyl                                               239                                                                               CH.sub.2S                                                                           5-chloro-2-benzthiazolyl                                               240                                                                               CH.sub.2S                                                                           6-chloro-2-benzthiazolyl                                               241                                                                               CH.sub.2S                                                                           6-ethoxy-2-benzthiazolyl                                               242                                                                               CH.sub.2S                                                                           5-trifluoromethyl-2-benzthiazolyl                                      243                                                                               CH.sub.2S                                                                           4,8-dimethyl-2-quinolyl                                                244                                                                               CH.sub.2O                                                                           4,8-dimethyl-2-quinolyl                                                245                                                                               CH.sub.2O                                                                           6-iso-butyl-2-pyridyl                                                  246                                                                               CH.sub.2O                                                                           3-cyano-6-iso-butyl-2-pyridyl                                          __________________________________________________________________________

                                      TABLE 21                                     __________________________________________________________________________      ##STR48##                                                                     No.                                                                               A    Hetaryl                   mp                                                                               NMR: δ (ppm)                         __________________________________________________________________________      1 CH.sub.2 S                                                                          4-pyridyl                                                               2 CH.sub.2 O                                                                          6-methyl-2-pyridyl        oil                                                                              3.95(S, 3H); 4.05                                                              (S, 3H); 5.35(S, 2H)                        3 CH.sub.2 S                                                                          6-methy-2-pyridyl                                                       4 CH.sub.2 O                                                                          6-ethyl-2-pyridyl                                                       5 CH.sub.2 S                                                                          6-ethyl-2-pyridyl                                                       6 CH.sub.2 O                                                                          6-n-propyl-2-pyridyl                                                    7 CH.sub.2 S                                                                          6-n-propyl-2-pyridyl                                                    8 CH.sub.2 O                                                                          6-iso-propyl-2-pyridyl                                                  9 CH.sub.2 S                                                                          6-iso-propyl-2-pyridyl                                                  10                                                                               CH.sub.2 O                                                                          6-n-butyl-2-pyridyl                                                     11                                                                               Ch.sub.2 S                                                                          6-n-butyl-2-pyridyl                                                     12                                                                               CH.sub.2 O                                                                          6-tert.-butyl-2-pyridyl                                                 13                                                                               CH.sub.2 S                                                                          6-tert.-butyl-2-pyridyl                                                 14                                                                               CH.sub.2 O                                                                          6-n-pentyl-2-pyridyl                                                    15                                                                               CH.sub.2 S                                                                          6-n-pentyl-2-pyridyl                                                    16                                                                               CH.sub.2 O                                                                          6-n-hexyl-2-pyridyl                                                     17                                                                               CH.sub.2 S                                                                          6-n-hexyl-2-pyridyl                                                     18                                                                               CH.sub.2 O                                                                          6-phenyl-2-pyridyl                                                      19                                                                               CH.sub.2 S                                                                          6-phenyl-2-pyridyl                                                      20                                                                               CH.sub.2 O                                                                          6-benzyl-2-pyridyl                                                      21                                                                               CH.sub.2 S                                                                          6-benzyl-2-pyridyl                                                      22                                                                               CH.sub.2 S                                                                          6-benzyl-2-pyridyl                                                      23                                                                               CH.sub.2 S                                                                          6-trifluoromethyl-2-pyridyl                                             24                                                                               CH.sub.2 O                                                                          6-methoxy-2-pyridyl                                                     25                                                                               CH.sub.2 S                                                                          6-methoxy-2-pyridyl                                                     26                                                                               CH.sub.2 O                                                                          6-chloro-2-pyridyl                                                      27                                                                               CH.sub.2 S                                                                          6-chloro-2-pyridyl                                                      28                                                                               CH.sub.2 O                                                                          3,6-dimethyl-2-pyridyl                                                  29                                                                               CH.sub.2 S                                                                          3,6-dimethyl-2-pyridyl                                                  30                                                                               CH.sub.2 O                                                                          3,6-diethyl-2-pyridyl                                                   31                                                                               CH.sub.2 S                                                                          3,6-diethyl-2-pyridyl                                                   32                                                                               CH.sub.2 O                                                                          4,6-dimethyl-2-pyridyl                                                  33                                                                               CH.sub.2 S                                                                          4,6-dimethyl-2-pyridyl                                                  34                                                                               CH.sub.2 O                                                                          5,6-dimethyl-2-pyridyl                                                  35                                                                               CH.sub.2 S                                                                          5,6-dimethyl-2-pyridyl                                                  36                                                                               CH.sub.2 O                                                                          4-phenyl-6-methyl-2-pyridyl                                             37                                                                               CH.sub.2 S                                                                          4-phenyl-6-methyl-2-pyridyl                                             38                                                                               CH.sub.2 O                                                                          4,6-diphenyl-2-pyridyl                                                  39                                                                               CH.sub.2 S                                                                          4,6-diphenyl-2-pyridyl                                                  40                                                                               CH.sub.2 O                                                                          3,4-dichloro-6-methyl-2-pyridyl                                         41                                                                               CH.sub.2 S                                                                          3,4-dichloro-6-methyl-2-pyridyl                                         42                                                                               CH.sub.2 O                                                                          3,4,5-trichloro-6-phenyl-2-pyridyl                                      43                                                                               CH.sub.2 S                                                                          3,4,5-trichloro-6-phenyl-2-pyridyl                                      44                                                                               CH.sub.2 O                                                                          4-trifluoromethyl-6-methyl-2-pyridyl                                    45                                                                               CH.sub.2 S                                                                          4-trifluoromethyl-6-methyl-2-pyridyl                                    46                                                                               CH.sub.2 O                                                                          3-acetyl-4,6-dimethyl-2-pyridyl                                         47                                                                               CH.sub.2 S                                                                          3-acetyl-4,6-dimethyl-2-pyridyl                                         48                                                                               CH.sub.2 O                                                                          3-cyano-6-methyl-2-pyridyl                                              49                                                                               CH.sub.2 S                                                                          3-cyano-6-methyl-2-pyridyl                                              50                                                                               CH.sub.2 O                                                                          3-cyano-6-ethyl-2-pyridyl                                               51                                                                               CH.sub.2 S                                                                          3-cyano-6-ethyl-2-pyridyl                                               52                                                                               CH.sub.2 O                                                                          3-cyano-6-n-propyl-2-pyridyl                                            53                                                                               CH.sub.2 S                                                                          3-cyano-6-n-propyl-2-pyridyl                                            54                                                                               CH.sub.2 O                                                                          3-cyano-6-iso-propyl-2-pyridyl                                          55                                                                               CH.sub.2 S                                                                          3-cyano-6-iso-propyl-2-pyridyl                                          56                                                                               CH.sub.2 O                                                                          3-cyano-6-cyclo-propyl-2-pyridyl                                        57                                                                               CH.sub.2 S                                                                          3-cyano-6-cyclo-propyl-2-pyridyl                                        58                                                                               CH.sub.2 O                                                                          3-cyano-6-n-butyl-2-pyridyl                                             59                                                                               CH.sub.2 S                                                                          3-cyano-6-n-butyl-2-pyridyl                                             60                                                                               CH.sub.2 O                                                                          3-cyano-6-tert.-butyl-2-pyridyl                                         61                                                                               CH.sub.2 S                                                                          3-cyano-6-tert.-butyl-2-pyridyl                                         62                                                                               CH.sub.2 O                                                                          3-cyano-6-cyclo-hexyl-2-pyridyl                                         63                                                                               CH.sub.2 S                                                                          3-cyano-6-cyclo-hexyl-2-pyridyl                                         64                                                                               CH.sub.2 O                                                                          3-cyano-6-phenyl-2-pyridyl                                              65                                                                               CH.sub.2 S                                                                          3-cyano-6-phenyl-2-pyridyl                                              66                                                                               CH.sub.2 O                                                                          3-methyloxycarbonyl-6-iso-propyl-2-pyridyl                              67                                                                               CH.sub.2 S                                                                          3-methyloxycarbonyl-6-iso-propyl-2-pyridyl                              68                                                                               CH.sub.2 O                                                                          3-ethyloxycarbonyl-6-iso-propyl-2-pyridyl                               69                                                                               CH.sub.2 S                                                                          3-ethyloxycarbonyl-6-iso-propyl-2-pyridyl                               70                                                                               CH.sub.2 O                                                                          3-cyano-4,6-dimethyl-2-pyridyl                                          71                                                                               CH.sub.2 S                                                                          3-cyano-4,6-dimethyl-2-pyridyl                                          72                                                                               CH.sub.2 O                                                                          3,5,6-trichloro-2-pyridyl                                               73                                                                               CH.sub.2 S                                                                          3,5,6-trichloro-2-pyridyl                                               74                                                                               CH.sub.2 O                                                                          5-trifluoromethyl-2-pyridyl                                             75                                                                               CH.sub.2 S                                                                          5-trifluoromethyl-2-pyridyl                                             76                                                                               CH.sub.2 O                                                                          3-chloro-5-trifluoromethyl-2-pyridyl                                    77                                                                               CH.sub.2 S                                                                          3-chloro-5-trifluoromethyl-2-pyridyl                                     78                                                                              CH.sub.2 O                                                                          2-quinolyl                                                              79                                                                               CH.sub.2 S                                                                          2-quinolyl                                                              80                                                                               CH.sub.2 O                                                                          3-methyl-2-quinolyl                                                     81                                                                               CH.sub.2 S                                                                          3-methyl-2-quinolyl                                                     82                                                                               CH.sub.2 O                                                                          4-methyl-2-quinolyl                                                     83                                                                               CH.sub.2 S                                                                          4-methyl-2-quinolyl                                                     84                                                                               CH.sub.2 O                                                                          4-ethyl-2-quinolyl                                                      85                                                                               CH.sub.2 S                                                                          4-ethyl-2-quinolyl                                                      86                                                                               CH.sub.2 O                                                                          4-phenyl-2-quinolyl                                                     87                                                                               CH.sub.2 S                                                                          4-phenyl-2-quinolyl                                                     88                                                                               CH.sub.2 O                                                                          6-methyl-2-quinolyl                                                     89                                                                               CH.sub.2 S                                                                          6-methyl-2-quinolyl                                                     90                                                                               CH.sub.2 O                                                                          6-chloro-2-quinolyl                                                     91                                                                               CH.sub.2 S                                                                          6-chloro-2-quinolyl                                                     92                                                                               CH.sub.2 O                                                                          8-methyl-2-quinolyl                                                     93                                                                               CH.sub.2 S                                                                          8-methyl-2-quinolyl                                                     94                                                                               CH.sub.2 O                                                                          8-chloro-2-quinolyl                                                     95                                                                               CH.sub.2 S                                                                          8-chloro-2-quinolyl                                                     96                                                                               CH.sub.2 O                                                                          4-Ethoxycarbonyl-2-quinolyl                                             97                                                                               CH.sub.2 S                                                                          4-Ethoxycarbonyl-2-quinolyl                                             98                                                                               CH.sub.2 O                                                                          3,4-dimethyl-2-quinolyl                                                 99                                                                               CH.sub.2 S                                                                          3,4-dimethyl-2-quinolyl                                                100                                                                               CH.sub.2 O                                                                          4-methyl-8-methoxy-2-quinolyl                                          101                                                                               CH.sub.2 S                                                                          4-methyl-8-methoxy-2-quinolyl                                          102                                                                               CH.sub.2 O                                                                          4-phenyl-8-ethoxy-2-quinolyl                                           103                                                                               CH.sub.2 S                                                                          4-phenyl-8-ethoxy-2-quinolyl                                           104                                                                               CH.sub.2 O                                                                          4-methyl-8-chloro-2-quinolyl                                           105                                                                               CH.sub.2 S                                                                          4-methyl-8-chloro-2-quinolyl                                           106                                                                               CH.sub.2 O                                                                          4-methyl-8-fluoro-2-quinolyl                                           107                                                                               CH.sub.2 S                                                                          4-methyl-8-fluoro-2-quinolyl                                           108                                                                               CH.sub.2 O                                                                          4-quinolyl                                                             109                                                                               CH.sub.2 S                                                                          4-quinolyl                                                             110                                                                               CH.sub.2 O                                                                          2-methyl-4-quinolyl                                                    111                                                                               CH.sub.2 S                                                                          2-methyl-4-quinolyl                                                    112                                                                               CH.sub.2 O                                                                          2-trichloromethyl-4-quinolyl                                           113                                                                               CH.sub.2 S                                                                          2-trichloromethyl-4-quinolyl                                           114                                                                               CH.sub.2 O                                                                          2-trifluoromethyl-2-quinolyl                                           115                                                                               CH.sub.2 S                                                                          2-trifluoromethyl-2-quinolyl                                           116                                                                               CH.sub.2 O                                                                          2-iso-propyl-4-quinolyl                                                117                                                                               CH.sub.2 S                                                                          2-iso-propyl-4-quinolyl                                                118                                                                               CH.sub.2 O                                                                          2-n-pentyl-4-quinolyl                                                  119                                                                               CH.sub.2 S                                                                          2-n-pentyl-4-quinolyl                                                  120                                                                               CH.sub.2 O                                                                          2-phenyl-4-quinolyl                                                    121                                                                               CH.sub.2 S                                                                          2-phenyl-4-quinolyl                                                    122                                                                               CH.sub.2 O                                                                          2-methoxycarbonyl-4-quinolyl                                           123                                                                               CH.sub.2 S                                                                          2-methoxycarbonyl-4-quinolyl                                           124                                                                               CH.sub.2 O                                                                          2,6-dimethyl-4-quinolyl                                                125                                                                               CH.sub.2 S                                                                          2,6-dimethyl-4-quinolyl                                                126                                                                               CH.sub.2 O                                                                          2-methyl-6-chloro-4-quinolyl                                           127                                                                               CH.sub.2 S                                                                          2-methyl-6-chloro-4-quinolyl                                           128                                                                               CH.sub.2 O                                                                          2-methyl-6-fluoro-4-quinolyl                                           129                                                                               CH.sub.2 S                                                                          2-methyl-6-fluoro-4-quinolyl                                           130                                                                               CH.sub.2 O                                                                          8-quinolyl                                                             131                                                                               CH.sub.2 S                                                                          8-quinolyl                                                             132                                                                               CH.sub.2 O                                                                          2-methyl-8-quinolyl                                                    133                                                                               CH.sub.2 S                                                                          2-methyl-8-quinolyl                                                    134                                                                               CH.sub.2 O                                                                          5,7-dichloro-8-quinolyl                                                135                                                                               CH.sub.2 S                                                                          5,7-dichloro-8-quinolyl                                                136                                                                               CH.sub.2 O                                                                          4,6-dimethyl-2-pyrimidinyl                                             137                                                                               CH.sub.2 S                                                                          4,6-dimethyl-2-pyrimidinyl                                             138                                                                               CH.sub.2 O                                                                          4-trifluoromethyl-2-pyrimidinyl                                        139                                                                               CH.sub.2 S                                                                          4-trifluoromethyl-2-pyrimidinyl                                        140                                                                               CH.sub.2 O                                                                          4,5,6-trimethyl-2-pyrimidinyl                                          141                                                                               CH.sub.2 S                                                                          4,5,6-trimethyl-2-pyrimidinyl                                          142                                                                               CH.sub.2 O                                                                          4-benzyl-6-methyl-2-pyrimidinyl                                        143                                                                               CH.sub.2 S                                                                          4-benzyl-6-methyl-2-pyrimidinyl                                        144                                                                               CH.sub.2 O                                                                          4-methyl-6-phenyl-2-pyrimidinyl                                        145                                                                               CH.sub.2 S                                                                          4-methyl-6-phenyl-2-pyrimidinyl                                        146                                                                               CH.sub.2 O                                                                          4,6-dimethyl-5-chloro-2-pyrimidinyl                                    147                                                                               CH.sub.2 S                                                                          4,6-dimethyl-5-chloro-2-pyrimidinyl                                    148                                                                               CH.sub.2 O                                                                          2,6-dimethyl-4-pyrimidinyl                                             149                                                                               CH.sub.2 S                                                                          2,6-dimethyl-4-pyrimidinyl                                             150                                                                               CH.sub.2 O                                                                          2,6-bis-(trifluoromethyl)-4-pyrimidinyl                                151                                                                               CH.sub.2 S                                                                          2,6-bis-(trifluoromethyl)-4-pyrimidinyl                                152                                                                               CH.sub.2 O                                                                          2-chloromethyl-6-methyl-4-pyrimidinyl                                  153                                                                               CH.sub.2 S                                                                          2-chloromethyl-6-methyl-4-pyrimidinyl                                  154                                                                               CH.sub.2 O                                                                          2-methyl-6-chloromethyl-4-pyrimidinyl                                  155                                                                               CH.sub.2 S                                                                          2-methyl-6-chloromethyl-4-pyrimidinyl                                  156                                                                               CH.sub.2 O                                                                          2-iso-propyl-6-methyl-4-pyrimidinyl                                    157                                                                               CH.sub.2 S                                                                          2-iso-propyl-6-methyl-4-pyrimidinyl                                    158                                                                               CH.sub.2 O                                                                          2-iso-propyl-6-chloromethyl-4-pyrimidinyl                              159                                                                               CH.sub.2 S                                                                          2-iso-propyl-6-chloromethyl-4-pyrimidinyl                              160                                                                               CH.sub.2 O                                                                          2-cyclo-propyl-6-chloromethyl-4-pyrimidinyl                            161                                                                               CH.sub.2 S                                                                          2-cyclo-propyl-6-chloromethyl-4-pyrimidinyl                            162                                                                               CH.sub.2 O                                                                          2-cyclo-propyl-6-methyl-4-pyrimidinyl                                  163                                                                               CH.sub.2 S                                                                          2-cyclo-propyl-6-methyl-4-pyrimidinyl                                  164                                                                               CH.sub.2 O                                                                          2-methyl-6-methoxymethyl-4-pyrimidinyl                                 165                                                                               CH.sub.2 S                                                                          2-methyl-6-methoxymethyl-4-pyrimidinyl                                 166                                                                               CH.sub.2 O                                                                          2-iso-propyl-6-methoxymethyl-4-pyrimidinyl                             167                                                                               CH.sub.2 S                                                                          2-iso-propyl-6-methoxymethyl-4-pyrimidinyl                             168                                                                               CH.sub.2 O                                                                          2-phenyl-4-pyrimidinyl                                                 169                                                                               CH.sub.2 S                                                                          2-phenyl-4-pyrimidinyl                                                 170                                                                               CH.sub.2 O                                                                          3,5-dimethyl-4-pyrimidinyl                                             171                                                                               CH.sub.2 S                                                                          3,5-dimethyl-4-pyrimidinyl                                             172                                                                               CH.sub.2 O                                                                          2-methylthio-6-trifluoromethyl-4-pyrimidinyl                           173                                                                               CH.sub.2 S                                                                          2-methylthio-6-trifluoromethyl-4-pyrimidinyl                           174                                                                               CH.sub.2 O                                                                          2-methylthio-5-chloro-6-trifluoromethyl-4-pyrimidinyl                  175                                                                               CH.sub.2 S                                                                          2-methylthio-5-chloro-6-trifluoromethyl-4-pyrimidinyl                  176                                                                               CH.sub.2 O                                                                          2-methylthio-5-n-octyl-6-methyl-4-pyrimidinyl                          177                                                                               CH.sub.2 S                                                                          2-methylthio-5-n-octyl-6-methyl-4-pyrimidinyl                          178                                                                               CH.sub.2 O                                                                          2-methyl-6-trifluoromethyl-4-pyrimidinyl                               179                                                                               CH.sub.2 S                                                                          2-methyl-6-trifluoromethyl-4-pyrimidinyl                               180                                                                               CH.sub.2 O                                                                          2-n-propyl-6-trifluoromethyl-4-pyrimidinyl                             181                                                                               CH.sub.2 S                                                                          2-n-propyl-6-trifluoromethyl-4-pyrimidinyl                             182                                                                               CH.sub.2 O                                                                          2-iso-propyl-6-trifluoromethyl-4-pyrimidinyl                           183                                                                               CH.sub.2 S                                                                          2-iso-propyl-6-trifluoromethyl-4-pyrimidinyl                           184                                                                               CH.sub.2 O                                                                          2-tert.-butyl-6-trifluoromethyl-4-pyrimidinyl                          185                                                                               CH.sub.2 S                                                                          2-tert.-butyl-6-trifluoromethyl-4-pyrimidinyl                          186                                                                               CH.sub.2 O                                                                          2-methyl-5-chloro-6-trifluoromethyl-4-pyrimidinyl                      187                                                                               CH.sub.2 S                                                                          2-methyl-5-chloro-6-trifluoromethyl-4-pyrimidinyl                      188                                                                               CH.sub.2 O                                                                          2-n-propyl-5-chloro-6-trifluoromethyl-4-pyrimidinyl                    189                                                                               CH.sub.2 S                                                                          2-n-propyl-5-chloro-6-trifluoromethyl-4-pyrimidinyl                    190                                                                               CH.sub.2 O                                                                          2-iso-propyl-5-chloro-6-trifluoromethyl-4-pyrimidinyl                  191                                                                               CH.sub.2 S                                                                          2-iso-propyl-5-chloro-6-trifluoromethyl-4-pyrimidinyl                  192                                                                               CH.sub.2 O                                                                          2-tert.-butyl-5-chloro-6-trifluoromethyl-4-pyrimidininyl               193                                                                               CH.sub.2 S                                                                          2-tert.-butyl-5-chloro-6-trifluoromethyl-4-pyrimidininyl               194                                                                               CH.sub.2 S                                                                          2-pyrimidinyl                                                          195                                                                               CH.sub.2 O                                                                          6-cyclopropyl-2-pyridyl                                                196                                                                               CH.sub.2 S                                                                          6-cyclopropyl-2-pyridyl                                                197                                                                               CH.sub.2 O                                                                          2-pyrizinyl                                                            198                                                                               CH.sub.2 S                                                                          2-pyrazinyl                                                            199                                                                               CH.sub.2 O                                                                          6-chloro-2-pyrazinyl                                                   200                                                                               CH.sub.2 S                                                                          6-chloro-2-pyrazinyl                                                   201                                                                               CH.sub.2 O                                                                          5-methyl-2-pyrazinyl                                                   202                                                                               CH.sub.2 S                                                                          5-methyl-2-pyrazinyl                                                   203                                                                               CH.sub.2 O                                                                          3-pyridazinyl                                                          204                                                                               CH.sub.2 S                                                                          3-pyridazinyl                                                          205                                                                               CH.sub.2  O                                                                         5-chloro-3-pyridazinyl                                                 206                                                                               CH.sub.2 S                                                                          5-chloro-3-pyridazinyl                                                 207                                                                               CH.sub.2 O                                                                          2-thienyl                                                              208                                                                               CH.sub.2 S                                                                          2-thienyl                                                              209                                                                               CH.sub.2 O                                                                          3-thienyl                                                              210                                                                               CH.sub.2 S                                                                          3-thienyl                                                              211                                                                               CH.sub.2 O                                                                          4-chloro-3-thienyl                                                     212                                                                               CH.sub.2 S                                                                          4-chloro-3-thienyl                                                     213                                                                               CH.sub.2 O                                                                          2-chloro-3-thienyl                                                     214                                                                               CH.sub.2 S                                                                          2-chloro-3-thienyl                                                     215                                                                               CH.sub.2 O                                                                          5-chloro-3-thienyl                                                     216                                                                               CH.sub.2 S                                                                          5-chloro-3-thienyl                                                     217                                                                               CH.sub.2 O                                                                          2-quinoxalinyl                                                         218                                                                               CH.sub.2 S                                                                          2-quinoxalinyl                                                         219                                                                               CH.sub.2 O                                                                          3-methyl-2-quinxalinyl                                                 220                                                                               CH.sub.2 S                                                                          3-methyl-2-quinxalinyl                                                 221                                                                               CH.sub.2 O                                                                          7,8-dimethyl-2-quinoxalinyl                                            222                                                                               CH.sub.2 S                                                                          7,8-dimethyl-2-quinoxalinyl                                            223                                                                               CH.sub.2 O                                                                          7,8-dichloro-2-quinoxalinyl                                            224                                                                               CH.sub.2 S                                                                          7,8-dichloro-2-quinoxalinyl                                            225                                                                               CH.sub.2 O                                                                          7-methyl-2-quinoxalinyl                                                226                                                                               CH.sub.2 S                                                                          7-methyl-2-quinoxalinyl                                                227                                                                               CH.sub.2 O                                                                          8-methyl-2-quinoxalinyl                                                228                                                                               CH.sub.2 S                                                                          8-methyl-2-quinoxalinyl                                                229                                                                               CH.sub.2 O                                                                          7-methoxy-2-quinoxalinyl                                               230                                                                               CH.sub.2 S                                                                          7-methoxy-2-quinoxalinyl                                               231                                                                               CH.sub.2 O                                                                          3-phenyl-5-isoxazolyl                                                  232                                                                               CH.sub.2 S                                                                          3-phenyl-5-isoxazolyl                                                  233                                                                               CH.sub.2 O                                                                          2-benzoxazolyl                                                         234                                                                               CH.sub.2 S                                                                          2-benzoxazolyl                                                         235                                                                               CH.sub.2 O                                                                          2-benzthiazolyl                                                        236                                                                               CH.sub.2 S                                                                          2-benzthiazolyl                                                        237                                                                               CH.sub.2 S                                                                          6-methyl-2-benzthiazolyl (non-polar isomer)                                                              oil                                                                              3.9(S, 3H); 4.0(S, 3H);                                                        4, 55(S, 2H)                               238                                                                               CH.sub.2 S                                                                          4-chloro-2-benzthiazolyl                                               239                                                                               CH.sub.2 S                                                                          5-chloro-2-benzthiazolyl                                               240                                                                               CH.sub.2 S                                                                          6-chloro-2-benzthiazolyl                                               241                                                                               CH.sub.2 S                                                                          6-Ethoxy-2-benzthiazolyl                                               242                                                                               CH.sub.2 S                                                                          5-trifluoromethyl-2-benzthiazolyl                                      243                                                                               CH.sub.2 S                                                                          4,8-dimethyl-2-quinolyl                                                244                                                                               CH.sub.2 O                                                                          4,8-dimethyl-2-quinolyl                                                245                                                                               CH.sub.2 O                                                                          6-iso-butyl-2-pyridyl                                                  246                                                                               CH.sub.2 O                                                                          3-cyano-6-iso-butyl-2-pyridyl                                          __________________________________________________________________________

                                      TABLE 22                                     __________________________________________________________________________      ##STR49##                                                                     No.                                                                               Z.sup.1                                                                               Z.sup.2                                                                             U      A       mp NMR                                           __________________________________________________________________________      1 2-OCH.sub.3                                                                           H    HCOCH.sub.3                                                                           CH.sub.2 CH.sub.2                                         2 2-OCH.sub.3                                                                           H    HCOCH.sub.3                                                                           CHCH                                                      3 2-OCH.sub.3                                                                           H    HCOCH.sub.3                                                                           CH.sub.2 O                                                4 2-OCH.sub.3                                                                           H    HCOCH.sub.3                                                                           CH.sub.2 OCO                                              5 2-OCH.sub.3                                                                           H    NOCH.sub.3                                                                            CH.sub.2 CH.sub.2                                         6 2-OCH.sub.3                                                                           H    NOCH.sub.3                                                                            CHCH                                                      7 2-OCH.sub.3                                                                           H    NOCH.sub.3                                                                            CH.sub.2 O                                                8 2-OCH.sub.3                                                                           H    NOCH.sub.3                                                                            CH.sub.2 OCO                                              9 2-OCH.sub.3                                                                           H    CHCH.sub.3                                                                            CH.sub.2 CH.sub.2                                        10 2-OCH.sub.3                                                                           H    CHCH.sub.3                                                                            CHCH                                                     11 2-OCH.sub.3                                                                           H    CHCH.sub.3                                                                            CH.sub.2 O                                               12 2-OCH.sub.3                                                                           H    CHCH.sub.3                                                                            CH.sub.2 OCO                                             13 4-OCH.sub.3                                                                           H    HCOCH.sub.3                                                                           CH.sub.2 CH.sub. 2                                       14 4-OCH.sub.3                                                                           H    HCOCH.sub.3                                                                           CHCH                                                     15 4-OCH.sub.3                                                                           H    HCOCH.sub.3                                                                           CH.sub.2 O                                               16 4-OCH.sub.3                                                                           H    HCOCH.sub.3                                                                           CH.sub.2 OCO                                             17 4-OCH.sub.3                                                                           H    NOCH.sub.3                                                                            CH.sub.2 CH.sub.2                                        18 4-OCH.sub.3                                                                           H    NOCH.sub.3                                                                            CHCH                                                     19 4-OCH.sub.3                                                                           H    NOCH.sub.3                                                                            CH.sub.2 O                                               20 4-OCH.sub.3                                                                           H    NOCH.sub.3                                                                            CH.sub.2 OCO                                             21 4-OCH.sub.3                                                                           H    CHCH.sub.3                                                                            CH.sub.2 CH.sub.2                                        22 4-OCH.sub.3                                                                           H    CHCH.sub.3                                                                            CHCH                                                     23 4-OCH.sub.3                                                                           H    CHCH.sub.3                                                                            CH.sub.2 O                                               24 4-OCH.sub.3                                                                           H    CHCH.sub.3                                                                            CH.sub.2 OCO                                             25 6-N(CH.sub.3).sub.2                                                                   H    HCOCH.sub.3                                                                           CH.sub.2 CH.sub.2                                        26 6-N(CH.sub.3).sub.2                                                                   H    HCOCH.sub.3                                                                           CHCH                                                     27 6-N(CH.sub.3).sub.2                                                                   H    HCOCH.sub.3                                                                           CH.sub.2 O                                               28 6-N(CH.sub.3).sub.2                                                                   H    HCOCH.sub.3                                                                           CH.sub.2 OCO                                             29 6-N(CH.sub.3).sub.2                                                                   H    NOCH.sub.3                                                                            CH.sub.2 CH.sub.2                                        30 6-N(CH.sub.3).sub.2                                                                   H    NOCH.sub.3                                                                            CHCH                                                     31 6-N(CH.sub.3).sub.2                                                                   H    NOCH.sub.3                                                                            CH.sub.2 O                                               32 6-N(CH.sub.3).sub.2                                                                   H    NOCH.sub. 3                                                                           CH.sub.2 O                                               33 6-N(CH.sub.3).sub.2                                                                   H    CHCH.sub.3                                                                            CH.sub.2 CH.sub.2                                        34 6-N(CH.sub.3).sub.2                                                                   H    CHCH.sub.3                                                                            CHCH                                                     35 6-N(CH.sub.3).sub.2                                                                   H    CHCH.sub.3                                                                            CH.sub.2 O                                               36 6-N(CH.sub.3).sub.2                                                                   H    CHCH.sub.3                                                                            CH.sub.2 OCO                                             37 5-NO.sub.2                                                                            6-OCH.sub.3                                                                         HCOCH.sub.3                                                                           CH.sub.2 CH.sub.2                                        38 5-NO.sub.2                                                                            6-OCH.sub.3                                                                         HCOCH.sub.3                                                                           CHCH                                                     39 5-NO.sub.2                                                                            6-OCH.sub.3                                                                         HCOCH.sub.3                                                                           CH.sub.2 O                                               40 5-NO.sub.2                                                                            6-OCH.sub.3                                                                         HCOCH.sub.3                                                                           CH.sub.2 OCO                                             41 5-NO.sub.2                                                                            6-OCH.sub.3                                                                         NOCH.sub.3                                                                            CH.sub.2 CH.sub.2                                        42 5-NO.sub.2                                                                            6-OCH.sub.3                                                                         NOCH.sub.3                                                                            CHCH                                                     43 5-NO.sub.2                                                                            6-OCH.sub.3                                                                         NOCH.sub.3                                                                            CH.sub.2 O                                               44 5-NO.sub.2                                                                            6-OCH.sub.3                                                                         NOCH.sub.3                                                                            CH.sub.2 OCO                                             45 5-NO.sub.2                                                                            6-OCH.sub.3                                                                         CHCH.sub.3                                                                            CH.sub.2 CH.sub.2                                        46 5-NO.sub.2                                                                            6-OCH.sub.3                                                                         CHCH.sub.3                                                                            CHCH                                                     47 5-NO.sub.2                                                                            6-OCH.sub.3                                                                         CHCH.sub.3                                                                            CH.sub.2 O                                               48 5-NO.sub.2                                                                            6-OCH.sub.3                                                                         CHCH.sub.3                                                                            CH.sub.2 OCO                                             49 5-NO.sub.2                                                                            H    HCOCH.sub.3                                                                           OCH.sub.2                                                50 5-NO.sub.2                                                                            H    NOCH.sub.3                                                                            OCH.sub.2                                                51 5-NO.sub.2                                                                            H    CHCH.sub.3                                                                            OCH.sub.2                                                52 4-NO.sub.2                                                                            H    HCOCH.sub.3                                                                           OCH.sub.2                                                53 4-NO.sub.2                                                                            H    NOCH.sub.3                                                                            OCH.sub.2                                                54 4-NO.sub.2                                                                            H    CHCH.sub.3                                                                            OCH.sub.2                                                55 2-CO.sub.2 CH.sub.3                                                                   H    HCOCH.sub.3                                                                           OCH.sub.2                                                56 2-CO.sub.2 CH.sub.3                                                                   H    NOCH.sub.3                                                                            OCH.sub.2                                                57 2-CO.sub.2 CH.sub.3                                                                   H    CHCH.sub.3                                                                            OCH.sub.2                                                58 4-OCH.sub.3                                                                           H    HCOCH.sub.3                                                                           OCH.sub.2                                                59 4-OCH.sub.3                                                                           H    NOCH.sub.3                                                                            OCH.sub.2                                                60 4-OCH.sub.3                                                                           H    CHCH.sub.3                                                                            OCH.sub.2                                                61 4-OCH.sub.3                                                                           5-Br HCOCH.sub.3                                                                           OCH.sub.2                                                62 4-OCH.sub.3                                                                           5-Br NOCH.sub.3                                                                            OCH.sub.2                                                63 4-OCH.sub.3                                                                           5-Br CHCH.sub.3                                                                            OCH.sub.2                                                64 CH.sub.2 C.sub.6 H.sub.5                                                              H    HCOCH.sub.3                                                                           OCH.sub.2                                                65 CH.sub.2 C.sub.6 H.sub.5                                                              H    NOCH.sub.3                                                                            OCH.sub.2                                                66 CH.sub.2 C.sub.6 H.sub.5                                                              H    CHCH.sub.3                                                                            OCH.sub.2                                                __________________________________________________________________________

In general terms, the novel compounds are extremely effective on a broad spectrum of phytopathogenic fungi, in particular those from the class consisting of the Ascomycetes and Basidiomycetes. Some of them have a systemic action and can be used as foliar and soil fungicides.

The fungicidal compounds are of particular interest for controlling a large number of fungi in various crops or their seeds, especially wheat, rye, barley, oats, rice, Indian corn, lawns, cotton, soybeans, coffee, sugar cane, fruit and ornamentals in horticulture and viticulture, and in vegetables such as cucumbers, beans and cucurbits.

The novel compounds are particularly useful for controlling the following plant diseases:

Erysiphe graminis in cereals,

Erysiphe cichoracearum and Sphaerotheca fuliginea in cucurbits,

Podosphaera leucotricha in apples,

Uncinula necator in vines,

Puccinia species in cereals,

Rhizoctonia solani in cotton,

Ustilago species in cereals and sugar cane,

Venturia inaeualis (scab) in apples,

Helminthosporium species in cereals,

Septoria nodorum in wheat,

Botrytis cinerea (gray mold) in strawberries and grapes,

Cercospora arachidicola in groundnuts,

Pseudocercosporella herpotrichoides in wheat and barley,

Pyricularia oryzae in rice,

Phytophthora infestans in potatoes and tomatoes,

Fusarium and Verticillium species in various plants,

Plasmopara viticola in grapes,

Alternaria species in fruit and vegetables.

The compounds are applied by spraying or dusting the plants with the active ingredients, or treating the seeds of the plants with the active ingredients. They may be applied before or after infection of the plants or seeds by the fungi. Either the fungi themselves, or the plants, seed, materials or the soil to be protected against fungus attack are treated with a fungicidally effective amount of the active ingredient.

The novel substances can be converted into conventional formulations such as solutions, emulsions, suspensions, dusts, powders, pastes and granules. The application forms depend entirely on the purposes for which they are intended; they should at all events ensure a fine and uniform distribution of the active ingredient. The formulations are produced in known manner, for example by extending the active ingredient with solvents and/or carriers, with or without the use of emulsifiers and dispersants; if water is used as solvent, it is also possible to employ other organic solvents as auxiliary solvents. Suitable auxiliaries for this purpose are solvents such as aromatics (e.g., xylene), chlorinated aromatics (e.g., chlorobenzenes), paraffins (e.g., crude oil fractions), alcohols (e.g., methanol, butanol), ketones (e.g., cyclohexanone), amines (e.g., ethanolamine, dimethylformamide), and water; carriers such as ground natural minerals (e.g., kaolins, aluminas, talc and chalk) and ground synthetic minerals (e.g., highly disperse silica and silicates); emulsifiers such as nonionic and anionic emulsifiers (e.g., polyoxyethylene fatty alcohol ethers, alkyl sulfonates and aryl sulfonates); and dispersants such as lignin, sulfite waste liquors and methylcellulose.

The fungicides generally contain from 0.1 to 95, and preferably from 0.5 to 90, wt % of active ingredient. The application rates are from 0.02 to 3 kg or more of active ingredient per hectare, depending on the type of effect desired. The novel compounds may also be used for protecting materials (timber), e.g., against Paecilomyces variotii. When the active ingredients are used for treating seed, rates of from 0.001 to 50, and preferably from 0.01 to 10, g per kg of seed are generally sufficient.

The agents and the ready-to-use formulations prepared from them, such as solutions, emulsions, suspensions, powders, dusts, pastes and granules, are applied in conventional manner, for example by spraying, atomizing, dusting, scattering, dressing or watering.

Examples of formulations are given below.

I. A solution of 90 parts by weight of compound no. 2/77 and 10 parts by weight of N-methyl-α-pyrrolidone, which is suitable for application in the form of very fine drops.

II. A mixture of 20 parts by weight of compound no. 4/65, 80 parts by weight of xylene, 10 parts by weight of the adduct of 8 to 10 moles of ethylene oxide and I mole of oleic acid-N-monoethanolamide, 5 parts by weight of the calcium salt of dodecylbenzenesulfonic acid, and 5 parts by weight of the adduct of 40 moles of ethylene oxide and 1 mole of castor oil. By finely dispersing the mixture in water, an aqueous dispersion is obtained.

III. An aqueous dispersion of 20 parts by weight of compound no. 13/8, 40 parts by weight of cyclohexanone, 30 parts by weight of isobutanol, 20 parts by weight of the adduct of 40 moles of ethylene oxide and 1 mole of castor oil. By finely dispersing the mixture in water, an aqueous dispersion is obtained.

IV. An aqueous dispersion of 20 parts by weight of compound no. 19/2, 25 parts by weight of cyclohexanol, 65 parts by weight of a mineral oil fraction having a boiling point between 210° and 280° C., and 10 parts by weight of the adduct of 40 moles of ethylene oxide and 1 mole of castor oil. By finely dispersing the mixture in water, an aqueous dispersion is obtained.

V. A hammer-milled mixture of 80 parts by weight of compound no. 19/26, 3 parts by weight of the sodium salt of diisobutylnaphthalene-α-sulfonic acid, 10 parts by weight of the sodium salt of a lignin-sulfonic acid obtained from a sulfite waste liquor, and 7 parts by weight of powdered silica gel. By finely dispersing the mixture in water, a spray liquor is obtained.

VI. An intimate mixture of 3 parts by weight of compound no. 2111 and 97 parts by weight of particulate kaolin. The dust contains 3 wt % of the active ingredient.

VII. An intimate mixture of 30 parts by weight of compound no. 2/14, 92 parts by weight of powdered silica gel and 8 parts by weight of paraffin oil sprayed onto the surface of this silica gel. This formulation of the active ingredient exhibits good adherence.

VIII. A stable aqueous dispersion of 40 parts by weight of compound no. 2/24, 10 parts of the sodium salt of a phenolsulfonic acid-urea-formaldehyde condensate, 2 parts of silica gel and 48 parts of water, which dispersion can be further diluted.

IX. A stable oily dispersion of 20 parts by weight of compound no. 2/77, 2 parts by weight of the calcium salt of dodecylbenzenesulfonic acid, 8 parts by weight of a fatty alcohol polyglycol ether, 2 parts by weight of the sodium salt of a phenolsulfonic acid-urea-formaldehyde condensate and 68 parts by weight of a paraffinic mineral oil.

In these application forms, the agents according to the invention may also be present together with other active ingredients, for example herbicides, insecticides, growth regulators, and fungicides, and may furthermore be mixed and applied together with fertilizers. Admixture with other fungicides frequently results in a greater fungicidal action spectrum.

Methyloxime (B) disclosed in DE 36 23 921, and 2-phenyloxymethylenephenylglyoxylic acid-O-methyloxime (C) disclosed in DE 36 23 921 were used for comparison purposes.

USE EXAMPLE 1 Action on Plasmopara viticola

Leaves of potted vines of the Muller-Thurgau variety were sprayed with aqueous suspensions containing (dry basis) 80% of active ingredient and 20% of emulsifier. To assess the duration of action, the plants were set up, after the sprayed-on layer had dried, for 8 days in the greenhouse. Then the leaves were infected with a zoospore suspension of Plasmopara viticola. The plants were first placed for 48 hours in a water vapor-saturated chamber at 24° C. and then in a greenhouse for 5 days at from 20° to 30° C. To accelerate and intensify the sporangiophore discharge, the plants were then again placed in the moist chamber for 16 hours. The extent of fungus attack was then assessed on the undersides of the leaves. The results show that active ingredients 2/77, 4/65, 13/8, 19/2 and 19/26, applied as 0.006 wt % spray liquors, had a better fungicidal action (85%) than the prior art active ingredients A, B and C (60%).

USE EXAMPLE 2 Action on Pyrenophora teres

Barley seedlings of the "Igri" variety were sprayed to runoff at the 2-leaf stage with aqueous suspensions containing (dry basis) 80% of active ingredient and 20% emulsifier. After 24 hours the plants were inoculated with a spore suspension of the fungus Pyrenophora teres and placed for 48 hours in a high-humidity climatic cabinet kept at 18° C. The plants were then cultivated for a further 5 days in the greenhouse at 20°-22° C. and a relative humidity of 70%. The extent of fungus spread was then determined.

The results show that active ingredients 2/11, 2/14, 2/24, 2/77, 2/84, 2/456, 2/473, 2/474, 4/8, 4/65, 7/8, 7/66, 13/9, 13/10, 13/65, 13/66, 19/2, 19/26, 19/194, 19/237, 19/238, 19/239, 19/240 and 19/242, applied as 0.05% spray liquors, had a better fungicidal action (95%) than prior art active ingredients B (60%) and C (50%).

The novel compounds are also suitable for effectively combating pests such as insects, arachnids and nematodes. They may be used as pesticides in crop protection and in the hygiene, stores protection and veterinary sector.

Examples of injurious insects belonging to the Lepidoptera order are Agrotis upsilon, Agrotis segetum, Alabama argillacea, Anticarsia gemmatalis, Argyresthia conjugella, Autographs gamma, Bupalus piniarius, Cacoecia murinana, Capua reticulana, Cheimatobia brumata, Choristoneura fumiferana, Choristoneura occidentalis, Cirphis unipuncta, Cydia pomonella, Dendrolimus pini, Diaphania nitidalis, Diatraea grandiosella, Earias insulana, Elasmopalpus lignosellus, Eupoecilia ambiguella, Evetria bouliana, Feltia subterranea, Galleria mellonella, Grapholita funebrana, Grapholita molests, Heliothis armigera, Heliothis virescens, Heliothis zea, Hellula undalis, Hibernia defoliaria, Hyphantria cunea, Hyponomeuta malinellus, Keifferia lycopersicella, Lambdina fiscellaria, Laphygma exigua, Leucoptera coffeella, Leucoptera scitella, Lithocolletis blancardella, Lobesia botrana, Loxostege sticticalis, Lymantria dispar, Lymantria monacha, Lyonetia clerkella, Malacosoma neustria, Mamestra brassicae, orgyia pseudotsugata, Ostrinia nubilalis, Panolis flamea, Pectinophora gossypiella, Peridroma saucia, Phalera bucephala, Phthorimaea operculella, Phyllocnistis citrella, Pieris brassicae, Plathypena scarbra, Plutella xylostella, Pseudoplusia includens, Phyacionia frustrana, Scrobipalpula absoluta, Sitotroga cerelella, Sparganothis pilleriana, Spodoptera frugiperda, Spodoptera littoralis, Spodoptera litura, Thaumatopoea pityocampa, Tortrix viridana, Trichoplusia ni and Zeiraphera canadensis.

Examples from the Coleoptera order are Agrilus sinuatus, Agriotes lineatus, Agriotes obscurus, Amphimallus solstitialis, Anisandrus dispar, Anthonomus grandis, Anthonomus pomorum, Atomaria linearis, Blastophagus piniperda, Blitophaga undata, Bruchus rufimanus, Bruchus pisorum, Bruchus lentis, Byctiscus betulae, Cassida nebulosa, Cerotoma trifurcata, Ceuthorrhynchus assimilis, Ceuthorrynchus napi, Chaetocnema tibialis, Conoderus vespertinus, Crioceris asparagi, Diabrotica longicornis, Diabrotica 12-punctata, Diabrotica virgifera, Epilachna varivestis, Epitrix hirtipennis, Eutinobothrus brasiliensis, Hylobius abietis, Hypera brunneipennis, Hypera postica, Ips typographus, Lema bilineata, Lema melanopus, Leptinotarsa decemlineata, Limonius californicus, Lissorhoptrus oryzophilus, Melanotus communis, Meligethes aeneus, melolontha hippocastani, Melolontha melolontha, Onlema oryzae, Ortiorrhynchus sulcatus, Ortiorrhynchus ovatus, Phaedon cochleariae, Phyllotreta chrysocephala, Phyllophaga sp., Phyllopertha horticola, Phyllotreta nemorum, Phyllotreta striolata, Popillia japonica, Sitona lineatus and Sitophilus granaria.

Examples from the Diptera order are Aedes aegypti, Aedes vexans, Anastrepha ludens, Anopheles maculipennis, Ceratitis capitata, Chrysomya bezziana, Chrysomya hominivorax, Chrysomya macellaria, Contarinia sorghicola, Cordylobia anthropophaga, Culex pipiens, Dacus cucurbitae, Dacus oleae, Dasineura brassicae, Fannia canicularis, Gasterophilus intestinalis, Glossia morsitans, Haematobia irritans, Haplodiplosis equestris, Hylemyia platura, Hypoderma lineata, Liriomyza sativae, Liriomyza trifolii, Lucilia caprina, Lucilia cuprina, Lucilia sericata, Lycoria pectoralis, Mayetiola destructor, Musca domestica, Muscina stabulans, Oestrus ovis, Oscinella frit, Pegomya hysocyami, Phorbia antiqua, Phorbia brassicae, Phorbia coarctata, Rhagoletis cerasi, Rhagoletis pomonella, Tabanus bovinus, Tipula oleracea and Tipula paludosa.

Examples from the Thysanoptera order are Frankliniella fusca, Frankliniella occidentalis, Frankliniella tritici, Scirtothrips citri, Thrips oryzae, Thrips palmi and Thrips tabaci.

Examples from the Hymenoptera order are Athalia rosae, Atta cephalotes, Atta sexdens, Atta texana, Hoplocampa minuta, Hoplocampa testundinea, Monomorium pharaonis, Solenopsis geminata and Solenopsis invicta.

Examples from the Heteroptera order are Acrosternum hilare, Blissus leucopterus, Cyrtopeltis notatus, Dysdercus cingulatus, Dysdercus intermedius, Eurygaster integriceps, Euchistus impictiventris, Leptoglossus phyllopus, Lygus lineolaris, Lygus pratensis, Nezara viridula, Piesma quadrata, Solubea insularis and Thyanta perditor.

Examples from the nematodes class are root-knot nematodes, e.g., Meloidogyne hapla, Meloidocivne incognita and Meloidogyne javanica, cyst-forming nematodes, e.g., Globodera rostochiensis, Heterodera avenae, Hetrodera glycinae, Heterodera schachtii and Heterodera trifolii, and stem and leaf eelworms, e.g., Belolaimus longicaudatus, Ditylenchus destructor, Ditylenchus dipsaci, Heliocotylenchus multicinctus, Longidorus elongatus, Radopholus similis, Rotylenchus robustus, Trichodorus primitivus, Tylenchorhynchus claytoni, Tylenchorhynchus dubius, Pratylenchus neglectus, Pratylenchus penetrans, Pratylenchus curvitatus and Pratylenchus goodeyi.

When the active ingredients are used for combating pests, the concentration of the active ingredients in the finished formulations may vary over a wide range. Generally, they are from 0.0001 to 10, and preferably from 0.001 to 0.1, %.

The active ingredients may also successfully be used in the ultra-low-volume (ULV) method, where it is possible to apply formulations containing more than 95 wt % of active ingredient, or even the active ingredient without additives.

In the open, the amount of active ingredient applied is for example from 0.01 to 10, particularly from 0.01 to 1.0, kg/ha. 

We claim:
 1. A compound of the formula ##STR50## wherein U is ═CH₂, ═CHCH₃, or ═CHCH₂ CH₃ ; X is methyl; and m is 0, 1, or
 2. 2. A fungicidal composition containing a fungicidally effective amount of a compound according to claim 1 and an inert carrier therefor.
 3. A process for combatting fungi comprising applying to the fungi, or to the plants, materials, seeds, or soil threatened by fungus attack, a fungicidally effective amount of a compound according to claim
 1. 4. A compound according to claim 1 wherein U is ═CHCH₃ and m is
 0. 5. A compound according to claim 1 wherein U is ═CHCH₃ and X_(m) is 2-methyl.
 6. A compound according to claim 1, wherein U is ═CHCH₃ and X_(m) is 2,5-dimethyl. 